Low dk copper clad laminate compositions

The matrix formulation of claim 12, wherein the diamine is selected from the group consisting of:

• 4,4′-methylenebis(2,6-diethylaniline);
• tricyclodecane diamine (TCD-diamine);
• Bisaniline-P;
• 2.2-bis[4-(4-aminophenoxy)phenyl] hexafluoropropane;
• 1,10-diaminodecane;
• 1,12-diaminododecane;
• PRIAMINE™ 1075 (dimer diamine):
• PRIAMINE™ 1074 (dimer diamine);
• dimer diamine;
• hydrogenated dimer diamine;
• 1,2-diamino-2-methylpropane;
• 1,2-diaminocyclohexane;
• 1,2-diaminopropane;
• 1,3-diaminopropane;
• 1,4-diaminobutane;
• 1,5-diaminopentane;
• 1,7-diaminoheptane;
• 1,8-diaminomenthane;
• 1,8-diaminooctane;
• 1,9-diaminononane;
• 3,3′-diamino-N-methyldipropylamine;
• diaminomaleonitrile;
• 1,3-diaminopentane;
• 9,10-diaminophenanthrene;
• 4,4′-diaminooctafluorobiphenyl;
• 3,5-diaminobenzoic acid;
• 3,7-diamino-2-methoxyfluorene;
• 4,4′-diaminobenzophenone;
• 3,4-diaminobenzophenone;
• 3,4-diaminotoluene;
• 2,6-diaminoanthroquinone;
• 2,6-diaminotoluene;
• 2,3-diaminotoluene;
• 1,8-diaminonaphthalene;
• 2,4-diaminotoluene;
• 2,5-diaminotoluene;
• 1,4-diaminoanthroquinone;
• 1,5-diaminoanthroquinone;
• 1,5-diaminonaphthalene;
• 1,2-diaminoanthroquinone;
• 2,4-cumenediamine;
• 1,3-bisaminomethylbenzene;
• 1,3-bisaminomethylcyclohexane;
• 2-chloro-1,4-diaminobenzene;
• 1,4-diamino-2,5-dichlorobenzene;
• 1,4-diamino-2,5-dimethylbenzene;
• 4,4′-diamino-2,2′-bistrifluoromethylbiphenyl;
• bis(amino-3-chlorophenyl)ethane;
• bis(4-amino-3,5-dimethylphenyl)methane;
• bis(4-amino-3,5-diisopropylphenyl)methane;
• bis(4-amino-3,5-methyl-isopropylphenyl)methane;
• bis(4-amino-3,5-diethylphenyl)methane;
• bis(4-amino-3-ethylphenyl)methane;
• diaminofluorene;
• 4,4′-(9-Fluorenylidene)dianiline;
• diaminobenzoic acid;
• 2,3-diaminonaphthalene;
• 2,3-diaminophenol;
• -5-methylphenyl)methane;
• bis(4-amino-3-methylphenyl)methane;
• bis(4-amino-3-ethylphenyl)methane;
• 4,4′-diaminophenylsulfone;
• 3,3′-diaminophenylsulfone;
• 2,2-bis(4,-(4-aminophenoxy)phenyl)sulfone;
• 2,2-bis(4-(3-aminophenoxy)phenyl)sulfone;
• 4,4′-oxydianiline;
• 4,4′-diaminodiphenyl sulfide;
• 3,4′-oxydianiline;
• 2,2-bis(4-(4-aminophenoxy)phenyl)propane;
• 1,3-bis(4-aminophenoxy)benzene;
• 4,4′-bis(4-aminophenoxy)biphenyl;
• 4,4′-diamino-3,3′-dihydroxybiphenyl;
• 4,4′-diamino-3,3′-dimethylbiphenyl;
• 4,4′-diamino-3,3′-dimethoxybiphenyl;
• Bisaniline M;
• Bisaniline P;
• 9,9-bis(4-aminophenyl)fluorene;
• o-tolidine sulfone;
• methylene bis(anthranilic acid);
• 1,3-bis(4-aminophenoxy)-2,2-dimethylpropane;
• 1,3-bis(4-aminophenoxy)propane;
• 1,4-bis(4-aminophenoxy)butane;
• 1,5-bis(4-aminophenoxy)butane;
• 2,3,5,6-tetramethyl-1,4-phenylenediamine;
• 3,3′, 5,5′-tetramehylbenzidine;
• 4,4′-diaminobenzanilide;
• 2,2-bis(4-aminophenyl)hexafluoropropane;
• polyoxyalkylenediamines;
• 1,3-cyclohexanebis(methylamine);
• m-xylylenediamine;
• p-xylylenediamine;
• bis(4-amino-3-methylcyclohexyl)methane;
• 1,2-bis(2-aminoethoxy)ethane;
• 3(4),8(9)-bis(aminomethyl)tricyclo(5.2.1.02,6)decane;
• and combinations thereof

The matrix formulation of claim 12, wherein the anhydride is selected from the group consisting of:

• Bisphenol-A-dianhydride;
• biphenyl tetracarboxylic dianhydride;
• pyromellitic dianhydride;
• maleic anhydride;
• polybutadiene-graft-maleic anhydride;
• polyethylene-graft-maleic anhydride;
• polyethylene-alt-maleic anhydride;
• polymaleic anhydride-alt-1-octadecene;
• polypropylene-graft-maleic anhydride;
• poly(styrene-co-maleic anhydride);
• maleic anhydride;
• succinic anhydride;
• 1,2,3,4-cyclobutanetetracarboxylic dianhydride;
• 1,4,5,8-naphthalenetetracarboxylic dianhydride;
• 3,4,9,10-perylenentetracarboxylic dianhydride;
• bicyclo(2.2.2)oct-7-ene-2,3,5,6-tetracarboxylic dianhydride;
• diethylenetriaminepentaacetic dianhydride;
• ethylenediaminetetraacetic dianhydride;
• 3,3′, 4,4′-benzophenone tetracarboxylic dianhydride;
• 3,3′, 4,4′-biphenyl tetracarboxylic dianhydride;
• 4,4′-oxydiphthalic anhydride;
• 3,3′, 4,4′-diphenylsulfone tetracarboxylic dianhydride;
• 2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride;
• 4,4′-bisphenol A diphthalic anhydride;
• 5-(2,5-dioxytetrahydro)-3-methyl-3-cyclohexene-1,2-dicarboxylic anhydride;
• ethylene glycol bis(trimellitic anhydride);
• hydroquinone diphthalic anhydride;
• allyl nadic anhydride;
• 2-octen-1-ylsuccinic anhydride;
• phthalic anhydride;
• 1,2,3,6-tetrahydrophthalic anhydride;
• 3,4,5,6-tetrahydrophthalic anhydride;
• 1,8-naphthalic anhydride;
• glutaric anhydride;
• dodecenylsuccinic anhydride;
• hexadecenylsuccinic anhydride;
• hexahydrophthalic anhydride;
• methylhexahydrophthalic anhydride;
• tetradecenylsuccinic anhydride and combinations thereof.