Process for obtaining aromatics and aromatic stream
AssigneePetroleo Brasileiro S.A. - Petrobras
InventorsAndrea De Rezende Pinho, Willian Luiz Souza Fernandez
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AssigneePetroleo Brasileiro S.A. - Petrobras
InventorsAndrea De Rezende Pinho, Willian Luiz Souza Fernandez
Estimating the term…
The present invention addresses to a process for the production of aromatic compounds from streams containing linear chains with 5 to 18 carbon atoms, of fossil or renewable origin, and application in the field of catalytic cracking aiming at a regenerator operation at much lower temperature, between 480° C. and 620° C., preferably the temperature should be between 500° C. and 600° C. The coked catalyst generated by the cracking of light streams with low potential for delta coke generation can have the combustion effected at a lower temperature. The regeneration temperature must be at least 40° C. and at most 100° C. higher than the reaction temperature, keeping the catalyst circulation high to maintain the energy balance in the reaction section. The minimum regeneration temperature can be ensured by installing an air preheating furnace before entering the regenerator and passing through the air distributor inside the regenerator. The used catalyst must contain zeolite with pores of intermediate size. Such conditions greatly favor the production of aromatics and the octane rating of the produced naphtha.
1-A PROCESS FOR OBTAINING AROMATICS from streams with linear chains with 5 to 18 carbon atoms, characterized in that it comprises the following steps:
2-THE PROCESS according to claim 1, characterized in that the pre-heated feed stream (2) contains triglycerides with carbonic chain fatty acids (C9-C18) from plant and/or animal biomass.
3-THE PROCESS according to claim 1, characterized in that the preheated feed stream (2) contains free carbonic chain fatty acids (C9-C18).
4-THE PROCESS according to claim 1, characterized in that the preheated feed stream (2) contains triglycerides with concentrations greater than 65% by mass of fatty acids.
5-THE PROCESS according to claim 2, characterized in that the triglyceride is selected from soybean oil (Glycine max), castor oil (Ricinus communis), cottonseed oil (Gossypium hirsutum or G. barbadenseis), palm oil (Elaies guinensis), pine oil (Tall oil), sunflower oil (Helianthus annuus), jatropha oil (Jatropha Curcas), algae oil, beef tallow (Tallow) and other oils of animal or plant origin or any other triglyceride or reaction product of its transesterification with methanol or ethanol.
6-THE PROCESS according to claim 1, characterized in that the preheated feed stream (2) includes a single oil or a mixture of two or more oils, in any ratios.
7-THE PROCESS according to claim 1, characterized in that the preheated feed stream (2) is a stream of fossil hydrocarbons selected from oil refining streams that have boiling points in the range between 40° C. and 300° C.
8-THE PROCESS according to claim 1, characterized in that the intermediate pore zeolitic catalyst (3) is selected from the types of structure consisting of:
9-THE PROCESS according to claim 1, characterized in that the reactor (5) operates at pressures in the range of 200 to 400 kPa, catalyst-oil ratio in the range of 5 to 30, and contact time in the range between 1.0 and 3.0 seconds.
10-THE PROCESS according to claim 1, characterized in that the hydrocarbon streams (7) obtained in the catalytic cracking reactor (5) are fuel gas, liquefied gas, naphtha and other hydrocarbons.
11-THE PROCESS according to claim 1, characterized in that the fluid catalytic cracking reactor (5) is of the riser type.
12-THE PROCESS according to claim 1, characterized in that the air (13) used in the combustion of the coke deposited on the catalyst is preheated through a furnace (16) to complement the thermal balance, being fed into the regeneration section (12) at temperatures from 400° C. to 550° C.
13-AN AROMATIC STREAM as obtained in the process defined in claim 1, characterized in that it has a typical naphtha distillation range between 30° C. and 220° C.
14-THE AROMATIC STREAM according to claim 13, characterized in that it is 100% of renewable origin.
15-THE AROMATIC STREAM according to claim 14, characterized in that it contains between 70% m/m and 90% m/m of aromatics with a benzene ring in mixture with paraffinic and olefinic compounds.
16-THE AROMATIC STREAM according to claim 14, characterized in that it has at least 100 RON octane rating and 85 MON octane rating.