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US 2023/0023593 A1Published application
Positive resist composition and pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsJun Hatakeyama, Takayuki Fujiwara
Life of this patent
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Abstract
A positive resist composition is provided comprising (A) a specific sulfonium salt as quencher, (B) a sulfonium salt consisting of a fluorinated sulfonate anion and a sulfonium cation as acid generator, and (C) a base polymer comprising repeat units having an acid labile group. The resist composition has a high sensitivity and resolution, improved LWR or CDU, and a broad process window and forms a pattern of good profile after exposure.
Claims10
A positive resist composition comprising
- (A) a quencher in the form of a sulfonium salt having the following formula (1):
- wherein R1 is fluorine, a C1-C4 alkyl group, C1-C4 alkyloxy group, C2-C4 alkenyl group, C2-C4 alkynyl group, phenyl group, or C1-C20 hydrocarbyloxycarbonyl group, some or all of the hydrogen atoms in the alkyl, alkyloxy, alkenyl, alkynyl, and hydrocarbyloxycarbonyl groups may be substituted by fluorine, chlorine, bromine, iodine, trifluoromethyl, trifluoromethoxy, trifluorothio, hydroxy, cyano, nitro or sulfonyl moiety, some constituent —CH2— in the alkyl, alkyloxy, alkenyl, alkynyl, and hydrocarbyloxycarbonyl groups may be replaced by an ester bond or ether bond, and some or all of the hydrogen atoms in the phenyl group may be substituted by fluorine, C1-C4 fluoroalkyl, C1-C4 fluoroalkyloxy, C1-C4 fluoroalkylthio, cyano or nitro moiety,
- R2 to R4 are each independently halogen or a C1-C20 hydrocarbyl group which may contain at least one atom selected from oxygen, sulfur, nitrogen and halogen, R2 and R3 may bond together to form a ring with the sulfur atom to which they are attached,
- (B) an acid generator in the form of a sulfonium salt consisting of a sulfonate anion having fluorine on the carbon atom at α- and/or β-position of the sulfo group and a sulfonium cation, and
- (C) a base polymer comprising repeat units of at least one type selected from repeat units (a1) having a carboxy group whose hydrogen is substituted by an acid labile group and repeat units (a2) having a phenolic hydroxy group whose hydrogen is substituted by an acid labile group.
2 more elements
Dependencies are inferred from the claim text.