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US 2022/0356282 A1Published application
Process for producing optical molding materials
AssigneeRohm Co., Ltd.
InventorsSteffen KRILL, Belaid Ait Aissa, Florian Zschunke, Gerhard Kõlbl, Rüdiger Carloff
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Abstract
A process can be used for producing optical molding materials on the basis of methyl methacrylate (MMA). The MMA produced by an optimized method and the molding materials feature in particular a very low yellowness index. This MMA has been produced by direct oxidative esterification of methacrolein. An optimized workup of the reactor output from the oxidative esterification of methacrolein can be used for removing particularly discoloring byproducts. This process moreover has the advantage that fewer demands are placed on plant apparatus configuration.
Claims15
1-20. (canceled)
21:
- An alkyl methacrylate, produced by a process comprising:
- a. producing methacrolein in a reactor I,
- b. oxidatively esterifying the methacrolein in the presence of an alcohol, oxygen, and a heterogeneous noble metal-containing catalyst, at a water content between 0.1% and 10% by weight and a pH between 5 and 8 in at least one reactor II, to obtain a reactor output,
- c. after-treating the reactor output from the at least one reactor II in a reactor III, to obtain a crude alkyl methacrylate, and
- d. isolating and purifying the crude alkyl methacrylate from the reactor III,
- wherein the alkyl methacrylate comprises dimethoxyisobutene (DMIB) and methyl isobutyrate, and has a DMIB content of less than 300 ppm and a methyl isobutyrate content of less than 600 ppm, and
- wherein in process step c, in the reactor III, a water content is at least 0.5% by weight higher than in the at least one reactor II.
4 more elements
22:
- The alkyl methacrylate according to claim 21, wherein the alkyl methacrylate has a content of DMIB of less than 100 ppm and a methyl isobutyrate content of less than 300 ppm.
23:
- An alkyl methacrylate resin, produced from a monomer mixture containing:
- 30% to 100% by weight of the alkyl methacrylate according to claim 21,
- 0% to 70% by weight of a monomer copolymerizable with the alkyl methacrylate and/or an alkyl methacrylate produced by another process, and
- optionally, 0% to 5% by weight of an added substance.
1 more element
24:
- The alkyl methacrylate according to claim 21, wherein process step a in the reactor I is a reaction of propanal with formaldehyde in the presence of at least one acid and optionally, in the presence of an amine.
25:
- The process according to claim 21, wherein the alcohol is methanol and the alkyl methacrylate is methyl methacrylate (MMA).
26:
- The alkyl methacrylate according to claim 21, wherein in process step c, an organic and/or a mineral acid is added to the reactor III to adjust the pH, and wherein in the reactor III, dimethoxyisobutene is cleaved with water to obtain methacrolein and methanol.
27:
- The alkyl methacrylate according to claim 26, wherein the acid is sulfuric acid, and wherein a liquid phase in the reactor III is at a temperature between 0° C. and 140° C.
28:
- The alkyl methacrylate according to claim 26, wherein the reactor III is a distillation column into the bottom of which the acid and optionally additional water are introduced, and in which methacrolein and portions of a remaining alcohol are separated from the crude alkyl methacrylate at a temperature between 50° C. and 100° C.
29:
- The alkyl methacrylate according to claim 26, wherein the reactor III is a phase separator into whose aqueous phase the acid and optionally additional water are introduced, and in which an aqueous phase containing a remaining alcohol is separated from an organic phase containing the crude alkyl methacrylate at a temperature between 0° C. and 100° C.
30:
- The alkyl methacrylate according to claim 26, wherein the reactor III is a tubular reactor in which the reactor output from the at least one reactor 1 having an internal temperature between 50° C. and 140° C., the acid, and optionally additional water are mixed to obtain a mixture, and the mixture is subsequently passed into a distillation column or a phase separator.
31:
- The alkyl methacrylate according to claim 26, wherein the reactor III is a continuously operated stirred reactor in which the reactor output from the at least one reactor II having an internal temperature between 50° C. and 140° C., the acid, and optionally additional water are mixed to obtain a mixture, and the mixture is subsequently passed into a distillation column or a phase separator.
32:
- The alkyl methacrylate according to claim 21, wherein in process step d, isolation and purification stages comprise at least one phase separator, at least one high boiler column, at least one low boiler column, and optionally at least one crystallization chamber,
- wherein the at least one phase separator, the at least one high boiler column, the at least one low boiler column, and optionally the at least one crystallization chamber are traversed in series.
33:
- A method for producing a transparent article, the method comprising:
- molding an alkyl methacrylate resin comprising the alkyl methacrylate according to claim 21 into a transparent article,
- wherein the transparent article is at least one selected from the group consisting of an optically conductive sheet, a headlight lens, a headlight cover, a cover for a light source, a display cover, a noise barrier, and a construction material for a greenhouse.
34:
- A method for producing a colored article, the method comprising:
- molding an alkyl methacrylate resin comprising the alkyl methacrylate according to claim 21 into a colored article,
- wherein the colored article is at least one selected from the group consisting of a molding in covers, a molding in a pillar trim, and a molding in decorative strips in passenger car interior and/or exterior applications.