# US 2023/0057572 A1 · Resistive random-access memory and method for fabricating the same

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- Number: US 2023/0057572 A1
- Document ID: US20230057572A1
- Status: Published application
- Kind: A1
- Application number: 17/489,829
- Filed: 2021-09-30
- Published: 2023-02-23
- Earliest claimed: 2021-08-18
- Assignees: United Microelectronics Corp.
- Applicants: United Microelectronics Corp.
- Inventors: Shu-Hung YU; Chun-Hung CHENG; Chuan-Fu WANG
- Web page: https://patentgrep.com/patent/US20230057572A1

## CPC

- H10N 70/841: {Electrodes}
- H10B 63/80: {Arrangements comprising multiple bistable or multi-stable switching components of the same type on a plane parallel to the substrate, e.g. cross-point arrays}
- H10N 70/011: {Manufacture or treatment of multistable switching devices}
- H10N 70/026: {by physical vapor deposition, e.g. sputtering}
- H10N 70/063: {by etching of pre-deposited switching material layers, e.g. lithography}
- H10N 70/066: {by filling of openings, e.g. damascene method}
- H10N 70/24: {based on migration or redistribution of ionic species, e.g. anions, vacancies}
- H10N 70/826: {adapted for essentially vertical current flow, e.g. sandwich or pillar type devices}
- H10N 70/8833: {Binary metal oxides, e.g. TaOx}
- H10N: ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B: ELECTRONIC MEMORY DEVICES

## Abstract

A ReRAM device includes a dielectric layer, a bottom electrode, a data storage layer, a metal covering layer, and a top electrode. The dielectric layer has a recess. At least a portion of the bottom electrode is exposed through the recess. The data storage layer is disposed on a sidewall and a bottom surface of the recess, electrically contacts with the bottom electrode, and has a top portion lower than an opening of the recess. The metal covering layer blanket covers the data storage layer, has an extension portion covering the top portion, and connects to the sidewall of the recess. The top electrode is disposed in the recess, and is electrically contact with the metal covering layer.

## Claims

### Claim 1

A resistive random-access memory (ReRAM) device, comprising:
a dielectric layer, having a recess;
a bottom electrode, wherein at least a portion of the bottom electrode is exposed through the recess;
a data storage layer, disposed on a sidewall and a bottom surface of the recess, electrically contacting with the bottom electrode, and having a top portion lower than an opening of the recess;
a metal covering layer, blanket covering the data storage layer, having an extension portion covering the top portion, and connecting to the sidewall of the recess; and
a top electrode, disposed in the recess, and electrically contacting with the metal covering layer.

### Claim 2 (depends on 1)

The ReRAM device according to claim 1, wherein the data storage layer comprises a transition metal oxide selected from a group consisting of hafnium oxide (HfOx), zirconium oxide (ZrOx), aluminum oxide (AlOx), nickel oxide (NiOx), tantalum oxide (TaOx), titanium oxide (TiOx) and arbitrary combinations thereof.

### Claim 3 (depends on 1)

The ReRAM device according to claim 1, wherein the metal covering layer comprises at least one metal element selected from a group consisting of cobalt (Co), nickel (Ni), lead (Pb), gold (Au), rhenium (Re), iridium (Ir), titanium (Ti), hafnium (Hf), platinum (Pt), ruthenium (Ru), aluminum (Al) and the arbitrary combinations thereof.

### Claim 4 (depends on 1)

The ReRAM device according to claim 1, wherein the metal covering layer comprises:
a first portion, disposed on the bottom surface; and
a second portion, disposed on the sidewall and connected the extension portion with the first portion.

### Claim 5 (depends on 4)

The ReRAM device according to claim 4, wherein the second portion has a cross-sectional structure with a wide top and a narrow bottom.

### Claim 6 (depends on 4)

The ReRAM device according to claim 4, wherein a thickness of the first portion is greater than a thickness of the extension portion.

### Claim 7 (depends on 1)

The ReRAM device according to claim 1, wherein the extension portion has a round corner close to a central axis of the recess.

### Claim 8 (depends on 1)

The ReRAM device according to claim 1, wherein the top electrode comprises:
a plug portion, contacting to the second portion; and
a landing portion, disposed on the extension portion and covering the extension portion.

### Claim 9

A method for fabricating a ReRAM device, comprising:
forming a recess in a dielectric layer, through which at least a portion of a bottom electrode is exposed;
forming a data storage layer to cover a sidewall and a bottom surface of the recess, so as to make the data storage layer electrically contacting with the bottom electrode;
forming a metal covering layer, blanket over the data storage layer;
performing an etch-back process on the data storage layer and the metal covering layer to make a first top portion of the data storage layer and a second top portion of the metal covering layer both lower than an opening of the recess;
performing a metal sputtering process on the metal covering layer to form an extension portion on the second top portion and covering the first top portion, and to make the extension portion connected to the sidewall of the recess; and
forming a top electrode on the metal covering layer and electrically contacting with the metal covering layer.

### Claim 10 (depends on 9)

The method according to claim 9, wherein the etch-back process comprises using an etching gas containing chlorine, oxygen, and helium (Cl2/O2/He).

### Claim 11 (depends on 9)

The method according to claim 9, wherein the metal sputtering process comprises using a target that has material identical to or different from that of the metal covering layer.

### Claim 12 (depends on 9)

The method according to claim 9, wherein the forming of the top electrode comprises:
filling the recess with a conductive material; and
planarizing the conductive material.
