Composition comprising an alkoxysilane, a fatty ester and a silicone, and cosmetic use thereof
AssigneeL'oreal
InventorsClaire BOURDIN, Patrick MINOU
Life of this patent
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Abstract
The invention relates to a composition, especially a cosmetic composition, comprising: (i) one or more alkoxysilanes, (ii) one or more fatty esters; and (iii) one or more silicones. The invention also relates to a cosmetic process for treating keratin materials with this composition, and also to the use of this composition for caring for and/or shaping keratin materials.
Claims17
Composition, especially a cosmetic composition, comprising:
- (i) one or more alkoxysilanes,
- (ii) one or more fatty esters;
- and
- (iii) one or more silicones.
Composition according to the preceding claim, characterized in that the alkoxysilane is chosen from the following compounds:
- compounds of formula (I):
- in which:
- R4 represents a halogen or a group ORa or R1a;
- R5 represents a halogen or a group ORb or R2a;
- R6 represents a halogen or a group ORc or R3a;
- R1 and R2 represent, independently of each other, a hydrogen atom or a saturated or unsaturated, linear or branched hydrocarbon-based group, preferably R1 or R2 necessarily denoting a hydrogen atom,
- R3, Ra, Rb, Rc, R1a, R2a and R3a represent, independently of each other, a saturated or unsaturated, linear or branched hydrocarbon-based group, optionally bearing additional chemical groups such as acid or amine groups, Ra, Rb and Rc also possibly denoting hydrogen, and at least two of the groups R4, R5 and R6 being other than groups R1a, R2a and R3a, and preferably at least two of the groups Ra, Rb and Rc being other than hydrogen.
- compounds of formula (II):
- (R21O)x(R22)ySi—(B)p-[NR23—(Ba)pa]q-[NR23a—(Bb)pb]qa-Si(R22a)ya(OR21a)xa
- in which:
- R21, R22, R21a and R22a represent, independently of each other, a saturated or unsaturated, linear or branched hydrocarbon-based chain, optionally containing one or more heteroatoms, optionally interrupted or substituted with one or more groups chosen from ether, ester, amine, amide, carboxyl, hydroxyl and carbonyl groups,
- R23 and R23a each independently represent a hydrogen atom or a saturated or unsaturated, linear or branched hydrocarbon-based chain, optionally containing one or more heteroatoms, optionally interrupted or substituted with one or more ether, C1-C20 alcohol ester, amine, carboxyl, C6-C30 aryl, hydroxyl or carbonyl groups, or a heterocyclic or non-heterocyclic aromatic ring, optionally substituted with one or more C1-C20 alcohol ester, amine, amide, carboxyl, hydroxyl, carbonyl or acyl groups, R23 and R23a preferably representing a hydrogen atom,
- x is an integer ranging from 1 to 3, y=3-x, xa is an integer ranging from 1 to 3, ya=3-xa, p=0 or 1, pa=0 or 1, pb=0 or 1, q=0 or 1, qa=0 or 1, it being understood that at least q or qa is other than zero,
- B, Ba and Bb each independently represent a linear or branched divalent C1-C20 alkylene radical.
- compounds of formula (III):
- in which:
- R24 and R25 represent, independently of each other, a saturated or unsaturated, linear or branched hydrocarbon-based chain, optionally containing one or more heteroatoms, optionally interrupted or substituted with one or more groups chosen from ether, ester, amine, amide, carboxyl, hydroxyl and carbonyl groups,
- e=2 or 3;
- f=3-e;
- g=0 or 1;
- j=0 or 1;
- E and Ea each independently represent a linear or branched divalent C1-C20 alkylene radical,
- R26 and R27 each independently represent a hydrogen atom or a saturated or unsaturated, linear or branched hydrocarbon-based chain, optionally containing one or more heteroatoms, optionally interrupted or substituted with one or more ether, C1-C20 alcohol ester, amine, carboxyl, C6-C30 aryl, hydroxyl or carbonyl groups, or a heterocyclic or non-heterocyclic aromatic ring, optionally substituted with one or more C1-C20 alcohol ester, amine, amide, carboxyl, hydroxyl, carbonyl or acyl groups, R26 or R27 preferably representing a hydrogen atom,
- i is an integer ranging from 0 to 4,
- h is 0 or 1,
- the group(s) R28 each independently represent a hydrogen atom or a saturated or unsaturated, linear or branched, preferably C1-C10 hydrocarbon-based chain, optionally containing one or more heteroatoms, optionally interrupted or substituted with one or more ether, C1-C20 alcohol ester, amine, carboxyl, C6-C30 aryl, hydroxyl or carbonyl groups, or a heterocyclic or non-heterocyclic aromatic ring, optionally substituted with one or more C1-C20 alcohol ester, amine, amide, carboxyl, hydroxyl, carbonyl or acyl groups.
Composition according to either of the preceding claims, characterized in that the alkoxysilane is of formula (I) below:
- in which:
- R1 and R2, independently of each other, are chosen from hydrogen and ethyl, propyl and aminoethyl groups;
- R3 is chosen from ethyl, propyl and methylphenethyl groups;
- R4, R5 and R6, independently of each other, are chosen from methyl, methoxy and ethoxy groups.
Composition according to any one of the preceding claims, characterized in that the alkoxysilane is chosen from alkoxysilanes comprising one or more amine functions, which are preferably primary and/or secondary.
Composition according to any one of the preceding claims, characterized in that the alkoxysilane is chosen from 3-aminopropyltriethoxysilane, 3-aminopropylmethyldiethoxysilane, N-(2-aminoethyl)-3-aminopropyltriethoxysilane and 3-(2-aminoethylamino)propylmethyldiethoxysilane, and is preferably 3-aminopropyltriethoxysilane.
Composition according to any one of the preceding claims, characterized in that the alkoxysilane is present in the composition in an amount ranging from 0.05% to 20% by weight, in particular from 0.1% to 10% and preferably from 0.2% to 5% by weight relative to the total weight of the composition.
Composition according to any one of the preceding claims, characterized in that the fatty esters are chosen from:
- esters of saturated, linear or branched C1-C30 monoalcohols, with C10-C30 monofunctional fatty acids, the latter possibly being linear or branched, and saturated or unsaturated;
- esters of linear or branched C3-C8 monoalcohols, with C10-C30 difunctional fatty acids, the latter possibly being linear or branched, and saturated or unsaturated;
- esters and diesters of sugars and of C10-C30 fatty acids;
- mixtures thereof.
Composition according to any one of the preceding claims, characterized in that the fatty esters are solid at 25° C. and at atmospheric pressure (105 Pa).
Composition according to any one of the preceding claims, characterized in that the fatty esters are chosen from myristyl myristate, cetyl myristate, stearyl myristate, myristyl palmitate, cetyl palmitate, stearyl palmitate, myristyl stearate, cetyl stearate, stearyl stearate and behenyl behenate, and mixtures thereof.
Composition according to any one of the preceding claims, characterized in that the fatty ester(s) represent from 0.01% to 10% by weight and preferably from 0.1% to 5% by weight relative to the total weight of the composition.
Composition according to any one of the preceding claims, characterized in that the silicones are chosen from polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, silicone gums and resins, and polyorganosiloxanes modified with organofunctional groups, and also mixtures thereof.
Composition according to any one of the preceding claims, characterized in that the silicones are chosen from polydialkylsiloxanes bearing trimethylsilyl end groups, polydialkylsiloxanes bearing dimethylsilanol end groups and polysiloxanes bearing amino groups.
Composition according to any one of the preceding claims, in which the silicone(s) represent(s) from 0.01% to 10% by weight, preferably from 0.3% to 5% by weight and more particularly from 0.3% to 3% by weight relative to the total weight of the composition.
Dependencies are inferred from the claim text.