Crosslinked copolymer, preparation method and printing paste comprising said copolymer
AssigneeS.P.C.M. SA
InventorsFrédéric BLONDEL, Hadrien CHOLLAT-NAMY, Rémi THIBAL
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Abstract
The present invention relates to a crosslinked copolymer obtained by precipitation polymerization of at least one monomer comprising at least one carboxylic acid function, at least one hydrophobic monomer, and at least one crosslinking agent. The copolymer is mainly characterized in that 30 mol % to 90 mol % of the carboxylic acid functions are in salified form prior to the precipitation polymerization, the solvent used for the precipitation polymerization comprises at least one alcohol comprising 1 to 4 carbon atoms, and the copolymer is obtained in the absence of water-soluble non-ionic monomers.
Claims14
A crosslinked copolymer obtained by precipitation polymerization of at least:
- 60 mol % to 99.8 mol % of at least one anionic monomer comprising at least one carboxylic acid function,
- 0.1 mol % to 20 mol % of at least one hydrophobic monomer of formula (I),
- wherein:
- R1, R2 and R3 are, independently of each other, a hydrogen atom or a methyl group,
- X is a group C(═O)—O—Y or CH2—C(═O)—O—Y,
- wherein Y is a hydrocarbon group, saturated or unsaturated, wherein Y is linear, branched, cyclic, or aromatic, wherein Y comprises 3 to 30 carbon atoms, and from 0 to 4 heteroatoms selected from the group consisting of O, N, and S,
- 1*10−9 mol % to 2 mol % of at least one crosslinking agent,
- the crosslinked copolymer being having 30 mol % to 90 mol % of the carboxylic acid functions of the anionic monomer in salified form prior to the precipitation polymerization,
- the solvent used for the precipitation polymerization comprising at least one alcohol comprising 1 to 4 carbon atoms, and
- the copolymer being obtained in the absence of water-soluble non-ionic monomers.
Dependencies are inferred from the claim text.