A solid catalyst component for the Ziegler-Natta polymerization or co-polymerization of alpha-olefins, comprising internal electron donors comprising a dialkylurea compound, a malonate compound, a succinate compound, and a 1,3-diether compounds;
- wherein the succinate compound is less than 30% by mol with respect to total amount of internal electron donors;
- wherein the molar ratio between the succinate compound and the 1,3-diether compound is in the range of about 0.1-0.5;
- and
- wherein the molar ratio between the malonate compound and the 1,3-diether compound is in the range of about 0.3-2.5.