# US 2023/0264146 A1 · System for the removal of hydrogen/oxygen in a gaseous stream

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- Number: US 2023/0264146 A1
- Document ID: US20230264146A1
- Status: Published application
- Kind: A1
- Application number: 18/043,545
- Filed: 2021-08-31
- Published: 2023-08-24
- Earliest claimed: 2020-09-01
- Applicants: Enapter S.r.l.
- Inventors: Thorben BUSCH; Ralph CALDECOTT; Claudio AIELLO; Sean Crawford CHAPMAN; Antonio FILPI; Jan-Justus SCHMIDT; Max-Istvan SCHMIDT
- Web page: https://patentgrep.com/patent/US20230264146A1

## CPC

- B01D 53/8671: {Removing components of defined structure not provided for in B01D53/8603 - B01D53/8668}
- B01D 53/326: {in electrochemical cells}
- B01D 53/88: Handling or mounting catalysts
- C25B 1/04: by electrolysis of water
- C25B 9/23: comprising ion-exchange membranes in or on which electrode material is embedded
- C25B 9/60: Constructional parts of cells
- C25B 15/023: Measuring, analysing or testing during electrolytic production
- C25B 15/027: Temperature
- C25B 15/029: Concentration
- C25B 15/033: Conductivity
- C25B 15/083: {Separating products}
- C25B 15/085: {Removing impurities}
- B01D 2255/1021: Platinum
- B01D 2255/1023: Palladium
- B01D 2256/12: Oxygen
- B01D 2257/108: Hydrogen
- Y02E 30/30: Nuclear fission reactors
- Y02E 60/36: Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
- Y02E 60/50: Fuel cells
- Y02P 20/133: Renewable energy sources, e.g. sunlight
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)
- C25B: ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR (anodic or cathodic protection C23F13/00; single-crystal growth C30B)
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

According to one embodiment of the present invention there is provided a combiner for the removal of hydrogen/oxygen gas in a gaseous stream, said combiner comprising: a pipe capable of accommodating the flow of a gaseous stream, wherein the pipe is adapted to transmit the gaseous stream to a catalytically active structure (CAS), the CAS having: contact with the substantial majority of the gaseous stream, a housing, and an inlet, said inlet being connected to the pipe, and an outlet, for the removal of the gaseous stream post recombination, and a second pipe connected to the outlet of the CAS for the transmission of the gaseous stream away from the combiner. A second embodiment of the invention sees the CAS housed within an electrochemical cell directly.

## Claims

### Claim 1

A combiner device for, in use, removing a hydrogen contaminant in a principal gas stream comprising predominantly oxygen, or vice versa, with said combiner device comprising:
a catalytically active structure (CAS) comprising a housing having an inlet and an outlet;
a first pipe coupled to the inlet for conveying said principal gas stream into the housing such that it flows from the inlet to the outlet, and an exhaust pipe for conveying said principal gas stream away from said housing;
the CAS further comprising a structural element comprising or including a catalytic material operable to combine hydrogen and oxygen to form water, the structural element being located within the housing, part way between the inlet and the outlet, and extending across a substantial majority of a cross-section thereof, such that, in use, the principal gas stream flows therethrough.

### Claim 2 (depends on 1)

The combiner device of claim 1, wherein the CAS is configured to combine hydrogen and oxygen to form water when the quantity of the contaminant gas in the principal gas stream is above a predetermined amount, the device further comprising supplementing means for increasing an amount of the contaminant gas in the principal gas stream to above said predetermined threshold so as to ensure that combination by the CAS of hydrogen and oxygen in said principal gas stream occurs.

### Claim 3 (depends on 2)

The combiner device of claim 2, wherein said supplementing means comprises either:
means for recirculating the principal gas stream from downstream of the CAS back to upstream thereof, or
a reservoir containing the contaminant gas, the reservoir being adapted to release said contaminant gas under a predetermined condition.

### Claim 4 (depends on 3)

The combiner device of claim 3, wherein the reservoir is a metal hydride.

### Claim 5 (depends on 1)

The combiner device of claim 1, configured to simultaneously recombine the contaminant gas with the principal gas to form water, and detect the presence of said contaminant gas.

### Claim 6 (depends on 5)

The combiner device of claim 5, further comprising one or more of the following sensors is used for the detection of the contaminant gas:
a humidity sensor,
a temperature sensor,
a thermal conductivity sensor.

### Claim 7 (depends on 6)

The combiner device of claim 6, wherein the one or more sensors is coupled to computing means for determining the amount of a contaminant gas present in the principal gas stream.

### Claim 8 (depends on 1)

The combiner device of claim 1 coupled with a demister, the CAS being either:
upstream of a demister pad,
downstream of a demister pad, or
combined with a demister pad.

### Claim 9 (depends on 8)

The combiner device of claim 8, wherein the demister additionally acts as a flame arrestor, preferably wherein the demister is attached to the inlet.

### Claim 10 (depends on 8)

The combiner device of claim 8, wherein the demister is a microporous material, preferably one of: a foam or sintered material, preferably a foam or sintered metal; a ceramic, preferably a sintered ceramic; or a carbon based material.

### Claim 11 (depends on 1)

The combiner device of claim 1, further comprising means for the removal and optional recycling of the generated liquid.

### Claim 12 (depends on 1)

The combiner device of claim 1, wherein the structural element comprises a backbone of: carbon black, metal oxides including ceramics, a polymeric film, metal foam, zeolitic structures, or metal organic frameworks.

### Claim 13 (depends on 1)

The combiner device of claim 1, further comprising means for the introduction of ambient air to the principal gas stream.

### Claim 14 (depends on 1)

The combiner device of claim 1, wherein the catalytic material is platinum, palladium or an alloy thereof.

### Claim 15 (depends on 1)

The combiner device of claim 1, wherein the catalytic material is a non-PGM material including metal alloys, ceramics, chalcogenides, pnictogenides, organometallics, or other metal complexes.

### Claim 16

An electrochemical cell comprising:
a membrane electrode assembly (MEA) wherein the MEA comprises:
an anode layer, a cathode layer and an ion exchange membrane situated therebetween;
an anodic compartment adapted to operate at a first pressure,
a cathodic compartment adapted to operate at a second pressure, and
an electrically insulated catalytically active structure (CAS), wherein the CAS is:
situated in the compartment with a relatively lower pressure, and
extending across a substantial majority of the cross-section said compartment, such that, in use, the principal gas stream flows therethrough.

### Claim 17 (depends on 16)

The electrochemical cell of claim 16, comprising any one of: an electrolyser, AEM or PEM, a fuel cell, reversible fuel cell, electrochemical compressor, or an AEM electrolyser with a dry cathode preferably wherein the AEM electrolyser with the dry cathode is configured to operate with the dry cathode at an elevated pressure.

### Claim at position 18

18-19. (canceled)

### Claim 20 (depends on 16)

The electrochemical cell of claim 16, wherein the CAS is insulated from other components of the electrochemical cell by an ionomer thin film or ultra-thin membrane on one or both sides, or a combination thereof.

### Claim 21 (depends on 1)

A method, in a system that utilizes a principal gas stream comprising hydrogen and oxygen, for removing contaminant hydrogen from a principal gas stream comprising predominantly oxygen, or vice versa, the method comprising providing, in said system, a combiner device according to claim 1 such that said principal gas stream flows through the housing from the inlet to the outlet.

### Claim 22 (depends on 21)

A method according to claim 21, wherein:
said system comprises an electrochemical cell; and/or
said principal gas stream comprises between 0.4 and 20% contaminant gas; and/or
the operating temperature is between 20 and 100° C.

### Claim at position 22

23-24. (canceled)