# US 2023/0053477 A1 · Insecticidal Mixtures

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- Number: US 2023/0053477 A1
- Document ID: US20230053477A1
- Status: Published application
- Kind: A1
- Application number: 17/789,896
- Filed: 2020-12-31
- Published: 2023-02-23
- Earliest claimed: 2019-12-31
- Assignees: Adama Makhteshim Ltd.
- Applicants: Adama Makhteshim Ltd.
- Inventors: Gerson Dalla Corte; Ernesto Benetti; Dave Feist; Rajavelu N K; Naidu Cas; Pradeep Kulkarni; Hua Cheng
- Web page: https://patentgrep.com/patent/US20230053477A1

## CPC

- A01N 57/28: containing acyclic or cycloaliphatic radicals
- A01N 37/34: Nitriles
- A01N 43/36: five-membered rings
- A01N 43/56: 1,2-Diazoles; Hydrogenated 1,2-diazoles
- A01N 47/02: the carbon atom having no bond to a nitrogen atom
- A01P 7/04: Insecticides
- A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01P: BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS

## Abstract

The present invention relates to insecticidal mixtures comprising a) an anthranilamide compound of formula (I) and b) an insecticidal compound.

## Claims

### Claim 1

1) A insecticidal mixture comprising: (i) an anthranilamide compound of formula (I)
in which
A1 and A2 independently of one another represent oxygen or sulfur,
X1 represents N or CR10,
R1 represents hydrogen or represents C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl or C3-C6-cycloalkyl, each of which is optionally mono- or polysubstituted, where the substituents independently of one another may be selected from the group consisting of R6, halogen, cyano, nitro, hydroxyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C2-C4-alkoxycarbonyl, C1-C4-alkylamino, C2-C8-dialkylamino, C3-C6-cycloalkylamino, (C1-C4-alkyl)-C3-C6-cycloalkylamino and R11,
R2 represents hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, C1-C4-alkoxy, C1-C4-alkylamino, C2-C5-dialkylamino, C3-C6-cycloalkylamino, C2-C6-alkoxycarbonyl or C2-C6-alkylcarbonyl,
R3 represents hydrogen, R11 or represents C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, each of which is optionally mono- or polysubstituted, where the substituents independently of one another may be selected from the group consisting of R6, halogen, cyano, nitro, hydroxyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C2-C6-alkoxycarbonyl, C2-C6-alkylcarbonyl, C3-C6-trialkylsilyl, R11, phenyl, phenoxy and a 5- or 6-membered heteroaromatic ring, where each phenyl, phenoxy and 5- or 6-membered heteroaromatic ring may optionally be substituted and where the substituents independently of one another may be selected from one to three radicals W or one or more radicals R12, or
R2 and R3 may be attached to one another and form the ring M,
R4 represents hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, C1-C6-haloalkyl, C2-C6-haloalkenyl, C2-C6-haloalkynyl, C3-C6-halocycloalkyl, halogen, cyano, nitro, hydroxyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylthio, C1-C4-haloalkylsulfinyl, C1-C4-haloalkylsulfonyl, C1-C4-alkylamino, C2-C8-dialkylamino, C3-C6-cycloalkylamino, C3-C6-trialkylsilyl or represents phenyl, benzyl or phenoxy, each of which is optionally mono- or polysubstituted, where the substituents independently of one another may be selected from the group consisting of C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C2-C4-haloalkynyl, C3-C6-halocycloalkyl, halogen, cyano, nitro, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-alkylamino, C2-C8-dialkylamino, C3-C6-cycloalkylamino, C3-C6-(alkyl)cycloalkylamino, C2-C4-alkylcarbonyl, C2-C6-alkoxycarbonyl, C2-C6-alkylaminocarbonyl, C3-C8-dialkylaminocarbonyl and C3-C6-trialkylsilyl,
R5 and R8 in each case independently of one another represent hydrogen, halogen or represent in each case optionally substituted C1-C4-alkyl, C1-C4-haloalkyl, R12, G, J, -OJ, —OG, —S(O)p-J, —S(O)pG, —S(O)p-phenyl, where the substituents independently of one another may be selected from one to three radicals W or from the group consisting of R12, C1-C10-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy and C1-C4-alkylthio, where each substituent may be substituted by one or more substituents independently of one another selected from the group consisting of G, J, R6, halogen, cyano, nitro, amino, hydroxyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylthio, C1-C4-haloalkylsulfinyl, C1-C4-haloalkylsulfonyl, C1-C4-alkylamino, C2-C8-dialkylamino, C3-C6-trialkylsilyl, phenyl and phenoxy, where each phenyl or phenoxy ring may optionally be substituted and where the substituents independently of one another may be selected from one to three radicals W or one or more radicals R12,
G in each case independently of one another represents a 5- or 6-membered non-aromatic carbocyclic or heterocyclic ring which may optionally contain one or two ring members from the group consisting of C(═O), SO and S(═O)2 and which may optionally be substituted by one to four substituents independently of one another selected from the group consisting of C1-C2-alkyl, halogen, cyano, nitro and C1-C2-alkoxy, or independently of one another represents C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, (cyano)-C3-C7-cycloalkyl, (C1-C4-alkyl)-C3-C6-cycloalkyl, (C3-C6-cycloalkyl)-C1-C4-alkyl, where each cycloalkyl, (alkyl)cycloalkyl and (cycloalkyl)alkyl may optionally be substituted by one or more halogen atoms,
J in each case independently of one another represents an optionally substituted 5- or 6-membered heteroaromatic ring, where the substituents independently of one another may be selected from one to three radicals W or one or more radicals R12,
R6 independently of one another represents —C(=E1)R19, -L(=E1)R19, —C(=E1)LR19, -LC(=E1)LR19, —OP(=Q)(OR19)2, —SO2LR18 or -LSO2LR19, where each E1 independently of one another represents O, S, N—R15, N—OR1, N—N(R15)2, N'S═O, N—CN or N—NO2,
R7 represents hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, halogen, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylthio, C1-C4-haloalkylsulfinyl, C1-C4-haloalkylsulfonyl,
R9 represents C1—C-haloalkyl, C1-C4-haloalkoxy, C1-C4-haloalkylsulfinyl or halogen,
R10 represents hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, halogen, cyano or C1-C4-haloalkoxy,
R11 in each case independently of one another represents in each case optionally mono to trisubstituted C1-C6-alkylthio, C1-C6-alkylsulfenyl, C1-C6-haloalkylthio, C1-C6-haloalkylsulfenyl, phenylthio or phenylsulfenyl, where the substituents independently of one another may be selected from the list W, —S(O)nN(R16)2, —C(═O)R13, -L(C═O)R14, —S(C═O)LR14, —C(═O)LR13, —S(O)nNR13C(═O)R13, —S(O)nNR13C(═O)LR14 or —S(O)nNR13S(O)2LR14,
L in each case independently of one another represents O, NR18 or S,
R12 in each case independently of one another represents —B(OR17)2, amino, SH, thiocyanato, C3-C8-trialkylsilyloxy, C1-C4-alkyl disulfides, —SF5, —C(=E)R9, -LC(=E1)R19, —C(=E)LR19, -LC(=E1)LR19, —OP(=Q)(OR19)2, —SO2LR19 or -LSO2LR19,
Q represents O or S,
R13 in each case independently of one another represents hydrogen or represents in each case optionally mono- or polysubstituted C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl or C3-C6-cycloalkyl, where the substituents independently of one another may be selected from the group consisting of R6, halogen, cyano, nitro, hydroxyl, C1-C4-alkoxy, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-alkylamino, C2-C8-dialkylamino, C3-C6-cycloalkylamino or (C1-C4-alkyl)-C3-C6-cycloalkylamino,
R14 in each case independently of one another represents in each case optionally mono- or polysubstituted C2-C20-alkenyl, C2-C20-alkynyl or C3-C6-cycloalkyl, where the substituents independently of one another may be selected from the group consisting of R6, halogen, cyano, nitro, hydroxyl, C1-C4-alkoxy, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-alkylamino, C2-C8-dialkylamino, C3-C6-cycloalkylamino and (C1-C4-alkyl)-C3-C6-cycloalkylamino or represent optionally substituted phenyl, where the substituents independently of one another may be selected from one to three radicals W or one or more radicals R12,
R15 in each case independently of one another represents hydrogen or represents in each case optionally mono- or polysubstituted C1-C6-haloalkyl or C1-C6-alkyl, where the substituents independently of one another may be selected from the group consisting of cyano, nitro, hydroxyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylthio, C1-C4-haloalkylsulfinyl, C1-C4-haloalkylsulfonyl, C1-C4-alkylamino, C2-C8-dialkylamino, C2-C6-alkoxycarbonyl, C2-C6-alkylcarbonyl, C3-C6-trialkylsilyl and optionally substituted phenyl, where the substituents independently of one another may be selected from one to three radicals W or one or more radicals R12, or N(R15)2 represents a cycle which forms the ring M,
R16 represents C1-C12-alkyl or C1-C12-haloalkyl, or N(R16)2 represents a cycle which forms the ring M,
R17 in each case independently of one another represents hydrogen or C1-C4-alkyl, or B(OR17)2 represents a ring in which the two oxygen atoms are attached via a chain having two to three carbon atoms which are optionally substituted by one or two substituents independently of one another selected from the group consisting of methyl and C2-C6-alkoxycarbonyl,
R18 in each case independently of one another represents hydrogen, C1-C6-alkyl or C1-C6-haloalkyl, or N(R13)(R18) represents a cycle which forms the ring M,
R19 in each case independently of one another represents hydrogen or represents in each case mono- or polysubstituted C1-C6-alkyl, where the substituents independently of one another may be selected from the group consisting of cyano, nitro, hydroxyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylthio, C1-C4-haloalkylsulfinyl, C1-C4-haloalkylsulfonyl, C1-C4-alkylamino, C2-C8-dialkylamino, CO2H, C2-C6-alkoxycarbonyl, C2-C6-alkylcarbonyl, C3-C6-trialkylsilyl and optionally substituted phenyl, where the substituents independently of one another may be selected from one to three radicals W, C1-C6-haloalkyl, C3-C6-cycloalkyl or phenyl or pyridyl, each of which is optionally mono- to trisubstituted by W,
M in each case represents an optionally mono- to tetrasubstituted ring which, in addition to the nitrogen atom attached to the substituent pair R13 and R18, (R15)2 or (R16)2, contains two to six carbon atoms and optionally additionally a further nitrogen, sulfur or oxygen atom, where the substituents independently of one another may be selected from the group consisting of C1-C2-alkyl, halogen, cyano, nitro and C1-C2-alkoxy,
W in each case independently of one another represents C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C2-C4-haloalkynyl, C3-C6-halocycloalkyl, halogen, cyano, nitro, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-alkylsulfonyl, C1-C4-alkylamino, C2-C8-dialkylamino, C3-C6-cycloalkylamino, (C1-C4-alkyl)-C3-C6-cycloalkylamino, C2-C4-alkylcarbonyl, C2-C6-alkoxycarbonyl, CO2H, C2-C6-alkylaminocarbonyl, C3-C8-dialkylaminocarbonyl or C3-C6-trialkylsilyl,
n in each case independently of one another represents 0 or 1,
p in each case independently of one another represents 0, 1 or 2,
where, if (a) R5 represents hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-haloalkenyl, C2-C6-haloalkynyl, C1-C4-haloalkoxy, C1-C4-haloalkylthio or halogen and (b) R8 represents hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-haloalkenyl, C2-C6-haloalkynyl, C1-C4-haloalkoxy, C1-C4-haloalkylthio, halogen, C2-C4-alkylcarbonyl, C2-C6-alkoxycarbonyl, C2-C6-alkylaminocarbonyl or C3-C8 dialkylaminocarbonyl, (c) at least one substituent selected from the group consisting of R6, R11 and R12 if present and (d) if R12 is not present, at least one of the radicals R6 and R11 is different from C2-C6-alkylcarbonyl, C2-C6-alkoxycarbonyl, C2-C6-alkylaminocarbonyl and C3-C8-dialkylaminocarbonyl, and where the compound of the general formula (I) may also be an N-oxide or salt; and (ii) at least one insecticidal compound.

### Claim 2 (depends on 1)

2) The insecticidal mixture of claim 1, wherein the anthranilamide compound is selected from the group comprising, chlorantraniliprole, cyantraniliprole, tetraniliprole, tetrachlorantraniliprole, bromantraniliprole, and cyclaniliprole.

### Claim 3 (depends on 1, 2)

3) The insecticidal mixture of claim 1 or 2, wherein the anthranilamide compound is chlorantraniliprole.

### Claim 4 (depends on 1, 2)

4) The insecticidal mixture of claim 1 or 2, wherein the anthranilamide compound is cyantraniliprole.

### Claim 5 (depends on 1, 2)

5) The insecticidal mixture of claim 1 or 2, wherein the anthranilamide compound is cyclaniliprole.

### Claim 6 (depends on 1, 2)

6) The insecticidal mixture of claim 1 or 2, wherein the anthranilamide compound is tetraniliprole.

### Claim 7 (depends on 1, 2, 3, 4, 5, 6)

7) The insecticidal mixture of any one of claims 1-6, wherein the insecticidal compound is selected from the group consisting of:
a. Acetylcholine esterase inhibitors selected from triazemate or from the class of carbamates consisting of aldicarb, alanycarb, benfuracarb, carbaryl, carbofuran, carbosulfan, methiocarb, methomyl, oxamyl, primicarb, propoxur and thiodicarb, or from the class of organophosphates consisting of acephate, azinphos-ethyl, azinphos-methyl, chlorfenvinphos, chlorpyrifos, chlorpyrifos-methyl, demeton-S-methyl, diazinon, dichlorvos/DDVP, dicrotophos, dimethoate, disulfoton, ethion, fenitrothion, fenthion, isoxathion, malathion, methamidaphos, methidathion, mevinphos, monocrotophos, oxymethoate, oxydemeton-methyl, parathion, parathion-methyl, phenthoate, phorate, phosalone, phosmet, phosphamidon, pirimiphos-methyl, quinalphos, terbufos, tetrachlorvinphos, triazophos and trichlorfon;
b. GABA-gated chloride channel antagonists selected from the cyclodiene or ganochlorine endosulfan, N-Ethyl-2,2-dimethylpropionamide-2-(2,6-dichloro-α.α.α-trifluoro-p-tolyl) hydrazon, N-Ethyl-2,2-dichloro-1-methylcyclopropane-carboxamide-2-(2,6-dichloro-α.α.α-trifluoro-p-tolyl) hydrazon or from the class of phenylpyrazoles consisting of acetoprole, ethiprole, fipronil, pyrafluprole, pyriprole and vaniliprole;
c. Sodium channel modulators selected from the class of pyrethroids consisting of allethrin, bifenthrin, cyfluthrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, tau-fluvalinate, permethrin, silafluofen and tralomethrin;
d. Nicotinic acteylcholine receptor agonists/antagonists selected from nicotine, cartap hydrochloride, thiocyclam, sulfoxaflor or from the class of neonicotinoids consisting of acetamiprid, chlothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam and AKD-1022; or the allosteric nicotinic acteylcholine receptor agonists spinosad and spinetoram;
e. Chloride channel activators selected from abamectin, emamectin benzoate, lepimectin or milbemectin;
f. Juvenile hormone mimics selected from hydroprene, kinoprene, fenoxycarb or pyriproxyfen;
g. Compounds affecting the oxidative phosphorylation selected from diafenthiuron, fenbutatin oxide, propargite or chlorfenapyr,
h. Inhibitors of the chitin biosynthesis selected from buprofezin or from the class of benzylureas consisting of bistrifluron, diflubenzuron, flufenoxuron, hexaflumuron, lufenuron, novaluron and teflubenzuron;
i. Moulting disruptors selected from cyromazine or from the class of ecdysone agonists consisting of methoxyfenozide, tebufenozide and azadirachtin;
j. Mitochondrial electron transport inhibitors selected from pyridaben, tolfenpyrad or flufenerim;
k. Voltage-dependent sodium channel blockers selected from indoxacarb or metaflumizone;
l. Inhibitors of the lipid synthesis selected from spirodiclofen, spiromesifen or spirotetramat; and
m. group of various compounds consisting of amidoflumet, amitraz, bifenazate, clofentezine, cyenopyrafen, cyflumetofen, etoxazole, flonicamid, flubendiamine, flupyrazophos, hexythiazox, piperonyl butoxide, pymetrozine, pyridalyl, and pyrifluquinazon.

### Claim 8 (depends on 7)

8) The insecticidal mixture of claim 7, wherein the insecticidal compound is selected from the group consisting of acephate, novaluron, fipronil, chlorfenapyr, methoxyfenozide, thiamethoxam, abamectin, tau-fluvalinate and lambda-cyhalothrin.

### Claim 9 (depends on 8)

9) The insecticidal mixture of claim 8, wherein the insecticidal compound is acephate.

### Claim 10 (depends on 8)

10) The insecticidal mixture of claim 8, wherein the insecticidal compound is novaluron.

### Claim 11 (depends on 8)

11) The insecticidal mixture of claim 8, wherein the insecticidal compound is fipronil.

### Claim 12 (depends on 8)

12) The insecticidal mixture of claim 8, wherein the insecticidal compound is chlorfenapyr.

### Claim 13 (depends on 8)

13) The insecticidal mixture of claim 8, wherein the insecticidal compound is tau-fluvalinate.

### Claim 14 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13)

14) The insecticidal mixture of any one of claims 1-13, wherein the mixture exhibits synergistic effects.

### Claim 15 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14)

15) The insecticidal mixture of any one of claims 1-14, wherein the weight ratio of the anthranilamide compound of formula (I), and the insecticidal compound is from 1:100 to 100:1.

### Claim 16 (depends on 15)

16) The insecticidal mixture of claim 15, wherein the weight ratio of the anthranilamide compound of formula (I), and the insecticidal compound is from 1:50 to 50:1.

### Claim 17 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16)

17) The insecticidal mixture of any one of claims 1-16, wherein the weight ratio of the anthranilamide compound of formula (I), and acephate is from 1:50 to 1:1.

### Claim 18 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16)

18) The insecticidal mixture of any one of claims 1-16, wherein the weight ratio of the anthranilamide compound of formula (I), and novaluron is from 1:50 to 1:1.

### Claim 19 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16)

19) The insecticidal mixture of any one of claims 1-16, wherein the weight ratio of the anthranilamide compound of formula (I), and fipronil is from 1:50 to 1:1.

### Claim 20 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16)

20) The insecticidal mixture of any one of claims 1-16, wherein the weight ratio of the anthranilamide compound of formula (I), and chlorfenapyr is from 1:50 to 1:1.

### Claim 21 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16)

21) The insecticidal mixture of any one of claims 1-16, wherein the weight ratio of the anthranilamide compound of formula (I), and taufluvalinate is from 1:50 to 1:1.

### Claim 22 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21)

22) The insecticidal mixture of any one of claims 1-21, comprising about (i) 1-250 g/l of chlorantraniliprole, and (ii) 500-1500 g/l of acephate.

### Claim 23 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21)

23) The insecticidal mixture of any one of claims 1-21, comprising about (i) 1-250 g/l of chlorantraniliprole, and (ii) 1-250 g/l of novaluron.

### Claim 24 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21)

24) The insecticidal mixture of any one of claims 1-21, comprising about (i) 1-250 g/l of chlorantraniliprole, and (ii) 1-1000 g/l of fipronil.

### Claim 25 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21)

25) The insecticidal mixture of any one of claims 1-21, comprising about (i) 1-250 g/l of chlorantraniliprole, and (ii) 1-1000 g/l of chlorfenapyr.

### Claim 26 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21)

26) The insecticidal mixture of any one of claims 1-21, comprising about (i) 1-250 g/l of chlorantraniliprole, and (ii) 1-1000 g/l of tau-fluvalinate.

### Claim 27 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26)

27) The insecticidal mixture of any one of claims 1-26, wherein the anthranilamide compound of formula (I), and the insecticidal compound are applied jointly or in a succession.

### Claim 28 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27)

28) An insecticidal composition comprising: (i) the mixture of any one of claims 1-27; and (ii) an agriculturally acceptable carrier.

### Claim 29 (depends on 28)

29) The insecticidal composition of claim 28, further comprising at least one surfactant, solid diluent, liquid diluent, or a combination thereof.

### Claim 30 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29)

30) A method for enhancing plant development comprising applying to the plant, a locus of the plant and/or propagation material of the plant an effective amount of the mixture of any one of claims 1-27 or the composition of any one of claims 28-29 so as to thereby enhance plant development.

### Claim 31 (depends on 30)

31) The method of claim 30, wherein:
a) the method enhances root development,
b) the method enhances the root system of the plant,
c) the method enhances plant quality,
d) the method enhances plant vigor,
e) the method enhances plant yield,
f) the method prevents root damage,
g) the method improves rooting, and/or
h) the method improves the health of the plant.

### Claim 32 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29)

32) A method for controlling insects comprising contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of the mixture of any one of claims 1-27 or the composition of any one of claims 28-29 so as to thereby control insects.

### Claim 33 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29)

33) A method for protecting plants from attack or infestation by insects comprising contacting the plant, or the soil or water in which the plant is growing, with an effective amount of the mixture of any one of claims 1-27 or the composition of any one of claims 28-29 so as to thereby protecting plants from attack or infestation by insects.

### Claim 34 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29)

34) A method for increasing resistance to the compound of Formula (I) comprising contacting the plant, or the soil or water in which the plant is growing, with an effective amount of the mixture of any one of claims 1-27 or the composition of any one of claims 28-29 so as to thereby increasing resistance to the compound of Formula (I).

### Claim 35 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29)

35) A method for enhancing knock-down activity and/or prolonged control comprising contacting the plant, or the soil or water in which the plant is growing, with an effective amount of the mixture of any one of claims 1-27 or the composition of any one of claims 28-29 so as to thereby enhancing knock-down activity and/or prolonged control.

### Claim 36 (depends on 27, 28, 29, 30, 31, 32, 33, 34, 35)

36) The method of any one of claims 27-35, wherein an effective amount of the mixture or the composition is applied at a rate of 1-1000 L/ha.

### Claim 37 (depends on 28, 29)

37) A method for protection of seed comprising contacting the seeds with the mixture of any one of 1-27 or the composition of any one of claims 28-29 so as to thereby protect seeds.

### Claim 38 (depends on 37)

38) The method of claim 37, wherein an effective amount of the mixture or the composition is applied in an amount of from 0.1 g to 10 kg per 100 kg of seeds