Waterborne polyurethane dispersion and method for preparing the same
AssigneesDow Silicones Corporation, Dow Global Technologies LLC
InventorsYanli Feng, Hongyu Chen, Shaoguang Feng, Huan Chen, Lili Shi, Xiuyuan Ni, Lingyun Pang, Ming Bao
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Abstract
A waterborne polyurethane dispersion is provided. The waterborne polyurethane dispersion comprises residual moiety of a hydroxy-terminated siloxane compound in the main chain and exhibits good anti-stickiness while retaining superior mechanical properties. A laminated synthetic leather article prepared with said waterborne polyurethane dispersion as well the method for preparing the synthetic leather article are also provided.
Claims14
A waterborne polyurethane dispersion comprising polyurethane particles dispersed in water, wherein the waterborne polyurethane dispersion is derived from:
- (A) an isocyanate component comprising one or more compounds having at least two isocyanate groups;
- (B) an isocyanate-reactive component comprising one or more compounds having at least two isocyanate-reactive groups;
- (C) a hydroxy-terminated siloxane compound represented by Formula I:
- wherein each of R1 and R4 independently represents a methylene optionally substituted with one or two substituents selected from the group consisting of C1-C5 alkyl, C1-C5 alkoxy, C6-C12 aryl, C6-C12 aryloxy and halogen;
- each of R2 and R3 independently represents a C1-C6 alkylene oxide group optionally substituted with one or more substituents selected from the group consisting of C1-C5 alkyl, C1-C5 alkoxy, C6-C12 aryl, C6-C12 aryloxy and halogen;
- each of R5, R6, R7, R8, R9 and R10 independently represents a C1-C5 alkyl optionally substituted with one or more substituents selected from the group consisting of C1-C5 alkyl, C1-C5 alkoxy, C6-C12 aryl, C6-C12 aryloxy and halogen;
- wherein each of a and e is independently an integer of 0 to 30;
- each of b and d is independently an integer of 5 to 30;
- and c is an integer of 3 to 100;
- (D) a catalyst;
- (E) an emulsifier;
- (F) a chain extender;
- and
- (G) water.
Dependencies are inferred from the claim text.