Method for preparing polyamide by anionic ring-opening copolymerization and polyamide prepared thereby
AssigneeHanwha Solutions Corporation
InventorsDo Kyoung KIM, Jin Seo LEE, Seung Hoe DO
Life of this patent
Estimating the term…
Loading patent…
AssigneeHanwha Solutions Corporation
InventorsDo Kyoung KIM, Jin Seo LEE, Seung Hoe DO
Estimating the term…
The present invention relates to a method for preparing a polyamide by anionic ring-opening copolymerization in consideration of the reactivity between a monomer and an alkali metal-based initiator. The present invention relates to a method for preparing a polyamide by anionic ring-opening copolymerization and a polyamide prepared thereby, in which, by adding a metal hydride, which is an alkali metal-based initiator, to a lactam having higher reactivity therewith, a production rate of an anion-initiated monomer is increased, thus enabling polymerization with a high conversion rate within a short polymerization reaction time to obtain a polymer having a uniform molecular weight. In the method for preparing the polyamide by anionic ring-opening copolymerization (AROP), a metal hydride is added as an alkali metal-based initiator in an amount of 0.01-20 parts by weight based on 100 parts by weight of two or more lactams, and the alkali metal-based initiator is mixed with a lactam having higher reactivity among two lactams. Therefore, the metal hydride, which is the alkali metal-based initiator, is added to the monomer having high reactivity therewith to increase a production rate of an anion-initiated monomer and improve a conversion rate into a random copolymer.
A method for preparing a polyamide by anionic ring-opening copolymerization (AROP), wherein a metal hydride is added as an alkali metal-based initiator in an amount of 0.01-20 parts by weight based on 100 parts by weight of two or more lactams, and the alkali metal-based initiator is mixed with a lactam having higher reactivity among two lactams.
Dependencies are inferred from the claim text.