Method for producing cyclic olefin compound
AssigneeMitsui Chemicals, Inc.
InventorsHaruyuki MAKIO, Takaaki YANO, Akira MATSUURA
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Abstract
Provided is a method for producing a cyclic olefin compound, including a step of producing a cyclic olefin compound by acting a divalent nickel complex represented by General Formula (1) to decarbonylate and decarboxylate an alicyclic dicarboxylic acid anhydride, in which the divalent nickel complex includes at least one specific anionic ligand Y. Ni(Y)m(L)n (1) (here, Ni is divalent nickel, Y is an anionic monodentate or polydentate ligand and has at least one Ni-E covalent bond, E is a heteroatom or a π-bonding group, m is 1 or 2, L is a neutral ligand, and n is a real number of 0 to 6)
Claims17
A method for producing a cyclic olefin compound, comprising:
- a step of producing a cyclic olefin compound by acting a divalent nickel complex represented by General Formula (1) to decarbonylate and decarboxylate an alicyclic dicarboxylic acid anhydride,
- wherein the divalent nickel complex includes at least one anionic ligand Y represented by any of General Formulae (2) to (7), (X1), and (Y1),
- Ni(Y)m(L)n (1)
- wherein Ni is divalent nickel, Y is an anionic monodentate or polydentate ligand and has at least one Ni-E covalent bond, E is a heteroatom or a π-bonding group, m is 1 or 2, L is a neutral ligand, and n is a real number of 0 to 6,
- wherein R1 is a hydrogen atom or a hydrocarbon group which may have a substituent,
- wherein R2 is a divalent hydrocarbon group which may have a substituent,
- wherein R3, R4, and R5 are hydrocarbon groups which may have a substituent, R3 and R5 or R4 and R5 may be bonded to each other to form a ring, and R3, R4, and R5 may be hydrogen atoms,
- wherein R6 is a divalent hydrocarbon group which may have a substituent, R7 is a hydrogen atom, a hydrocarbon group which may have a substituent, or an oxo group, and in a case where R7 is a hydrocarbon group, R7 may be bonded to R6 to form a ring,
- wherein Z′ is halogen or OH,
- wherein Ox is an oxoacid selected from NO3−, CO32−, and PO43−,
- wherein R1′, R2′, R3′, R4′, and R5′ are each independently a hydrogen atom or a hydrocarbon group which may have a substituent,
- wherein R6′, R7′, and R8′ are each independently a hydrogen atom or a hydrocarbon group which may have a substituent.
Dependencies are inferred from the claim text.