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US 2023/0092316 A1Published application
Epoxy functionalized poly(aryl ether sulfones) copolymers
AssigneeSolvay Specialty Polymers USA, LLC
InventorsKamlesh NAIR, Joel POLLINO
Life of this patent
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Abstract
The invention pertains to a side-chain epoxy-functionalized copolymer (P1) and to the process for preparing this copolymer (P1). The present invention also pertains to the use of the copolymer (P1) in the preparation of a membrane, a composite material or a coating. The present invention also relates to a resin composition comprising at least the copolymer (P1) according to the present invention.
Claims14
A copolymer (P1) comprising:
- recurring units (RP1) of formula (M):
- recurring units (R*P1) of formula (N):
- optionally at least 50 μeq of hydroxyl end groups, amine end groups, acid end groups or epoxy end groups,
- wherein
- each R1 is independently selected from the group consisting of a halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium;
- each i is independently selected from 0 to 4;
- GN is selected from the group consisting of at least one of the following formulas:
- each k is independently selected from 0 to 4;
- each j is independently selected from 3 to 7;
- T and Q are independently selected from the group consisting of a bond, —CH2—, —O—;
- —SO2—, —S—;
- —C(O)—;
- —C(CH3)2—;
- —C(CF3)2—;
- —C(═CCl2)—;
- —C(CH3)(CH2CH2COOH)—;
- —N═N—;
- —RaC═CRb—, where each Ra and Rb, independently of one another, is a hydrogen, a C1-C12-alkyl, C1-C12-alkoxy, or C6-C18-aryl group;
- —(CH2)m— and —(CF2)m— with m being an integer from 1 to 6;
- an aliphatic divalent group, linear or branched, of up to 6 carbon atoms;
- and combinations thereof.
18 more elements
A process for preparing copolymer (P1) comprising at least partially epoxidizing a copolymer (P0) comprising:
- recurring units (RP0) of formula (M):
- recurring units (R*P0) of formula (P):
- optionally at least 50 μeq of hydroxyl end groups, amine end groups, acid end groups or epoxy end groups,
- wherein
- each R1 is independently selected from the group consisting of a halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium;
- each i is independently selected from 0 to 4;
- GP is selected from the group consisting of at least one of the following formulas:
- each k is independently selected from 0 to 4,
- T and Q are independently selected from the group consisting of a bond, —CH2—, —O—;
- —SO2—;
- —S—;
- —C(O)—;
- —C(CH3)2—;
- —C(CF3)2—;
- —C(═CCl2)—;
- —C(CH3)(CH2CH2COOH)—;
- —N═N—;
- —RaC═CRb—, where each Ra and Rb, independently of one another, is a hydrogen, a C1-C12-alkyl, C1-C12-alkoxy, or C6-C18-aryl group;
- —(CH2)m— and —(CF2)m— with m being an integer from 1 to 6;
- an aliphatic divalent group, linear or branched, of up to 6 carbon atoms;
- and combinations thereof.
18 more elements
The process of claim 11, being carried out:
- in the presence of a peroxy acid, or
- with at least one hydrogen peroxide precursor and at least one carboxylic acid or derivative thereof in the presence of water.
Dependencies are inferred from the claim text.