# US 2022/0034841 A1 · Discharge ionization detector

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- Number: US 2022/0034841 A1
- Document ID: US20220034841A1
- Status: Published application
- Kind: A1
- Application number: 17/341,486
- Filed: 2021-06-08
- Published: 2022-02-03
- Earliest claimed: 2020-07-31
- Assignees: Shimadzu Corporation
- Applicants: Shimadzu Corporation
- Inventors: Kei SHINADA
- Web page: https://patentgrep.com/patent/US20220034841A1

## CPC

- G01N 27/70: and measuring current or voltage
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

A discharge ionization detector includes: a gas passage (104, 120) through which an electric-discharge gas is to be passed; a plasma generation electrode (106-108) configured to generate an electric discharge in the gas passage so as to generate plasma from the electric-discharge gas; a sample-gas introduction section (124) through which a sample gas is introduced into the gas passage; a collection electrode (117) configured to collect ions generated from a sample with the plasma; a bias electrode (113) located between the plasma generation electrode and the collection electrode, and configured to create an electric field for guiding the charged particles to the collection electrode; and a DC power unit (131, 133) capable of independently controlling a voltage applied to the bias electrode and a voltage applied to the collection voltage. A peak-shape abnormality in a signal output can be suppressed by appropriately adjusting the voltages.

## Claims

### Claim 1

A discharge ionization detector comprising:
a gas passage through which an electric-discharge gas is to be passed;
a plasma generation electrode configured to generate an electric discharge in the gas passage so as to generate plasma from the electric-discharge gas in the gas passage by the electric discharge;
a sample-gas introduction section through which a sample gas is introduced into the gas passage;
a collection electrode provided in the gas passage and configured to collect charged particles generated from a sample component in the sample gas with the plasma;
a bias electrode located between the plasma generation electrode and the collection electrode, and configured to create, within the gas passage, an electric field for guiding the charged particles to the collection electrode; and
a DC power unit configured to produce a bias-electrode voltage to be applied to the bias electrode and a collection-electrode voltage to be applied to the collection voltage, where the bias-electrode voltage and the collection-electrode voltage are independently controllable.

### Claim 2 (depends on 1)

The discharge ionization detector according to claim 1, further comprising:
a controller configured to control the DC power unit so as to automatically adjust the collection-electrode voltage so that a signal output obtained from the collection electrode has the same sign as the electric charge of the charged particles to be detected, and to change the bias-electrode voltage to a value previously specified as a voltage for a sample measurement.

### Claim 3

A method for adjusting a discharge ionization detector including:
a gas passage through which an electric-discharge gas is to be passed;
a plasma generation electrode configured to generate an electric discharge in the gas passage so as to generate plasma from the electric-discharge gas in the gas passage by the electric discharge;
a collection electrode provided in the gas passage and configured to collect charged particles generated from a sample component in a sample gas with the plasma; and
a bias electrode configured to generate an electric field for guiding the charged particles to the collection electrode,
wherein the method comprises:
a step of setting a bias-electrode voltage, which is a DC voltage applied to the bias electrode, to 0 V under the condition that the sample gas is not introduced into the gas passage;
a step of adjusting a collection-electrode voltage, which is a DC voltage applied to the collection electrode, so that a signal output obtained from the collection electrode under the condition that the bias-electrode voltage is set at 0 V has the same sign as the charge of the charged particles to be detected; and
a step of changing the bias-electrode voltage to a value previously specified as a voltage for a sample measurement.

### Claim 4 (depends on 1)

A gas chromatograph device including a column and a detector configured to detect sample components separated from each other by the column, wherein the detector is the discharge ionization detector according to claim 1.

### Claim 5

A method for adjusting a gas chromatograph device including:
a column;
a detector configured to detect sample components separated from each other by the column; and
a chromatogram creator configured to create a chromatogram based on an output signal from the detector,
the detector being a discharge ionization detector including:
a gas passage through which an electric-discharge gas is to be passed;
a plasma generation electrode configured to generate an electric discharge in the gas passage so as to generate plasma from the electric-discharge gas in the gas passage by the electric discharge;
a collection electrode provided in the gas passage and configured to collect charged particles generated from a sample component in a sample gas with the plasma; and
a bias electrode configured to generate an electric field for guiding the charged particles to the collection electrode,
wherein the method comprises a step of adjusting a collection-electrode voltage, which is a DC voltage applied to the collection electrode, so as to reduce an abnormality in a peak shape on the chromatogram created by the chromatogram creator, while performing a sample analysis using the gas chromatograph device.