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US 2022/0072522 A1Published application
Borylimide catalysts
AssigneeSCG Chemicals Co., Ltd.
InventorsPhilip Mountford, Benjamin A. Clough, Bowen Xie
Life of this patent
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Abstract
The present invention provides a borylimide catalyst and further relates to compositions comprising the borylimide catalysts and processes for the polymerisation of olefins (e.g. ethylene) using the borylimide catalysts or the compositions comprising the borylimide catalysts.
Claims20
A compound of Formula (I):
- wherein:
- M is selected from titanium, zirconium and hafnium;
- X1 and X2 are independently selected from halo, hydrogen, a phosphonate, sulfonate or boronate group, amino, (1-6C)alkyl, (1-6C)alkoxy, aryl, aryloxy and heterocycloalkyl (such as THF), wherein said (1-6C)alkyl, (1-6C)alkoxy, aryl and aryloxy groups may be optionally substituted with one of more groups selected from halo, oxo, hydroxy, amino, nitro, (1-6C)alkyl, (2-6C)alkenyl, (2-6C)alkynyl, (1-6C)haloalkyl, (1-6C)alkoxy, aryl and Si[(1-4C)alkyl]3;
- Y is BR1R2;
- Z is a polydentate ligand coordinated to M by at least 2 donor atoms Q, wherein each Q is independently selected from N, O, S and P;
- R1 and R2 are independently selected from NR3R4, OR5, SR6 and CR7R8R9;
- R3, R4, R5, R6, R7, R8 and R9 are independently selected from hydrogen, (1-6C)alkyl, (2-6C)alkenyl, (2-6C)alkynyl, aryl and heteroaryl, wherein said (1-6C)alkyl, (2-6C)alkenyl, (2-6C)alkynyl, aryl and heteroaryl groups are optionally substituted with one or more substituents selected independently from halo, hydroxy, amino, nitro, (1-6C)alkyl and (1-6C)haloalkyl;
- or R1 and R2 are linked, such that when taken in combination with the boron atom to which they are attached, they form a group:
- wherein ring A is a carbocyclic or heterocyclic ring, optionally substituted with one or more substituents selected independently from halo, hydroxy, amino, (1-6C)alkyl, (1-6C)alkoxy, (1-6C)haloalkyl, aryl and heteroaryl, wherein said aryl and heteroaryl groups are optionally substituted with one or more substituents selected independently from halo, hydroxy, amino, nitro, (1-6C)alkyl and (1-6C)haloalkyl.
6 more elements
Dependencies are inferred from the claim text.