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US 2022/0017663 A1Published application
Polyethylene and Its Chlorinated Polyethylene
AssigneeLG Chem, Ltd.
InventorsCheolhwan Jeong, Si Jung Lee, Sun Mi Kim, Ue Ryung Seo, Yi Young Choi, Bog Ki Hong
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Abstract
There are provided a polyethylene capable of improving tensile strength while maintaining excellent processability and Mooney viscosity characteristics when preparing a chlorinated polyethylene compound by implementing a molecular structure having a low content of low molecular weight and a high content of high molecular weight, and a chlorinated polyethylene prepared using the same.
Claims13
A polyethylene having a density of 0.945 g/cm3 or more when measured in accordance with ASTM D-1505,
- wherein a fraction of an area representing a high molecular weight content of log Mw>6.0 is 4 to 12%,
- a fraction of an area representing a medium molecular weight content of 4.5<log Mw<5.0 is 35 to 50%, and
- a fraction of an area representing a low molecular weight content of log Mw<4.0 is 10% or less,
- relative to a total area of a molecular weight distribution curve drawn with a log value of weight average molecular weight as the x axis and a molecular weight distribution with respect to the log value as the y axis using gel permeation chromatography, and
- an entanglement molecular weight (Me) of the following Equation 1 is 27,000 to 52,000 g/mol:
- Me=(ρRT)/GN0 [Equation 1]
- wherein Equation 1,
- ρ is a density (kg/m3) of polyethylene measured in accordance with ASTM D-1505×0.8,
- R is a gas constant of polyethylene of 8.314 Pa·m3/mol·K,
- T is an absolute temperature of the measured temperature, and
- GN0 is a plateau modulus of polyethylene, which is a storage modulus when a loss modulus has a minimum value in a region where the storage modulus is greater than the loss modulus, wherein the storage modulus and loss modulus are measured while changing an angular frequency to 0.05 to 500 rad/s under conditions of 190° C. and 0.5% strain using a rotary rheometer.
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Dependencies are inferred from the claim text.