Coating compositions

A method for coating a substrate material, comprising:

• optionally applying an adhesion promoter onto the substrate surface;
• applying onto the substrate surface a coating composition comprising:
• at least one cyclic olefin selected from the group consisting of Formulae (I), (II), and (III), optionally at least one linear olefin of Formula (IV);
• at least one coating additive;
• and
• at least one curing agent selected from an organometallic complex, a free radical initiator, and a cationic initiator;
• wherein the cyclic olefin of Formulae (I), (II), and (III), and the linear olefin of Formula (IV) have the following structures:
• wherein:
• Ra is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted linear or branched C2-24 alkenyl, halogen, —C(O)Rf, —CH2—C(O)Rf, —ORg, —CH2—ORg, —CN, —NO2, —CF3, —P(O)(ORh)2, —OP(O)(ORh)2, —S(O)2ORh, —OS(O)2Rh, optionally substituted heterocycle, —CH2-(optionally substituted heterocycle), optionally substituted C3-10 cycloalkyl, —CH2-(optionally substituted C3-10 cycloalkyl), optionally substituted C5-24 aryl, —CH2-(optionally substituted C5-24 aryl), optionally substituted C3-12 cycloalkenyl, —CH2-(optionally substituted C3-12 cycloalkenyl), C(Rh)(Ri)COORj, —C(Rh)(Ri)C(O)H, —C(Rh)(Ri)C(O)Rk, —C(Rh)(Ri)CRl(ORm)(ORn), —C(Rh)(Ri)C(O)NRoRp, —C(Rh)(Ri)C(O)NRoORn;
• Rb is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted linear or branched C2-24 alkenyl, halogen, —C(O)Rf, —CH2—C(O)Rf, —ORg, —CH2—ORg, —CN, —NO2, —CF3, —P(O)(ORh)2, —OP(O)(ORh)2, —Si(ORk)3—S(O)2ORh, —OS(O)2Rh, optionally substituted heterocycle, spiro optionally substituted heterocycle, —CH2-(optionally substituted heterocycle), optionally substituted C3-10 cycloalkyl, —CH2-(optionally substituted C3-10 cycloalkyl), optionally substituted C5-24 aryl, —CH2-(optionally substituted C5-24 aryl), optionally substituted C3-12 cycloalkenyl, —CH2-(optionally substituted C3-12 cycloalkenyl), C(Rh)(Ri)COORj, —C(Rh)(Ri)C(O)H, —C(Rh)(Ri)C(O)Rk, —C(Rh)(Ri)CRl(ORm)(ORn), —C(Rh)(Ri)C(O)NRoRp, —C(Rh)(Ri)C(O)NRoORn;
• Rc is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted linear or branched C2-24 alkenyl, halogen, —C(O)Rf, —CH2—C(O)Rf, —ORg, —CH2—ORg, CN, NO2, —CF3, —P(O)(ORh)2, —OP(O)(ORh)2, —S(O)2ORh, —OS(O)2Rh, optionally substituted heterocycle, —CH2-(optionally substituted heterocycle), optionally substituted C3-10 cycloalkyl, —CH2-(optionally substituted C3-10 cycloalkyl), optionally substituted C5-24 aryl, —CH2-(optionally substituted C5-24 aryl), optionally substituted C3-12 cycloalkenyl, —CH2-(optionally substituted C3-12 cycloalkenyl), C(Rh)(Ri)COORj, —C(Rh)(Ri)C(O)H, —C(Rh)(Ri)C(O)Rk, —C(Rh)(Ri)CRl(ORm)(ORn), —C(Rh)(Ri)C(O)NRoRp, —C(Rh)(Ri)C(O)NRoORn;
• Rd is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted linear or branched C2-24 alkenyl, halogen, —C(O)Rf, —CH2—C(O)Rf, —ORg, —CH2—ORg, CN, NO2, —CF3—P(O)(ORh)2, —OP(O)(ORh)2, —S(O)2ORh, —OS(O)2Rh, optionally substituted heterocycle, —CH2-(optionally substituted heterocycle), optionally substituted C3-10 cycloalkyl, —CH2-(optionally substituted C3-10 cycloalkyl), optionally substituted C5-24 aryl, —CH2-(optionally substituted C5-24 aryl), optionally substituted C3-12 cycloalkenyl, —CH2-(optionally substituted C3-12 cycloalkenyl), C(Rh)(Ri)COORj, —C(Rh)(Ri)C(O)H, —C(Rh)(Ri)C(O)Rk, —C(Rh)(Ri)CRl(ORm)(ORn), —C(Rh)(Ri)C(O)NRoRp, —C(Rh)(Ri)C(O)NRoORn;
• each Rs is independently optionally substituted linear or branched C1-24 alkyl, optionally substituted linear or branched C2-24 alkenyl, halogen, —C(O)Rf, —CH2—C(O)Rf, —ORg, —CH2—ORg, —CN, —NO2, —CF3, —P(O)(ORh)2, —OP(O)(ORh)2, —S(O)2ORh, —OS(O)2Rh, optionally substituted heterocycle, —CH2-(optionally substituted heterocycle), optionally substituted C3-10 cycloalkyl, —CH2-(optionally substituted C3-10 cycloalkyl), optionally substituted C5-24 aryl, —CH2-(optionally substituted C5-24 aryl), optionally substituted C3-12 cycloalkenyl, —CH2-(optionally substituted C3-12 cycloalkenyl), C(Rh)(Ri)COORj, —C(Rh)(Ri)C(O)H, —C(Rh)(Ri)C(O)Rk, —C(Rh)(Ri)CRl(ORm)(ORn), —C(Rh)(Ri)C(O)NRoRp, —C(Rh)(Ri)C(O)NRoORn;
• t is 0, 1, 2, 3, 4, 5, or 6;
• Rf is OH, ORk, NRgRh, optionally substituted linear or branched C1-24 alkyl, optionally substituted C3-10 cycloalkyl, optionally substituted heterocycle, optionally substituted C5-24 aryl, or optionally substituted C3-12 cycloalkenyl;
• Rg is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted C3-10 cycloalkyl, optionally substituted heterocycle, optionally substituted C5-24 aryl, optionally substituted linear or branched C2-24 alkenyl, —C(O)-(optionally substituted C5-24 aryl), —C(O)-(optionally substituted linear or branched C2-24 alkenyl), or optionally substituted C3-12 cycloalkenyl;
• Rh is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted C3-10 cycloalkyl, optionally substituted heterocycle, optionally substituted C5-24 aryl, or optionally substituted C3-12 cycloalkenyl;
• Ri is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted C3-10 cycloalkyl, optionally substituted heterocycle, optionally substituted C5-24 aryl, or optionally substituted C3-12 cycloalkenyl;
• Rj is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted C3-10 cycloalkyl, optionally substituted heterocycle, optionally substituted C5-24 aryl, or optionally substituted C3-12 cycloalkenyl;
• Rk is optionally substituted linear or branched C1-24 alkyl, optionally substituted C3-10 cycloalkyl, optionally substituted heterocycle, optionally substituted C5-24 aryl, or optionally substituted C3-12 cycloalkenyl;
• Rl is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted C3-10 cycloalkyl, optionally substituted heterocycle, optionally substituted C5-24 aryl, or optionally substituted C3-12 cycloalkenyl;
• Rm is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted C3-10 cycloalkyl, optionally substituted heterocycle, optionally substituted C5-24 aryl, or optionally substituted C3-12 cycloalkenyl;
• Rn is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted C3-10 cycloalkyl, optionally substituted heterocycle, optionally substituted C5-24 aryl, or optionally substituted C3-12 cycloalkenyl;
• Ro is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted C3-10 cycloalkyl, optionally substituted heterocycle, optionally substituted C5-24 aryl, or optionally substituted C3-12 cycloalkenyl;
• Rp is H, optionally substituted linear or branched C1-24 alkyl, optionally substituted C3-10 cycloalkyl, optionally substituted heterocycle, optionally substituted C5-24 aryl, or optionally substituted C3-12 cycloalkenyl;
• and
• z is 0, 1, 2, or 3;
• and at least one metal carbene metathesis catalyst, and at least one additive;
• and
• curing the coating applied on the substrate surface.