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US 2022/0069240 A1Published application
Composition and organic light-emitting device including the same
AssigneesSamsung Electronics Co., Ltd., Samsung SDI Co., Ltd.
InventorsMyungsun SIM, Sunghun LEE, Yoonhyun Kwak, Jiwhan Kim, Jeoungin Yi, Mitsunori ITO, Wataru SOTOYAMA, Kum Hee LEE, Byoungki CHOI, Sunghyun JUNG, Dalho Huh, Hyungsun Kim
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Abstract
Provided are a composition and an organic light-emitting device including the same, wherein the composition includes a platinum-containing organometallic compound, a first compound, a second compound, and a third compound.
Claims20
A composition comprising:
- a platinum-containing organometallic compound, a first compound, a second compound, and a third compound,
- wherein the platinum-containing organometallic compound, the first compound, the second compound, and the third compound are different from each other,
- the first compound comprises at least one electron transport moiety,
- the second compound does not comprise an electron transport moiety,
- the third compound has a greater band gap than each of a band gap of the first compound and a bandgap of the second compound,
- a difference between an absolute value of a highest occupied molecular orbital (HOMO) energy level of the first compound and an absolute value of a HOMO energy level of the second compound is equal to or less than about 0.35 eV, and
- the HOMO energy levels of the first compound and the second compound are each measured using a DFT method with Gaussian program on structures structurally optimized using B3LYP/6-31G(d,p) functional and basis set.
4 more elements
A composition comprising:
- a platinum-containing organometallic compound, a first compound, a second compound, and a third compound,
- wherein the platinum-containing organometallic compound, the first compound, the second compound, and the third compound are different from each other,
- the first compound comprises at least one electron transport moiety,
- the second compound does not comprise an electron transport moiety,
- the third compound has a greater band gap than a band gap of the first compound and a band gap of the second compound,
- the platinum-containing organometallic compound is an organometallic compound represented by Formula 1-1 or 1-2:
- wherein, in Formulae 1-1 and 1-2,
- M is platinum (Pt),
- Y1 is O or S, and each of Y2 to Y4 is a chemical bond,
- each of X1 and X3 is C, and each of X2 and X4 is N,
- T1 is a single bond, a double bond, *—N(R51)—*′, *—B(R51)—*′, *—P(R51)—*′, *—C(R51)(R52)—*′, *—Si(R51)(R52)—*′, *—Ge(R51)(R52)—*′, *—S—*′, *—Se—*′, *—O—*′, *—C(═O)—*′, *—S(═O)—*′, *—S(═O)2—*—C(R51)=*′, *═C(R51)—*′, *—C(R51)═C(R52)—*′, *—C(═S)—*′, or *—C≡C—*′,
- T2 is a single bond, a double bond, *—N(R53)—*′, *—B(R53)—*′, *—P(R53)—*′, *—C(R53)(R54)—*′, *—Si(R53)(R54)—*′, *—Ge(R53)(R54)—*′, *—S—*′, *—Se—*′, *—O—*′, *—C(═O)-*′, *—S(═O)—*′, *—S(═O)2—*—C(R53)=*′, *═C(R53)—*′, *—C(R53)═C(R54)—*′, *—C(═S)—*′, or *—C≡C—*′,
- T3 is a single bond, a double bond, *—N(R55)—*′, *—B(R55)—*′, *—P(R55)—*′, *—C(R55)(R56)—*′, *—Si(R55)(R56)—*′, *—Ge(R55)(R56)—*′, *—S—*′, *—Se—*′, *—O—*′, *—C(═O)-*′, *—S(═O)—*′, *—S(═O)2—*—C(R55)=*′, *═C(R55)—*′, *—C(R55)═C(R56)—*′, *—C(═S)—*′, or *—C≡C*′,
- X11 is N or C-[(L11)a11-(R11)b11], X12 is N or C-[(L12)a12-(R12)b12], X13 is N or C-[(L13)a13-(R13)b13], and X14 is N or C-[(L14)a14-(R14)b14],
- X21 is N or C-[(L21)a21-(R21)b21], X22 is N or C-[(L22)a22-(R22)b22], and X23 is N or C-[(L23)a23-(R23)b23],
- X29 is O, S, C(R27)(R28), Si(R27)(R28), or N-[(L29)a29-(R29)b29],
- X31 is N or C-[(L31)a31-(R31)b31], X32 is N or C-[(L32)a32-(R32)b32], and X33 is N or C-[(L33)a33-(R33)b33],
- X41 is N or C-[(L41)a41-(R41)b41], X42 is N or C-[(L42)a42-(R42)b42], X43 is N or C-[(L43)a43-(R43)b43], and X44 is N or C-[(L44)a44-(R44)b44],
- L11 to L14, L21 to L23, L31 to L33, and L41 to L44 are each independently a single bond, a C5-C30 carbocyclic group unsubstituted or substituted with at least one R10a or a C1-C30 heterocyclic group unsubstituted or substituted with at least one R10a,
- a11 to a14, a21 to a23, a31 to a33, and a41 to a44 are each independently an integer from 1 to 10,
- R11 to R14, R21 to R23, R27 to R29, R31 to R33, and R41 to R44 are each independently hydrogen, deuterium, —F, —Cl, —Br, —I, —SF5, a hydroxyl group, a cyano group, a nitro group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a substituted or unsubstituted C1-C60 alkyl group, a substituted or unsubstituted C2-C60 alkenyl group, a substituted or unsubstituted C2-C60 alkynyl group, a substituted or unsubstituted C1-C60 alkoxy group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C1-C10 heterocycloalkyl group, a substituted or unsubstituted C3-C10 cycloalkenyl group, a substituted or unsubstituted C1-C10 heterocycloalkenyl group, a substituted or unsubstituted C6-C60 aryl group, a substituted or unsubstituted C6-C60 aryloxy group, a substituted or unsubstituted C6-C60 arylthio group, a substituted or unsubstituted C1-C60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group, —N(Q1)(Q2), —Si(Q3)(Q4)(Q5), —B(Q6)(Q7), or —P(═O)(Q8)(Q9),
- b11 to b14, b21 to b23, b29, b31 to b33, and b41 to b44 are each independently an integer from 1 to 10,
- two of R11 to R14 are optionally linked to each other form a C5-C30 carbocyclic group unsubstituted or substituted with at least one R10a or a C1-C30 heterocyclic group unsubstituted or substituted with at least one R10a,
- two of R21 to R23 are optionally linked to each other to form a C5-C30 carbocyclic group unsubstituted or substituted with at least one R10a or a C1-C30 heterocyclic group unsubstituted or substituted with at least one R10a,
- two of R31 to R33 are optionally linked to each other to form a C5-C30 carbocyclic group unsubstituted or substituted with at least one R10a or a C1-C30 heterocyclic group unsubstituted or substituted with at least one R10a, and
- two of R41 to R44 are optionally linked to each other to form a C5-C30 carbocyclic group unsubstituted or substituted with at least one R10a or a C1-C30 heterocyclic group unsubstituted or substituted with at least one R10a.
23 more elements
Dependencies are inferred from the claim text.