# US 2023/0057045 A1 · Compound and method for producing the same, resin composition, resin sheet, multilayer printed wiring board, and semiconductor device

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- Number: US 2023/0057045 A1
- Document ID: US20230057045A1
- Status: Published application
- Kind: A1
- Application number: 17/784,163
- Filed: 2020-12-09
- Published: 2023-02-23
- Earliest claimed: 2019-12-11
- Assignees: Mitsubishi Gas Chemical Company, Inc.
- Applicants: Mitsubishi Gas Chemical Company, Inc.
- Inventors: Shunsuke KATAGIRI; Takuya SUZUKI; Seiji SHIKA; Yune KUMAZAWA
- Web page: https://patentgrep.com/patent/US20230057045A1

## CPC

- C07C 69/75: of acids with a six-membered ring
- C07C 69/757: having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, [IMAGE cpc-sch-C07C-0958.gif] groups,[IMAGE cpc-sch-C07C-0959.gif] groups, or[IMAGE cpc-sch-C07C-0960.gif] in the acid moiety
- C08G 73/12: Unsaturated polyimide precursors
- C08L 79/085: {Unsaturated polyimide precursors}
- H05K 1/0313: {Organic insulating material}
- C07B 2200/07: Optical isomers
- C07C 2601/14: The ring being saturated
- H05K 1/0271: {Arrangements for reducing stress or warp in rigid printed circuit boards, e.g. caused by loads, vibrations or differences in thermal expansion}
- H05K 3/389: {by the use of a coupling agent, e.g. silane}
- H05K 2201/0129: Thermoplastic polymer, e.g. auto-adhesive layer; Shaping of thermoplastic polymer
- H05K 2201/068: wherein the coefficient of thermal expansion is important
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- H05K: PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- C07B: GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR (preparation of carboxylic acid esters by telomerisation C07C67/47; telomerisation C08F)

## Abstract

A compound (A) of the present invention is represented by the formula (1): wherein each R1 independently represents a group represented by the formula (2) or a hydrogen atom, and each R2 independently represents a hydrogen atom or a linear or branched alkyl group having 1 to 6 carbon atoms, provided that at least one R1 is a group represented by the formula (2); and wherein -* represents a bonding hand.

## Claims

### Claim 1

A compound represented by the following formula (17):

### Claim 2

(canceled)

### Claim 3 (depends on 1)

A method for producing the compound according to claim 1, comprising a step of reacting an alcohol compound represented by the following formula (4)
wherein each R3 independently represents an ethyl group.

### Claim 4

(canceled)

### Claim 5 (depends on 3)

The production method according to claim 3, wherein the reaction is carried out in the absence of a catalyst.

### Claim 6 (depends on 3)

The production method according to claim 3, wherein the reaction is performed in at least one solvent selected from the group consisting of a halogen solvent, a ketone solvent, and an ester solvent.

### Claim 7 (depends on 6)

The production method according to claim 6, wherein the solvent is at least one selected from the group consisting of dichloromethane, methyl ethyl ketone, butyl acetate, γ-butyrolactone, and propylene glycol monomethyl ether acetate.

### Claim 8

A resin composition comprising a compound represented by the following formula (16) and/or a compound represented by the following formula (17):
and
a bismaleimide compound (B) comprising a constituent unit represented by the following formula (7) and maleimide groups at both ends of the molecular chain:
wherein R4 represents a linear or branched alkylene group having 1 to 16 carbon atoms, or a linear or branched alkenylene group having 2 to 16 carbon atoms; R5 represents a linear or branched alkylene group having 1 to 16 carbon atoms, or a linear or branched alkenylene group having 2 to 16 carbon atoms; each R6 independently represents a hydrogen atom, a linear or branched alkyl group having 1 to 16 carbon atoms, or a linear or branched alkenyl group having 2 to 16 carbon atoms; and each n1 independently represents an integer of 1 to 10.

### Claim 9

(canceled)

### Claim 10 (depends on 8)

The resin composition according to claim 8, further comprising at least one maleimide compound (C) selected from the group consisting of a compound represented by the following formula (8), a compound represented by the following formula (9), a compound represented by the following formula (10), a compound represented by the following formula (11), a compound represented by the following formula (12), and a compound represented by the following formula (13):
wherein R7, R8, and R9 each independently represent a hydrogen atom, or a linear or branched alkyl group having 1 to 8 carbon atoms and optionally having a substituent;
wherein R10, R11, and R12 each independently represent a hydrogen atom, a hydroxyl group, or a linear or branched alkyl group having 1 to 6 carbon atoms and optionally having a substituent; and n2 is an integer of 1 to 10;
wherein each R13 independently represents a hydrogen atom, a methyl group or an ethyl group, and each R14 independently represents a hydrogen atom or a methyl group;
wherein each R15 independently represents a hydrogen atom or a methyl group; and n3 is an integer of 1 to 10;
wherein each R16 independently represents a hydrogen atom, a methyl group or an ethyl group; and
wherein each R17 independently represents a hydrogen atom or a methyl group; and n4 is an integer of 1 to 10.

### Claim 11 (depends on 8)

The resin composition according to claim 8, further comprising a photo initiator (D).

### Claim 12 (depends on 11)

The resin composition according to claim 11, wherein the photo initiator (D) comprises a compound represented by the following formula (14):
wherein each R18 independently represents a group represented by the following formula (15) or a phenyl group; and
wherein -* represents a bonding hand, and each R19 independently represents a hydrogen atom or a methyl group.

### Claim 13 (depends on 6)

A resin sheet comprising:
a support; and
a resin layer disposed on one surface or both surfaces of the support,
wherein the resin layer comprises the resin composition according to claim 6.

### Claim 14 (depends on 13)

The resin sheet according to claim 13, wherein the resin layer has a thickness of 1 to 50 μm.

### Claim 15 (depends on 6)

A multilayer printed wiring board comprising:
an insulation layer; and
a conductor layer formed on one surface or both surfaces of the insulation layer,
wherein the conductor layer comprises the resin composition according to claim 6.

### Claim 16 (depends on 6)

A semiconductor device comprising the resin composition according to claim 6.
