Method for producing optically active compound
AssigneeSumitomo Chemical Company, Limited
InventorsLeopold Mpaka LUTETE, Koji HAGIYA
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AssigneeSumitomo Chemical Company, Limited
InventorsLeopold Mpaka LUTETE, Koji HAGIYA
Estimating the term…
An object of the present invention is to provide a further more effective process for preparing a certain optically active compound including an optically active 1-acetyl-2,2,4-trimethyl-1,2,3,4-tetrahydroquinoline. The present invention provides a process for an optically active compound represented by formula (3) (wherein R5 represents a hydrogen atom etc., R6 and R7 each independently represents a hydrogen atom, etc., R8 represents a C1-C6 alkyl group, and R9, R10 and R11 each independently represents a hydrogen atom, etc. The carbon atom with a symbol of the asterisked “*” represents an asymmetric carbon atom), which comprises a reacting a compound represented by formula (2) (wherein R5, R6, R7, R8, R9, R10, and R11 has the same meanings as the above) with hydrogen in the presence of asymmetric cobalt complex.
A process for preparing an optically active compound represented by formula (3):
An asymmetric cobalt complex represented by formula (1′):
A hydride complex which is obtained by reacting an asymmetric cobalt complex represented by formula (1′):
An alkyl complex which is obtained by reacting an asymmetric cobalt complex represented by formula (1′):
Dependencies are inferred from the claim text.