# US 2023/0264115 A1 · Method for separating water and contaminants from valuable or harmful liquids > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 2023/0264115 A1 - Document ID: US20230264115A1 - Status: Published application - Kind: A1 - Application number: 18/020,263 - Filed: 2021-08-13 - Published: 2023-08-24 - Earliest claimed: 2020-08-14 - Inventors: Craig Nazzer - Web page: https://patentgrep.com/patent/US20230264115A1 ## CPC - B01D 3/06: Flash distillation - B01D 1/14: with heated gases or vapours {or liquids} in contact with the liquid - B01D 3/10: Vacuum distillation (B01D3/12 takes precedence) - B01D 5/006: {with evaporation or distillation} - C02F 1/06: Flash evaporation - C02F 1/004: {using large scale industrial sized filters} - C02F 1/38: by centrifugal separation - C02F 1/66: by neutralisation; pH adjustment (for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58) - C02F 2101/10: Inorganic compounds - C02F 2101/20: Heavy metals or heavy metal compounds - C02F 2101/325: {Emulsions} - C02F 2101/34: containing oxygen - C02F 2101/38: containing nitrogen - C02F 2303/06: Sludge reduction, e.g. by lysis - C02F 2303/08: Corrosion inhibition - C02F 2303/22: Eliminating or preventing deposits, scale removal, scale prevention (C02F1/042, C02F1/4602, C02F5/00 take precedence) - B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28) - C02F: TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE (separation in general B01D; special arrangements on waterborne vessels of installations for treating water, waste water or sewage, e.g. for producing fresh water, B63J; adding materials to water to prevent corrosion C23F; treating radioactively-contaminated liquids G21F9/04; regeneration of reactants for recirculation into processes, see the relevant places for the processes) ## Abstract The present disclosure is a method of removing water and contaminants from an aqueous feed stream comprising a water soluble process liquid. Embodiments of the method may include splitting the method into stages, vaporising the process liquid by direct contact with a heated heating fluid, removing precipitated contaminants by chemical means, and treating the heating fluid to maintain or enhance its properties. ## Claims ### Claim 1 A method of removing contaminants, including dissolved contaminants, from a feed stream, said feed stream comprising water and said contaminants and a process liquid that is water soluble and less volatile than water, said method comprising the following steps: heating a heating fluid comprised of components that are immiscible with a salt solvent and less volatile than the process liquid to produce a heated heating fluid; bringing at least a portion of the feed stream into contact with at least a portion of the heated heating fluid at one or more places that are upstream of and/or within a flash separator to vaporise at least a portion of the process liquid thereby causing at least a portion of the dissolved contaminants to form precipitated solid matter; enabling at least a portion of the heating fluid to mix with at least a portion of the precipitated solid matter thereby producing a depleted mixture that comprises at least a portion of the heating fluid and at least a portion of the precipitated solid matter; and bringing the salt solvent into contact with at least a portion of the depleted mixture whereby said salt solvent dissolves at least a portion of the precipitated solid matter, to create a waste solution that comprises at least a portion of the dissolved contaminants. ### Claim 2 A method of removing contaminants, including dissolved contaminants, from a feed stream, said feed stream comprising water and said contaminants and a process liquid that is water soluble and less volatile than water, said method comprising the following steps: applying a concentration process to remove water from at least a portion of the feed stream to produce a Stage A output stream having a concentration of process liquid that is higher than that of the feed stream; heating a heating fluid comprised of components that are immiscible with a salt solvent and less volatile than the process liquid to produce a heated heating fluid; bringing at least a portion of the Stage A output stream into contact with at least a portion of the heated heating fluid at one or more places that are upstream of and/or within a flash separator to vaporise at least a portion of the process liquid thereby causing at least a portion of the dissolved contaminants to form precipitated solid matter; enabling at least a portion of the heating fluid to mix with at least a portion of the precipitated solid matter thereby producing a depleted mixture that comprises at least a portion of the heating fluid and at least a portion of the precipitated solid matter; and bringing the salt solvent into contact with at least a portion of the depleted mixture, whereby said salt solvent dissolves at least a portion of the precipitated solid matter to create a waste solution that comprises at least a portion of the dissolved contaminants. ### Claim 3 A method of removing contaminants, including dissolved contaminants, from a feed stream, said feed stream comprising water and said contaminants and a process liquid that is water soluble and less volatile than water, said method comprising the following steps: heating a concentrated process liquid to produce heated concentrated process liquid; bringing at least a portion of the feed stream into contact with at least a portion of the heated concentrated process liquid at one or more places that are upstream of and/or within a Stage B separation vessel to vaporise a portion of the process liquid thereby producing an unvaporised liquid that comprises at least a portion of the dissolved contaminants; enabling at least a portion of the unvaporised liquid to mix with at least a portion of the concentrated process liquid thereby producing a Stage B to C stream that comprises at least a portion of the process liquid and at least a portion of the dissolved contaminants; heating a heating fluid comprised of components that are immiscible with a salt solvent and less volatile than the process liquid to produce a heated heating fluid; bringing at least a portion of the Stage B to C stream into contact with at least a portion of the heated heating fluid at one or more places that are upstream of and/or within a flash separator to vaporise at least a portion of the process liquid thereby causing at least a portion of the dissolved contaminants to form precipitated solid matter; enabling at least a portion of the heating fluid to mix with at least a portion of the precipitated solid matter thereby producing a depleted mixture that comprises at least a portion of the heating fluid and at least a portion of the precipitated solid matter; and bringing the salt solvent into contact with at least a portion of the depleted mixture whereby said salt solvent dissolves at least a portion of the precipitated solid matter, thereby creating a waste solution that comprises at least a portion of the dissolved contaminants. ### Claim 4 (depends on 2) The method as claimed in claim 2 wherein the concentration process comprises heating the feed stream to a temperature sufficient to vaporise and remove at least a portion of the water. ### Claim 5 (depends on 3) The method as claimed in claim 3 further including the step of regulating the flow of the Stage B to C stream to limit the accumulation of at least a portion of the dissolved contaminants in the Stage B separation vessel. ### Claim 6 (depends on 1) The method as claimed in claim 1 further including the step of applying one or more heating fluid treatment means to decontaminate at least a portion of the heating fluid. ### Claim 7 (depends on 1) The method as claimed in claim 1 further including the step of applying one or more heating fluid treatment means to at least a portion of the heating fluid to modify one or more properties of the heating fluid, including but not limited to density, vapour pressure, viscosity, thermal stability, pH, solubility, heat capacity, thermal conductivity, corrosivity, toxicity, and flammability. ### Claim 8 (depends on 6) The method as claimed in claim 6 wherein the one or more heating fluid treatment means include adding one or more substances and mixing said added substances with at least a portion of the heating fluid to achieve any one or more of the following effects: to cause a reaction with carbonate and/or bicarbonate contaminants thereby producing water and/or carbon dioxide; to reduce the oxygen content of the heating fluid; to remove and/or dissolve and/or destroy asphaltenes, resins, gums and/or sludges; to prevent or inhibit the formation of, or enable the removal of, scale or fouling deposits on metal surfaces; to break-down, suppress, or inhibit the formation of, emulsions or foam; to reduce the cloud point and/or freezing point of liquid contaminants; to neutralise acids and/or increase alkalinity and/or inhibit corrosion; and to react with dissolved contaminants and cause precipitation of solid matter that can be removed by mechanical means of separation. ### Claim 9 (depends on 6) The method as claimed in claim 6 wherein the one or more heating fluid treatment means include heating at least a portion of the heating fluid to vaporise and thereby remove at least a portion of the liquid contaminants. ### Claim 10 (depends on 6) The method as claimed in claim 6 wherein the one or more heating fluid treatment means include removing contaminating particles of solid matter from at least a portion of the heating fluid by mechanical means of separation including but not limited to any one or more of: centrifuging, settling, clarifying, filtering, and hydrocycloning. ### Claim 11 (depends on 6) The method as claimed in claim 6 wherein the one or more heating fluid treatment means include adding one or more substances and mixing said added substances with at least a portion of the heating fluid to cause a reaction that converts at least a portion of the organic salt contaminants into volatile organic acids and vaporising at least a portion of said volatile organic acids. ### Claim 12 (depends on 7) The method as claimed in claim 7 wherein the one or more heating fluid treatment means include adding one or more substances and mixing said added substances with at least a portion of the heating fluid to modify one or more properties of the heating fluid, including but not limited to density, vapour pressure, viscosity, thermal stability, pH, solubility, heat capacity, thermal conductivity, corrosivity, toxicity, and flammability. ### Claim 13 (depends on 1) The method as claimed in claim 1 wherein the heating fluid comprises components that are immiscible with the process liquid. ### Claim 14 (canceled) ### Claim 15 (depends on 1) The method as claimed in claim 1 wherein the process liquid comprises any one or more liquids selected from the group comprising: mono-ethylene glycol; diethylene glycol; triethylene glycol; and amines. ### Claim 16 (depends on 1) The method as claimed in claim 1 wherein the dissolved contaminants comprise any one or more of: monovalent salts including sodium chloride; divalent ions including calcium; and organic acid salts including acetate. ### Claim 17 (depends on 1) The method as claimed in claim 1 wherein at least all but a negligible remnant of the process liquid that contacts the heated heating fluid is vaporised. ### Claim at position 18 18-19. (canceled) ### Claim 20 (depends on 1) The method as claimed in claim 1 wherein the heating fluid comprises one or more liquid components selected from any of the following groups: oils; fatty acids; heat transfer fluids; liquid metals; ionic liquids; and deep eutectic solvents. ### Claim 21 (depends on 1) The method as claimed in claim 1 wherein at least a portion of the salt solvent enters the flash separator and mixes with depleted mixture and dissolves at least a portion of the precipitated solid matter thereby creating a waste solution that comprises at least a portion of the dissolved contaminants. ### Claim 22 (depends on 1) The method as claimed in claim 1 wherein at least a portion of the depleted mixture moves into a solvent wash system wherein at least a portion of the precipitated solid matter dissolves in at least a portion of the salt solvent, thereby creating a waste solution that comprises at least a portion of the dissolved contaminants. ### Claim 23 (canceled)