# US 2023/0054844 A1 · Ink composition, product, liquid resin composition, and produced matter

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- Number: US 2023/0054844 A1
- Document ID: US20230054844A1
- Status: Published application
- Kind: A1
- Application number: 17/759,483
- Filed: 2021-01-22
- Published: 2023-02-23
- Earliest claimed: 2020-01-27
- Assignees: Shoei Chemical Inc.
- Applicants: Shoei Chemical Inc.
- Inventors: Paul TYRELL
- Web page: https://patentgrep.com/patent/US20230054844A1

## CPC

- C09D 11/033: characterised by the solvent
- C09D 11/03: characterised by features other than the chemical nature of the binder
- C09D 11/037: characterised by the pigment
- C09D 11/322: Pigment inks
- C09D 11/36: based on non-aqueous solvents
- C09D 11/38: characterised by non-macromolecular additives other than solvents, pigments or dyes
- C09D 11/52: Electrically conductive inks
- C09K 11/025: {non-luminescent particle coatings or suspension media}
- C09K 11/08: containing inorganic luminescent materials
- C09K 11/70: containing phosphorus
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

## Abstract

An ink composition according to an embodiment of the present invention, comprising: a volatile solvent; and dispersed in the volatile solvent, a plurality of semiconductor nanoparticles each coordinated to a plurality of organic ligands, wherein a ratio by mass of the semiconductor nanoparticles to the volatile solvent is greater than 1:1. A product according to an embodiment of the present invention comprising: a solid substrate; and arranged on the solid substrate, a dried residue of an ink composition, the dried residue comprising a plurality of semiconductor nanoparticles arranged without an intervening polymer matrix, wherein the a plurality of semiconductor nanoparticles each coordinated to a plurality of organic ligands.

## Claims

### Claim 1

An ink composition, comprising:
a volatile solvent; and
dispersed in the volatile solvent, a plurality of semiconductor nanoparticles each coordinated to a plurality of organic ligands, wherein a ratio by mass of the semiconductor nanoparticles to the volatile solvent is greater than 1:1.

### Claim 2 (depends on 1)

The ink composition according to claim 1, wherein
the volatile solvent includes a solvent which is a monocyclic terpenoid.

### Claim 3 (depends on 1)

The ink composition according to claim 1, wherein
the volatile solvent includes a solvent which is a monocyclic terpenoid and is an alcohol.

### Claim 4 (depends on 1)

The ink composition according to claim 1, wherein
the volatile solvent includes one or more of dihydroterpineol, terpineol, and dihydroterpineol acetate.

### Claim 5 (depends on 1)

The ink composition according to claim 1, wherein
the plurality of organic ligands includes an aliphatic thiol, carboxylic acid, or amine.

### Claim 6 (depends on 1)

The ink composition according to claim 1, wherein
the plurality of organic ligands includes dodecanethiol.

### Claim 7 (depends on 1)

The ink composition according claim 1, wherein
the ratio by mass of the semiconductor nanoparticles to the volatile solvent is between 2:1 and 4:1.

### Claim 8 (depends on 1)

The ink composition according claim 1, wherein
the ink composition substantially does not include a matrix material or other material other than the organic ligand surrounding the semiconductor nanoparticles.

### Claim 9

A product comprising:
a solid substrate; and
arranged on the solid substrate, a dried residue of an ink composition, the dried residue comprising a plurality of semiconductor nanoparticles arranged without an intervening polymer matrix, wherein the a plurality of semiconductor nanoparticles each coordinated to a plurality of organic ligands.

### Claim 10 (depends on 9)

The product according to claim 9, wherein
the plurality of semiconductor nanoparticles of the dried residue includes a close-packed layer of the semiconductor nanoparticles.

### Claim 11 (depends on 9)

The product according to claim 9, wherein
the dried residue consists substantially of the plurality of semiconductor nanoparticles.

### Claim 12 (depends on 11)

The product according to claim 11, wherein
the dried residue includes a trace amount of the volatile solvent.

### Claim 13 (depends on 9)

The product according to claim 9, wherein
the plurality of organic ligands includes an aliphatic thiol, carboxylic acid, or amine.

### Claim 14 (depends on 9)

The product according to claim 9, wherein
the plurality of organic ligands includes dodecanethiol.

### Claim 15 (depends on 9)

The product according to claim 9, wherein
the solid substrate comprises a substantially transparent substrate.

### Claim 16

A liquid resin composition comprising:
a thermally polymerizable resin; and
dispersed in the thermally polymerizable resin, a plurality of semiconductor nanoparticles each coordinated to a plurality of organic ligands, wherein a ratio by mass of the semiconductor nanoparticles to the thermally polymerizable resin is greater than 1:1.

### Claim 17 (depends on 16)

The liquid resin composition according to claim 16, wherein
the thermally polymerizable resin includes an acrylate monomer.

### Claim at position 18

-20. (canceled)

### Claim 21 (depends on 16)

The liquid resin composition according claim 16, wherein
the ratio by mass of the semiconductor nanoparticles to the thermally polymerizable resin is between 2:1 and 4:1.

### Claim at position 20

-28. (canceled)

### Claim 29 (depends on 9)

The product according to claim 9, wherein
the dried residue includes a trace amount of the volatile solvent.
