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US 2023/0146532 A1Published application
Light emitting device
AssigneeSamsung Display Co., Ltd.
InventorsMUN-KI SIM, TAEIL KIM, SUN YOUNG PAK, JUNHA PARK, JANG YEOL BAEK, Kyoung SUNWOO, CHANSEOK OH, MINJUNG JUNG
Life of this patent
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Abstract
A light emitting device that includes a first electrode, a second electrode opposite to the first electrode, and an emission layer between the first electrode and the second electrode is provided. The emission layer includes a first compound, and at least one of a second compound, a third compound, or a fourth compound. Improved emission efficiency properties are obtained.
Claims20
A light emitting device, comprising:
- a first electrode;
- a second electrode opposite to the first electrode;
- and
- an emission layer between the first electrode and the second electrode,
- wherein the emission layer comprises:
- a first compound represented by Formula 1;
- and
- at least one of a second compound represented by Formula H-1, a third compound represented by Formula H-2, or a fourth compound represented by Formula D-2:
- in Formula 1,
- X1 and X2 are each independently NR6, O, or S, where at least one of X1 or X2 is NR6,
- Y is NR7, O, or S,
- Z is a substituted or unsubstituted t-butyl group, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms,
- R1 to R7 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms, and/or combined with an adjacent group to form a ring,
- n1 is an integer of 0 to 2,
- n2 and n5 are each independently an integer of 0 to 4, and
- n3 and n4 are each independently an integer of 0 to 3,
- in Formula H-1,
- L1 is a direct linkage, a substituted or unsubstituted arylene group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group of 2 to 30 ring-forming carbon atoms,
- Ar1 is a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms,
- R8 and R9 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms, and
- n6 and n7 are each independently an integer of 0 to 4,
- in Formula H-2,
- at least one of Z1 to Z3 is N, and the Z1, Z2 and Z3 that are not N are CR13, and
- R10 to R13 are each independently a hydrogen atom, a deuterium atom, a cyano group, a substituted or unsubstituted silyl group, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms,
- in Formula D-2,
- Q1 to Q4 are each independently C or N,
- C1 to C4 are each independently a substituted or unsubstituted hydrocarbon ring of 5 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heterocycle of 2 to 30 ring-forming carbon atoms,
- L21 to L23 are each independently a direct linkage, *—O—*, *—S—*,
- a substituted or unsubstituted divalent alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted arylene group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group of 2 to 30 ring-forming carbon atoms,
- b1 to b3 are each independently 0 or 1,
- R21 to R26 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 1 to 30 ring-forming carbon atoms, and/or combined with an adjacent group to form a ring, and
- d1 to d4 are each independently an integer of 0 to 4.
29 more elements
A light emitting device, comprising:
- a first electrode;
- a hole transport region on the first electrode;
- an emission layer on the hole transport region;
- an electron transport region on the emission layer;
- and
- a second electrode on the electron transport region,
- wherein the emission layer comprises:
- a first compound represented by Formula 1;
- and
- the hole transport region comprises a hole transport compound represented by Formula H-a:
- in Formula 1,
- X1 and X2 are each independently NR6, O, or S, where at least one among X1 and X2 is NR6,
- Y is NR7, O, or S,
- Z is a substituted or unsubstituted t-butyl group, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms,
- R1 to R7 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted amine group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms, and/or combined with an adjacent group to form a ring,
- n1 is an integer of 0 to 2,
- n2 and n5 are each independently an integer of 0 to 4, and
- n3 and n4 are each independently an integer of 0 to 3,
- in Formula H-a,
- Ya and Yb are each independently CReRf, NRg, O, or S,
- Ara is a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms,
- L1 and L2 are each independently a direct linkage, a substituted or unsubstituted arylene group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group of 2 to 30 ring-forming carbon atoms,
- Ra to Rg are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted amine group, a substituted or unsubstituted thio group, a substituted or unsubstituted oxy group, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms, and/or combined with an adjacent group to form a ring,
- na and nd are each independently an integer of 0 to 4, and
- nb and nc are each independently an integer of 0 to 3.
22 more elements
Dependencies are inferred from the claim text.