Resole phenolic resins, processes of synthesis of said resins and use thereof
OwnerSergio Adriano Saraiva, Daniel Bisaninventors
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Abstract
The present invention relates to resole-type phenolic resin synthesis processes using lignin, to resole-type phenolic resins comprising aldehyde, lignin, a base, urea, and optionally phenol, as well as to the use of said phenolic resins for application as an adhesive.
Claims69
Phenolic resin synthesis process, characterized in that it comprises the steps of:
- a) mixing phenol, lignin and optionally aldehyde at a temperature range of 25 to 60° C. until fully homogenized;
- b) adding a catalyst;
- c) adding aldehyde until it reaches a temperature of 45 to 95° C.;
- d) keeping the obtained product at a temperature of 45 to 95° C.;
- e) adding catalyst to the obtained product;
- f) keeping the obtained product at a temperature ranging from 45 to 95° C.;
- g) adjusting the temperature of the obtained product to 40 to 70° C.;
- h) optionally adding a catalyst;
- i) adding urea;
- j) optionally keeping the obtained product at a temperature of 40 to 70° C.;
- and
- k) cooling to room temperature.
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Phenolic resin synthesis process, characterized in that it comprises the steps of:
- a) diluting a catalyst in water, at a temperature range of 25 to 60° C.;
- b) adding lignin at a temperature from 20 to 95° C.;
- c) cooling the product obtained to a temperature of 50 to 75° C.;
- d) adding aldehyde at a temperature of 50 to 85° C.;
- e) keeping the obtained product at a temperature of 60 to 95° C.;
- f) adding a catalyst;
- g) keeping the obtained product at a temperature ranging from 60 to 95° C.;
- h) adjusting the temperature of the obtained product to 40 to 70° C.;
- i) adding urea;
- j) keeping the obtained product at a temperature of 40 to 70° C.;
- and
- k) cooling to room temperature.
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Phenolic resin, characterizedd in that it comprises aldehyde, lignin, a base, urea, and, optionally, phenol.
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Dependencies are inferred from the claim text.