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US 2023/0145772 A1Published application
Polyester Carbonates Consisting of Different Diols in a Defined Ratio
AssigneeCovestro Deutschland AG
InventorsAlexander Meyer, Thomas Pfingst, Lukas Fabian Schulz
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Abstract
The present invention relates to a process for preparing a polyester carbonate on the basis of cycloaliphatic diacids and at least one 1,4:3,6-dianhydrohexitol and at least one further aliphatic dihydroxy compound, to a polyester carbonate and to a molding compound and a molded product containing the polyester carbonate. The polyester carbonates according to the invention are characterized by good mechanical properties and molecular weights.
Claims19
A polyestercarbonate, comprising the structural formula (1)
- in which
- A independently per repeating unit represents at least either structural unit (A) or structural unit (B), where
- (A) represents chemical formula (2)
- and
- (B) represents chemical formula (3)
- *—X—* (3),
- where x represents a branched alkylene group having 4 to 20 carbon atoms, which may optionally be interrupted by at least one heteroatom, or a cycloalkylene group comprising at least one branch, wherein the cycloalkylene group has 4 to 20 carbon atoms, which may optionally be interrupted by at least one heteroatom,
- y each independently represents chemical formula (IIIa) or (IIIb)
- in which B each independently represents a CH2 group or a heteroatom selected from the group consisting of O and S,
- R1 each independently represents a single bond or an alkylene group having 1 to 10 carbon atoms,
- n is a number between 0 and 3, and
- 0<x<1,
- where the * in each case indicate the position at which the chemical formulae are incorporated into the polyestercarbonate,
- wherein the polyestercarbonate comprises
- 98 mol % to 75 mol % of structural unit (A) and
- 2 mol % to 25 mol % of structural unit (B),
- based in each case on the sum of the structural units (A) and (B), and
- wherein the polyestercarbonate has a relative solution viscosity, measured in dichloromethane at a concentration of 5 g/l at 25° C. with an Ubbelohde viscometer, of 1.20 to 1.70.
15 more elements
Dependencies are inferred from the claim text.