# US 2023/0057032 A1 · Gas sensor

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- Number: US 2023/0057032 A1
- Document ID: US20230057032A1
- Status: Published application
- Kind: A1
- Application number: 17/981,528
- Filed: 2022-11-07
- Published: 2023-02-23
- Earliest claimed: 2018-12-25
- Assignees: NGK Insulators, Ltd.
- Applicants: Ngk Insulators, Ltd.
- Inventors: Yusuke WATANABE; Shota KAGEYAMA; Yuki NAKAYAMA
- Web page: https://patentgrep.com/patent/US20230057032A1

## CPC

- G01N 27/419: Measuring voltages or currents with a combination of oxygen pumping cells and oxygen concentration cells
- G01N 27/4071: {using sensor elements of laminated structure}
- G01N 27/4072: {characterized by the diffusion barrier}
- G01N 27/4073: {Composition or fabrication of the solid electrolyte}
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

A sensor element and fabrication method thereof, the sensor element includes: a main pump cell including an inner pump electrode facing a first inner space into which a measurement gas is introduced, an external pump electrode provided on an element surface, and a solid electrolyte therebetween; an auxiliary pump cell including an auxiliary pump electrode provided facing a second inner space, the external pump electrode, and the solid electrolyte therebetween; and a measurement pump cell including a measurement electrode, the external pump electrode, and the solid electrolyte therebetween. The inner pump electrode has a porosity of 10 - 25%, the auxiliary pump electrode has a porosity of 30 - 50%, a thickness ratio of both the electrodes is 1.0 - 4.0, and current flowing to the main pump cell has a current density of 0.05 - 0.5 mA/mm2 when the measurement gas has an oxygen concentration of 20.5%.

## Claims

### Claim 1

A method of fabricating a limiting current type gas sensor, the limiting current type gas sensor comprising a sensor element made of an oxygen-ion conductive solid electrolyte and capable of specifying a concentration of NOx in a measurement gas, said sensor element comprising:
a gas inlet through which the measurement gas is introduced from an external space;
a first inner space communicated with said gas inlet under a predetermined diffusion resistance;
a second inner space communicated with said first inner space under a predetermined diffusion resistance;
a main pump cell as an electrochemical pump cell including an inner pump electrode provided facing said first inner space, an external pump electrode provided on a surface of said sensor element, and said solid electrolyte provided between said inner pump electrode and said external pump electrode;
an auxiliary pump cell as an electrochemical pump cell including an auxiliary pump electrode provided facing said second inner space, said external pump electrode, and said solid electrolyte provided between said auxiliary pump electrode and said external pump electrode;
a measurement electrode disposed inside said sensor element and interposing at least a diffusion limiting part between said measurement electrode and said second inner space; and
a measurement pump cell as an electrochemical pump cell including said measurement electrode, said external pump electrode, and said solid electrolyte provided between said measurement electrode and said external pump electrode,
wherein the method comprises the steps of:
forming said inner pump electrode to have a porosity P1 of 10% to 25%:
forming said auxiliary pump electrode to have a porosity P2 of 30% to 50%;
forming the inner pump electrode to have thickness TI and the auxiliary pump electrode to have a thickness T2 such that a ratio T1/T2 is 1.0 to 4.0; and
forming said main pump cell to have a reference current density of 0.05 mA/mm2 to 0.5 mA/mm2, said reference current density being a current density when said measurement gas has an oxygen concentration of 20.5%.

### Claim 2 (depends on 1)

The method of fabricating a limiting current type gas sensor according to claim 1, further comprising the steps of:
forming said inner pump electrode and said auxiliary pump electrode such that a porosity difference P2-P1 between said inner pump electrode and said auxiliary pump electrode is 30% or smaller.

### Claim 3 (depends on 1)

The method of fabricating a limiting current type gas sensor according to claim 1, further comprising the step of:
forming said inner pump electrode and said auxiliary pump electrode to each have a thickness of 5 µm to 30 µm and an area of 5 mm2 to 20 mm2.

### Claim 4 (depends on 2)

The method of fabricating a limiting current type gas sensor according to claim 2, further comprising the step of:
forming said inner pump electrode and said auxiliary pump electrode to each have a thickness of 5 µm to 30 µm and an area of 5 mm2 to 20 mm2.