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US 2023/0227316 A1Published application
Circular carbon process
AssigneeBASF SE
InventorsAndreas Bode, Dieter Flick, Andreas Spiegel
Life of this patent
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Abstract
A circular carbon process involves: a) reacting hydrogen and carbon monoxide to produce methane and water, b) decomposing methane into carbon and hydrogen, and c) using carbon as reducing agent and/or using carbon in a carbon-containing material as reducing agent, in a chemical process to produce carbon monoxide and a reduced substance. The methane produced in a) is used in b), the carbon produced in b) is used in c), and carbon monoxide produced in c) is used in a).
Claims14
1-14. (canceled)
15:
- A circular carbon process, comprising:
- a) reacting hydrogen and carbon monoxide to produce methane and water,
- b) decomposing the methane into carbon and hydrogen, and
- c) producing carbon monoxide and a reduced substance in a chemical process, wherein the carbon is used as reducing agent and/or the carbon is used in a carbon-containing material as reducing agent,
- wherein the methane produced in a) is used in b), wherein the carbon produced in b) is used in c), and wherein the carbon monoxide produced in the c) is used in a).
2 more elements
16:
- The process according to claim 15, wherein the chemical process in c) is a reduction of calcium oxide to calcium carbide via oxidizing of carbon to carbon monoxide, a reduction of silicon oxide to silicon or silicon carbide via oxidizing of carbon to carbon monoxide, a reduction of tin oxide to tin via oxidizing of carbon to carbon monoxide, a reduction of chromium oxide to chromium via oxidizing of carbon to carbon monoxide, a reduction of manganese oxide to manganese via oxidizing of carbon to carbon monoxide, and/or a reduction of calcium phosphate to phosphorus via oxidizing of carbon to carbon monoxide.
17:
- The process according to claim 15, wherein reaction heat from an exothermic methanation reaction in a) is used in c) for separation or purification of the carbon monoxide.
18:
- The process according to claim 15, wherein the hydrogen produced in b) is used in a).
19:
- The process according to claim 15, further comprising:
- d) producing hydrogen, which is used in a).
20:
- The process according to claim 19, wherein the hydrogen is produced via water electrolysis or steam methane reforming with or without carbon capture and storage in d).
21:
- The process according to claim 20, wherein the water produced in a) is used for the water electrolysis in d).
22:
- The process according to claim 15, wherein at least one stream from outside the circular process comprising H2, CH4, CO, CO2 and/or C is introduced into the circular process, or
- wherein at least one stream comprising H2, CH4, CO, CO2 and/or C is extracted from the circular process to supply external demand and/or for storage of carbon.
23:
- The process according to claim 22, wherein biogas is used as an additional methane source.
24:
- The process according to claim 15, wherein a) and b) are both conducted in a pressure range from 1 to 30 bar.
25:
- A joint plant for a circular carbon process, comprising:
- a plant using carbon as reduction agent in a chemical process including a CO separation and conditioning,
- a gas pipeline for carbon oxide transport from the plant using carbon as reducing agent to a methanation plant,
- the methanation plant downstream reacting hydrogen and carbon monoxide to produce methane and water,
- a gas pipeline feeding a methane-rich mixture from the methanation plant to a pyrolysis plant,
- the pyrolysis plant downstream of the methanation plant decomposing methane to solid carbon and hydrogen, and
- a carbon solids transport device between the pyrolysis plant and the plant using carbon as reducing agent.
4 more elements
26:
- The plant according to claim 25, further comprising:
- an electrolysis plant, downstream of the methanation plant, separating water into oxygen and hydrogen.
27:
- The plant according to claim 26, further comprising:
- a gas pipeline for hydrogen transport from the pyrolysis plant and/or the electrolysis plant to the methanation plant,
- a pipeline for liquid water transport from the methanation plant to the electrolysis plant, and
- a transport pipeline or solids transport device for C supply from external sources to the plant using carbon as reducing agent.
1 more element