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US 2022/0089562 A1Published application
Sulfonium salt, photoacid generator, curable composition and resist composition
AssigneeSan-Apro Ltd.
InventorTakuto NAKAO
Life of this patent
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Abstract
Provided are a novel sulfonium salt having high photosensitivity to g-rays or h-rays; a novel photoacid generator containing a sulfonium salt that has high photosensitivity to g-rays or h-rays, has high solubility in solvents and cationically polymerizable compounds such as epoxy compounds, and has an excellent storage stability in compositions containing the cationically polymerizable compounds; and the like. The present invention relates to a sulfonium salt represented by the formula (1), a photoacid generator containing the sulfonium salt, and the like.
Claims17
A sulfonium salt represented by the following formula (1):
- wherein R1 and R2 each represent a C6-C30 aryl group, a C4-C30 heterocyclic hydrocarbon group, or a C1-C30 alkyl group, one or some of hydrogen atoms in the aryl group, the heterocyclic hydrocarbon group, or the alkyl group are optionally replaced by a substituent (t), the substituent (t) is at least one selected from the group consisting of C1-C18 alkyl groups, hydroxy groups, C1-C18 alkoxy groups, C2-C18 alkylcarbonyl groups, C7-C11 arylcarbonyl groups, C2-C19 acyloxy groups, C6-C20 arylthio groups, C1-C18 alkylthio groups, C6-C10 aryl groups, C4-C20 heterocyclic hydrocarbon groups, C6-C10 aryloxy groups, hydroxy (poly)alkyleneoxy groups represented by HO(-AO)q- (wherein AO represents at least one of an ethyleneoxy group or a propyleneoxy group, and q represents an integer of 1 to 5), and halogen atoms;
- R3 to R5 each represent an alkyl group, a hydroxy group, an alkoxy group, an alkylcarbonyl group, an arylcarbonyl group, an acyloxy group, an arylthio group, an alkylthio group, an aryl group, a heterocyclic hydrocarbon group, an aryloxy group, a hydroxy (poly)alkyleneoxy group, or a halogen atom;
- k, m, and n respectively represent the numbers of R3, R4, and R5;
- k represents an integer of 0 to 4;
- m represents an integer of 0 to 3;
- n represents an integer of 1 to 4;
- A represents a —O— group, a —S— group, a —SO— group, a —SO2— group, or a —CO— group;
- O represents an oxygen atom;
- S represents a sulfur atom;
- and X− represents a monovalent polyatomic anion.
7 more elements
Dependencies are inferred from the claim text.