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US 2023/0143596 A1Published application
Pesticidally active diazine-bisamide compounds
AssigneeSyngenta Crop Protection AG
InventorsMangala PHADTE, Sachin Balu CHAVAN, Daniel EMERY, Roger Graham HALL, Viorel Andrei IOSUB, André JEANGUENAT, Jagadeesh Prathap KILARU, Camille LE CHAPELAIN, Thomas PITTERNA, Guruprasad Narashimh SAWANT
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Abstract
Compounds of formula (I), wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, can be used as insecticides.
Claims18
A compound of the formula I
- wherein
- R1 is hydrogen, C1-C6alkyl, C1-C6cyanoalkyl, aminocarbonylC1-C6alkyl, hydroxycarbonylC1-C6alkyl, C1-C6nitroalkyl, trimethylsilaneC1-C6alkyl, C1-C3alkoxy-C1-C6alkyl, C1-C6haloalkyl, C2-C6alkenyl, C2-C6haloalkenyl, C2-C6alkynyl, C2-C6haloalkynyl, C3-C4cycloalkylC1-C2alkyl-, C3-C4cycloalkylC1-C2alkyl-wherein the C3-C4cycloalkyl group is substituted with 1 or 2 halogen atoms, oxetan-3-yl-CH2—, C1-C6alkylcarbonyl, C1-C6alkoxycarbonyl, phenyloxycarbonyl, benzyloxycarbonyl, benzyl or benzyl substituted with 1 to 3 substituents independently selected from halogen, C1-C6alkoxy and C1-C6haloalkyl;
- R2a is hydrogen, C1-C3alkyl, C1-C3haloalkyl, C1-C3haloalkylsuflanyl, C1-C3alkoxy, C1-C3haloalkoxy, halogen, NO2, SF5, CN, C(O)NH2, C(O)OH, C(S)NH2, C3-C6cycloalkyl, C3-C6cycloalkyl substituted with one to three substituents independently selected from Rx, C3-C6cycloalkylcarbonyl, phenyl, phenyl substituted with one to three substituents independently selected from Rx, heteroaryl, heteroaryl substituted with one to three substituents independently selected from Rx, OR6, piperidin-2-one-1-yl, piperidin-2-one-1-yl substituted with one to two substituents independently selected from Rx, pyridin-2-one-1-yl, pyridin-2-one-1-yl substituted with one to two substituents independently selected from Rx, azetidin-1-yl, azetidin-1-yl substituted with one to two substituents independently selected from Rx pyrrolidin-1-yl, pyrrolidin-1-yl substituted with one to two substituents independently selected from Rx, C3-C6cycloalkylC1-C4alkyl, C3-C6cycloalkylC1-C4alkyl substituted with one to two substituents independently selected from Rz;
- C3-C6cycloalkylC1-C3alkoxy, C3-C6cycloalkylC1-C3alkoxy substituted with one to two substituents independently selected from Rx, C1-C5cyanoalkyl, C1-C5cyanoalkoxy, C1-C4alkylsulfanyl, C1-C4alkylsulfanyl substituted with one to three substituents independently selected from Rx, C1-C4alkylsulfonyl, C1-C4alkylsulfonyl substituted with one to three substituents independently selected from Rx, C1-C4alkylsulfinyl, or C1-C4alkylsulfinyl substituted with one to three substituents independently selected from Rx;
- R2b is hydrogen, C1-C3alkyl, C1-C3haloalkyl, C1-C3haloalkylsuflanyl, C1-C3alkoxy, C1-C3haloalkoxy, halogen, NO2, SF5, CN, C(O)NH2, C(O)OH, C(S)NH2, C3-C6cycloalkyl, C3-C6cycloalkyl substituted with one to three substituents independently selected from Rx, C3-C6cycloalkylcarbonyl, phenyl, phenyl substituted with one to three substituents independently selected from Rx, heteroaryl, heteroaryl substituted with one to three substituents independently selected from Rx, OR6, piperidin-2-one-1-yl, piperidin-2-one-1-yl substituted with one to two substituents independently selected from Rx, pyridin-2-one-1-yl, pyridin-2-one-1-yl substituted with one to two substituents independently selected from Rx, azetidin-1-yl, azetidin-1-yl substituted with one to two substituents independently selected from Rx pyrrolidin-1-yl, pyrrolidin-1-yl substituted with one to two substituents independently selected from Rx, C3-C6cycloalkylC1-C4alkyl, C3-C6cycloalkylC1-C4alkyl substituted with one to two substituents independently selected from Rz;
- C3-C6cycloalkylC1-C3alkoxy, C3-C6cycloalkylC1-C3alkoxy substituted with one to two substituents independently selected from Rx, C1-C5cyanoalkyl, C1-C6cyanoalkoxy, C1-C4alkylsulfanyl, C1-C4alkylsulfanyl substituted with one to three substituents independently selected from Rx, C1-C4alkylsulfonyl, C1-C4alkylsulfonyl substituted with one to three substituents independently selected from Rx, C1-C4alkylsulfinyl, or C1-C4alkylsulfinyl substituted with one to three substituents independently selected from Rx;
- A is N or C—R2c;
- R2c is hydrogen, halogen, C1-C3alkyl, C1-C3haloalkyl, C1-C3alkoxy, or C1-C3haloalkoxy;
- R3 is C1-C3alkyl or C1-C3haloalkyl;
- R4a is selected from the group consisting of hydrogen, C1-C6alkyl, and C1-C6haloalkyl;
- R4b is selected from the group consisting of hydrogen, C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6cycloalkyl substituted with 1 to 3 substituents independently selected from R6, C2-C6alkenyl, C2-C6haloalkenyl, C2-C6alkynyl, C1-C3alkoxyC1-C4alkyl-, cyanoC1-C6alkyl-, phenyl, phenyl substituted with 1 to 3 substituents independently selected from R7, phenylC1-C2alkyl-, phenylC1-C2alkyl-substituted with 1 to 3 substituents independently selected from R8, heterocyclyl, heterocyclyl substituted with 1 to 3 substituents independently selected from R9, heterocyclylC1-C2alkyl-, heterocyclylC1-C2alkyl-substituted with 1 to 3 substituents independently selected from R10, heteroaryl, heteroaryl substituted with 1 to 3 substituents independently selected from R11, heteroarylC1-C2alkyl-, heteroarylC1-C2alkyl-substituted with 1 to 3 substituents independently selected from R12, and oxetanyl;
- or
- R4a and R4b together with the nitrogen atom to which they are attached form a 4- to 6-membered heterocyclyl, which optionally comprises 1 or 2 additional heteroatoms independently selected from N, O and S(O)r, and wherein said heterocyclyl moiety is optionally substituted by 1 or 2 substituents independently selected from R13, and r is 0, 1 or 2;
- R5a and R5b are, independently of each other, selected from hydrogen, halogen, CN, C1-C3alkyl, C1-C3haloalkyl, C3-C4cycloalkyl, C1-C3alkoxy, and C1-C3haloalkoxy;
- R6 is independently selected from cyano, OH, halogen, oxo (═O), C1-C3alkyl, C1-C3haloalkyl, and C1-C3alkoxy;
- R7 is independently selected from cyano, OH, halogen, C1-C3alkyl, C1-C3haloalkyl, C1-C3alkoxy and C1-C3haloalkoxy;
- R8 is independently selected from cyano, OH, halogen, C1-C3alkyl, C1-C3haloalkyl, C1-C3alkoxy and C1-C3haloalkoxy;
- R9, independent of the heterocyclyl group, is independently selected from cyano, OH, halogen, oxo (═O), C1-C3alkyl, C1-C3haloalkyl, and C1-C3alkoxy;
- R10, independent of the heterocyclylC1-C2alkyl-group, is independently selected from cyano, OH, halogen, oxo (═O), C1-C3alkyl, C1-C3haloalkyl, and C1-C3alkoxy;
- R11, independent of the heteroaryl group, is independently selected from cyano, OH, halogen, C1-C3alkyl, C1-C3haloalkyl, C1-C3alkoxy and C1-C3haloalkoxy;
- R12, independent of the heteroarylC1-C2alkyl-group, is independently selected from cyano, OH, halogen, C1-C3alkyl, C1-C3haloalkyl, C1-C3alkoxy and C1-C3haloalkoxy;
- R13 is independently selected from cyano, OH, halogen, oxo (═O), C1-C3alkyl, C1-C3haloalkyl, and C1-C3alkoxy;
- Rx is independently selected from halogen, C1-C3alkyl, C1-C3haloalkyl, C1-C3alkoxy, C1-C3haloalkoxy, NO2, SF5, CN, C(O)NH2, C(S)NH2, C1-C4haloalkylsulfanyl, C1-C4haloalkylsulfinyl, C1-C4haloalkylsulfonyl, C1-C4alkylsulfanyl, C1-C4alkylsulfinyl and C1-C4alkylsulfonyl;
- and
- Rz is independently selected from oxo, halogen, C1-C3 alkyl, C1-C3haloalkyl, C1-C3alkoxy, C1-C3haloalkoxy and CN;
- or an agrochemically acceptable salt, stereoisomer, enantiomer, tautomer and N-oxide of the compound of formula I.
23 more elements
Dependencies are inferred from the claim text.