Compound
AssigneeSumitomo Chemical Company, Limited
InventorsYuji ASATSU, Shoichi OZAWA, Ai KOBASHI
Life of this patent
Estimating the term…
Abstract
A compound having a molecular weight of 3000 or less and a partial structure represented by Formula (X) is provided: In Formula (X), a ring W1 represents a ring structure having at least one double bond as a constituent element of the ring and having no aromaticity; and R3 represents a heterocyclic group, a halogen atom, a nitro group, a cyano group, a hydroxy group, a thiol group, a carboxy group, —SF5, —SF3, —SO3H, —SO2H, an aliphatic hydrocarbon group having 1 to 25 carbon atoms which may have a substituent, or an aromatic hydrocarbon group having 6 to 18 carbon atoms which may have a substituent.
Claims34
A compound having a molecular weight of 3000 or less and a partial structure represented by Formula (X):
- [in Formula (X), a ring W1 represents a ring structure having at least one double bond as a constituent element of the ring and having no aromaticity;
- R3 represents a heterocyclic group, a halogen atom, a nitro group, a cyano group, a hydroxy group, a thiol group, a carboxy group, —SF5, —SF3, —SO3H, —SO2H, an aliphatic hydrocarbon group having 1 to 25 carbon atoms which may have a substituent, or an aromatic hydrocarbon group having 6 to 18 carbon atoms which may have a substituent, and —CH2— or —CH═ contained in the aliphatic hydrocarbon group or the aromatic hydrocarbon group may be substituted with —O—, —S—, —NR1A—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —CONR2A—, —O—CO—NR3A—, —NR4A—CO—, —NR5A—CO—O—, —NR6A—CO—NR7A—, —CO—S—, —S—CO—S—, —S—CO—NR8A—, —NR9A—CO—S—, —CS—, —O—CS—, —CS—O—, —NR10A—CS—, —NR11A—CS—S—, —S—CS—, —CS—S—, —S—CS—S—, —SO—, or —SO2—;
- and
- R1A, R2A, R3A, R4A, R5A, R6A, R7A, R8A, R9A, R10A, and R11A each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms].
A method for producing a compound represented by Formula (I):
- [in Formula (I), the ring W1, R1, R2, R3, R4, and R5 have the same meaning as described above],
- the method comprising a step of reacting a compound represented by Formula (I-1):
- [in Formula (I-1),
- a ring W1 represents a ring structure having at least one double bond as a constituent element of the ring and having no aromaticity;
- R1 and R2 each independently represent a hydrogen atom, a heterocyclic group, a halogen atom, a nitro group, a cyano group, a hydroxy group, a thiol group, a carboxy group, —SF5, —SF3, —SO3H, —SO2H, an aliphatic hydrocarbon group having 1 to 25 carbon atoms which may have a substituent, or an aromatic hydrocarbon group having 6 to 18 carbon atoms which may have a substituent, and —CH2— or —CH═ contained in the aliphatic hydrocarbon group or the aromatic hydrocarbon group may be substituted with —NR12A—, —SO2—, —CO—, —O—, —COO—, —OCO—, —CONR13A—, —NR14A—CO—, —S—, —SO—, —CF2— or —CHF—;
- R1 and R2 may be linked to each other to form a ring;
- R3 represents a heterocyclic group, a halogen atom, a nitro group, a cyano group, a hydroxy group, a thiol group, a carboxy group, —SF5, —SF3, —SO3H, —SO2H, an aliphatic hydrocarbon group having 1 to 25 carbon atoms which may have a substituent, or an aromatic hydrocarbon group having 6 to 18 carbon atoms which may have a substituent, and —CH2— or —CH═ contained in the aliphatic hydrocarbon group or the aromatic hydrocarbon group may be substituted with —O—, —S—, —NR1A—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —CONR2A—, —O—CO—NR3A—, —NR4A—CO—, —NR5A—CO—O—, —NR6A—CO—NR7A—, —CO—S—, —S—CO—S—, —S—CO—NR8A—, —NR9A—CO—S—, —CS—, —O—CS—, —CS—O—, —NR10A—CS—, —NR11A—CS—S—, —S—CS—, —CS—S—, —S—CS—S—, —SO—, or —SO2—;
- R2 and R3 may be bonded to each other to form a ring;
- and
- R1A, R2A, R3A, R4A, R5A, R6A, R7A, R8A, R9A, R10A, R11A, R12A, R13A, and R14A each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms], with a compound represented by Formula (I-2):
- [in Formula (I-2), R4 and R5 each independently represent an electron-withdrawing group;
- and R4 and R5 may be bonded to each other to form a ring].
A method for producing a compound represented by Formula (I):
- [in Formula (I), the ring W1, R1, R2, R3, R4, and R5 have the same meaning as described above;
- and R2 and R3 may be bonded to each other to form a ring],
- the method comprising a step of reacting a compound represented by Formula (I-7):
- [in Formula (I-7),
- a ring W1 represents a ring structure having at least one double bond as a constituent element of the ring and having no aromaticity;
- R3 represents a heterocyclic group, a halogen atom, a nitro group, a cyano group, a hydroxy group, a thiol group, a carboxy group, —SF5, —SF3, —SO3H, —SO2H, an aliphatic hydrocarbon group having 1 to 25 carbon atoms which may have a substituent, or an aromatic hydrocarbon group having 6 to 18 carbon atoms which may have a substituent, and —CH2— or —CH═ contained in the aliphatic hydrocarbon group or the aromatic hydrocarbon group may be substituted with —O—, —S—, —NR1A—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —CONR2A—, —O—CO—NR3A—, —NR4A—CO—, —NR5A—CO—O—, —NR6A—CO—NR7A—, —CO—S—, —S—CO—S—, —S—CO—NR8A—, —NR9A—CO—S—, —CS—, —O—CS—, —CS—O—, —NR10A—CS—, —NR11A—CS—S—, —S—CS—, —CS—S—, —S—CS—S—, —SO—, or —SO2—;
- R1A, R2A, R3A, R4A, R5A, R6A, R7A, R8A, R9A, R10A, and R11A each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms;
- R4 and R5 each independently represent an electron-withdrawing group;
- and
- R4 and R5 may be bonded to each other to form a ring], with a compound represented by Formula (I-6):
- [in Formula (I-6),
- R1 and R2 each independently represent a hydrogen atom, a heterocyclic group, a halogen atom, a nitro group, a cyano group, a hydroxy group, a thiol group, a carboxy group, —SF5, —SF3, —SO3H, —SO2H, an aliphatic hydrocarbon group having 1 to 25 carbon atoms which may have a substituent, or an aromatic hydrocarbon group having 6 to 18 carbon atoms which may have a substituent, and —CH2— or —CH═ contained in the aliphatic hydrocarbon group or the aromatic hydrocarbon group may be substituted with —NR12A—, —SO2—, —CO—, —O—, —COO—, —OCO—, —CONR13A—, —N14A—CO—, —S—, —SO—, —SO2—, —CF2— or —CHF—;
- R1 and R2 may be linked to each other to form a ring;
- R12A, R13A, and R14A each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms].
Dependencies are inferred from the claim text.