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US 2022/0089873 A1Published application
Hydrophilic cyclodextrin-containing silicone gels
AssigneeWacker Chemie AG
InventorsAmitabha MITRA, Sarah BURKE, Feng WANG, Christian HARTMAN, Margaret WHITTON, Chelsea GRIMM
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Abstract
Solvent-swollen crosslinked silicone gels containing covalently bonded cyclodextrin groups are prepared by hydrosilylation. The swollen gels are storage stable, compatible with water and polar solvents, and display a significant water break effect.
Claims12
A solvent swollen hydrophilic silicone gel composition comprising:
- a crosslinked silicone elastomer containing at least one covalently bonded cyclodextrin moiety, prepared by hydrosilylative crosslinking of reactants (A), (B), and (C)
- (A) optionally, a cyclodextrin reactant comprising a cyclodextrin or cyclodextrin derivative which has been modified to contain an organic group containing aliphatic unsaturation or an organic group containing silicon-bonded hydrogen;
- (B) optionally, an organopolysiloxane having at least one aliphatically unsaturated group;
- wherein component (B) is not optional when component (A) is not present or where component (A) contains no aliphatic unsaturation;
- (C) an organopolysiloxane containing at least one silicon-bonded hydrogen atom, the hydrosilylative crosslinking being effected by hydrosilylating aliphatically unsaturated groups of (A), when present, and (B), by means of silicon-bonded hydrogen atoms of (A), when present, and (C), in the presence of a hydrosilylation catalyst (D), wherein at least one cyclodextrin moiety is present among reactants (A), (B), and (C),
- and wherein the hydrosilylative crosslinking is conducted in the presence of a swelling solvent, forming a swollen hydrophilic silicone gel or the hydrosilylative crosslinking is conducted without swelling solvent and a crosslinked elastomer formed in the hydrosilylative crosslinking is dispersed into a swelling solvent to form a swollen hydrophilic silicone gel.
3 more elements
Dependencies are inferred from the claim text.