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US 2022/0106488 A1Published application
Grinding Aid for Titanium Dioxide Particles
AssigneeKronos International, Inc.
InventorsMariusz Molon, Nicole Kolmer-Anderl, Janine Siekman, Sebastian Doedt
Life of this patent
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Abstract
The present invention relates to a grinding aid as well as a grinding method. Further, the present invention pertains to a titanium dioxide particle with a layer comprising a grinding aid as described herein and the use of said titanium dioxide particle in various applications.
Claims30
A grinding aid for grinding titanium dioxide particles selected from the group consisting of silicate, silicate minerals, not including asbestos;
- silylated fumed silica, excluding asbestos;
- silylated precipitated silica;
- bentonite;
- zinc oxide;
- kaolin;
- boron nitride;
- mica;
- hydromagnesite;
- wollastonite;
- cristobalite;
- quartz;
- dolomite;
- huntite;
- siliceous earth;
- soda earth;
- manganese phosphite, calcium hydroxide;
- calcium oxide;
- magnesium hydroxide;
- magnesium oxide;
- antimony oxide;
- potassium hydroxide;
- sodium hydroxide;
- sodium sulfide;
- zinc sulfide;
- molybdenum disulfide;
- sodium borate;
- iron oxide;
- cupper iodide;
- aluminum oxide;
- sodium bisulfite;
- sodium nitrite;
- potassium iodide;
- sodium iodide;
- sulfur;
- sodium sulfite;
- potassium bromide;
- sodium thiosulfate;
- manganese chloride;
- copper bromide;
- barium nitrate;
- calcium chloride;
- manganese hypophosphite;
- lithium iodide;
- aluminum magnesium hydroxycarbonate;
- manganese oxide;
- calcium sulfoaluminate;
- barium tetraborate;
- ozocerite;
- pyrophyllite;
- hydrotalcite;
- manganese hydroxide;
- iron phosphide;
- barium hydroxide;
- zinc hydroxide;
- aluminum hydroxide;
- magnesium sodium fluoride silicate;
- titanium nitride;
- salts of acetyl acetic acids;
- C2-C24, aliphatic, linear chain, monocarboxylic acids, from natural fats and oils, and their mono-, di- and triglycerol esters, their branched fatty acids in naturally occurring amounts are included;
- C2-C24, aliphatic, linear monocarboxylic acids and their mono-, di- and triglycerol esters;
- esters of aliphatic monocarboxylic acids (C6-C22) with polyglycerol;
- aliphatic, monovalent, saturated, linear, primary (C4-C24) alcohols;
- linear with even number of carbon atoms (C12-C20) alkyl dimethylamines;
- alkyl(C8-C22)sulfonic acids;
- linear chain, primary, alkyl(C8-C22)sulfuric acids with even number of carbon chain;
- N,N-bis(2-hydroxyethyl)alkyl(C8-C18)amine;
- N,N-bis(2-hydroxyethyl)alkyl(C8-C18)amine hydrochloride;
- ethyl hydroxy methylcellulose;
- ethyl hydroxy propyl cellulose;
- glycine and salts thereof;
- lysine and salts thereof;
- methyl hydroxy methyl cellulose;
- polyacrylic acid and salts thereof;
- polyesters of 1,2-propanediol and/or 1,3- and/or 1,4-butanediol and/or polypropylene glycol with adipic acid, also with terminal acetic acid, or C12-C18 fatty acids, or n-octanol and/or n-decanol;
- polyethylene glycol (EO=1-50)-monoalkyl ether (linear and branched, C8-C20)-sulfate and salts thereof;
- propyl hydroxyethyl cellulose;
- propyl hydroxy methyl cellulose;
- propyl hydroxy propyl cellulose;
- sorbitol;
- ascorbic acid;
- hexadecyl trimethyl ammonium bromide;
- palmitic acid;
- stearic acid;
- ethylene diamine tetraacetic acid;
- benzoic acid;
- salicylic acid;
- camphor;
- citric acid;
- tartaric acid;
- 2,2′-methylene bis(4-ethyl-6-tert-butylphenol);
- o-phthalic acid;
- propyl 4-hydroxybenzoate;
- 4,4′-thiobis(6-tert-butyl-3-methylphenol);
- 2,2′-dihydroxy-5,5′-dichloro diphenylmethane;
- methyl 4-hydroxybenzoate;
- hexamethylene tetramine;
- caprolactam;
- 12-hydroxystearic acid;
- 2,4,6-triamino-1,3,5-triazine;
- succinic acid;
- maleic acid;
- fumaric acid;
- N,N′-ethylene-bis-stearamide;
- N,N′-ethylene-bis-oleamide;
- glutaric acid;
- erucic acid;
- pentaerythritol;
- 2,2′-methylenebis(4-methyl-6-tert-butylphenol);
- benzophenone;
- ethyl 4-hydroxybenzoate;
- Propyl gallate;
- triisopropanolamine;
- levulinic acid;
- adipic acid;
- sucrose octaacetate;
- dipentaerythritol;
- diphenyl sulfone;
- 2,6-di-tert-butyl-p-cresol;
- 2,2′-dihydroxy-4-methoxybenzophenone;
- 2,4-Dihydroxybenzophenone;
- 2-hydroxy-4-methoxybenzophenone;
- ascorbyl palmitate;
- butyl lactate;
- malonic acid;
- lauric acid;
- oxalic acid;
- oleamide;
- n-decanoic acid;
- silicon carbide;
- dicyandiamide;
- arachidic acid;
- lignoceric acid;
- 4,4′-dihydroxybenzophenone;
- octyl gallate;
- dodecyl gallate;
- 1,2-propylene glycol monostearate;
- 4,4′-bis(2-benzoxazolyl)stilbene;
- 2-hydroxy-4-n-octyloxybenzophenone;
- 2-(2′-hydroxy-5′-methylphenyl)benzotriazole;
- pyrophosphoric acid;
- dioctadecyl disulfide;
- crotonic acid;
- 2,6-di-tert-butyl-4-ethylphenol;
- isopropyl-4-hydroxybenzoate;
- tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate];
- malic acid;
- montan wax;
- candelilla wax;
- carnauba wax;
- carboxymethyl cellulose;
- cellulose;
- cellulose acetate butyrate;
- ethyl cellulose;
- ethyl hydroxyethyl cellulose;
- methyl ethyl cellulose;
- hydroxyethyl cellulose;
- hydroxypropyl cellulose;
- hydroxypropyl methylcellulose;
- methyl cellulose;
- food starch;
- hydroxyethyl starch;
- alginic acid;
- 1,2-propylene glycol alginate;
- hydroxyethylmethyl cellulose;
- hydroxypropyl starch;
- alpha-dextrin;
- boric acid;
- ascorbyl stearate;
- glycerin tribehenate;
- polyethylene glycol;
- polypropylene glycol;
- sorbitan monopalmitate;
- sorbitan tristearate;
- sorbitan monostearate;
- 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-1,3,5-triazin-2,4,6(1H,3H,5H)-trion;
- glyceryl monobehenate;
- tris(2,4-di-tert-butylphenyl)phosphite;
- dibenzyliden sorbitol;
- carboxymethyl ethyl cellulose;
- carboxymethyl methyl cellulose;
- hydroxy methylcellulose;
- monoethyl-3,5-di-tert-butyl-4-hydroxy-benzylphosphonate and calcium salt;
- 1-(2-hydroxyethyl)-4-hydroxy-2,2,6,6-tetramethylpiperidine dimethyl succinate and a copolymer;
- N-methacryloyloxyethyl-N,N-dimethyl-N-carboxymethyl ammonium chloride or sodium salt-octadecyl methacrylate-ethyl methacrylate-cyclohexyl methacrylate-N-vinyl-2-pyrrolidone, copolymers;
- hydrolyzed starch;
- polyethylene glycol(EO=2-6)-monoalkyl (C16-C18)-ether;
- regenerated cellulose;
- -cresol-dicyclopentadiene-isobutylene and copolymers thereof;
- bis(polyethylene glycol) hydroxymethyl phosphonate;
- polyethylene glycol-30-dipolyhydroxystearate;
- 2,2′-oxamidobis[ethyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate];
- poly[6-[(1,1,3,3-tetramethylbutyl)amino]-1,3,5-triazine-2,4-diyl]-[(2,2,6,6-tetramethyl-4-piperidyl)imino-hexamethylene-[(2,2,6,6-tetramethyl-4-piperidyl)imino];
- bis(4-ethylbenzylidene)sorbitol;
- 2,2′,2″-nitrilo(triethyl-tris(3,3′,5,5′-tetra-tert-butyl-1,1′-bi-phenyl-2,2′-diyl)phosphite);
- bis(2,6-di-tert-butyl-4-methylphenyl)pentaerythritol diphosphite;
- 2,2′-methylene-bis(4,6-di-tert-butylphenyl)sodium phosphate;
- bis(methylbenzylidene)sorbitol;
- 2,4-bis(octylthiomethyl)-6-methylphenol;
- 2,4-bis(dodecylthiomethyl)-6-methylphenol;
- 2,2′-Ethylidene-bis(4,6-di-tert-butylphenyl)fluorophosphonite;
- reaction product of di-tert-butylphosphonite with biphenyl, produced by condensation of 2,4-di-tert-butylphenol with the Friedel-Crafts reaction product of phosphorus trichloride and biphenyl;
- 2,4-di-tert-pentyl-6-[1-(3,5-di-tert-pentyl-2-hydroxyphenyl)ethyl]phenyl acrylate;
- 3,3-bis(methoxymethyl)-2,5-dimethylhexane;
- 2,4-dimethyl-6-(1-methylpentadecyl)phenol;
- bis(3,4-dimethylbenzylidene)sorbitol;
- 1,2-bis(3-aminopropyl)ethylenediamine, polymer with N-butyl-2,2,6,6-tetramethyl-4-piperidineamine and 2,4,6-trichloro-1,3,5-triazine;
- N,N′-dicyclohexyl-2,6-naphthalene dicarboxamide;
- pentaerythritol tetrakis (2-cyano-3,3-diphenyl acrylate);
- 9,9-bis(methoxymethyl)fluorene;
- 1,3,5-tris(4-benzoylphenol)benzene;
- polydimethylsiloxane with 3-aminopropyl end groups, polymer with 1-isocyanato-3-isocyanatomethyl-3,5,5-trimethylcyclohexane;
- 1,3,5-tris(2,2-dimethylpropanamido)benzene;
- hydrogenated homopolymers and/or copolymers prepared from 1-hexene and/or 1-octene and/or 1-decene and/or 1-dodecene and/or 1-tetradecene with a molecular weight of 440 to 12,000 g/mol;
- N,N′-bis(2,2,6,6-tetramethyl-4-piperidyl)-N,N′-diformylhexamethylenediamine;
- 2,2′-(1,4-phenylen)bis((4H-3,1-benzoxazin-4-on);
- polyester of adipic acid with 1,3-butanediol, 1,2-propanediol and 2-ethyl-1-hexanol;
- polyethylene glycol ethers (EO=1-50) of linear and branched primary alcohols (C8-C22);
- aliphatic linear C2-C24 monocarboxylic acids from natural oils and fats, lithium salt;
- ethoxylated secondary alcohols with C12-C14 with a beta-(2-hydroxyethoxy) group;
- alpha-alkenes (C20-C24), copolymer with maleic anhydride, reaction product with 4-amino-2,2,6,6-tetramethylpiperidine;
- bis(4-propylbenzylidene)propylsorbitol;
- neopentyl glycol, diesters and monoesters with benzoic acid and 2-ethylhexanoic acid;
- oxidized polyethylene waxes;
- sulfosuccinic acid, alkyl (C4-C20) or cyclohexyl diesters and salts thereof;
- sulfosuccinic acid monoalkyl (C10-C16) polyethylene glycol esters and salts thereof;
- cis-1,2-cyclohexanedicarboxylic acid and salts thereof;
- cis-endo-bicyclo[2.2.1]heptane-2,3-dicarboxylic acid and salts thereof;
- neodecanoic acid and salts thereof;
- pimelic acid and salts thereof;
- stearoyl-2-lactylate and salts thereof;
- N,N′,N″-tris(2-methylcyclohexyl)-1,2,3-propane-tricarboxamide;
- poly(12-hydroxystearic acid) stearate;
- fatty acids (C8-C22) from animal or vegetable fats and oils, esters with monohydric, primary, saturated, aliphatic, C3-C22 branched alcohols;
- fatty acids (C8-C22) from animal or vegetable fats and oils, esters with linear, monohydric, primary, saturated, aliphatic alcohols (C1-C22);
- fatty acids (C8-C22), esters with pentaerythritol and mixtures thereof.
232 more elements
Dependencies are inferred from the claim text.