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US 2021/0364229 A1Published application
Systems and Methods of Removing Contaminants in a Liquid Nitrogen Stream Used to Liquefy Natural Gas
AssigneeExxonMobil Upstream Research Company
InventorFritz Pierre, JR.
Life of this patent
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Abstract
Described herein are systems and processes of removing contaminants in a liquid nitrogen (LIN) stream used to produce liquefied natural gas (LNG). Greenhouse gas contaminants are removed from the LIN using a greenhouse gas removal unit. The LNG is compressed prior to being cooled by the LIN.
Claims24
A liquefied natural gas production system, the system comprising:
- a natural gas stream from a supply of natural gas;
- a liquid nitrogen stream from a liquid nitrogen supply;
- a natural gas compressor that compresses the natural gas stream to a pressure of at least 135 bara to form a compressed natural gas stream;
- a natural gas cooler that cools the compressed natural gas stream by indirect heat exchange with an ambient fluid to form a cooled compressed natural gas stream;
- a first heat exchanger that exchanges heat between an at least partially vaporized nitrogen stream and the cooled compressed natural gas stream to form an additionally cooled compressed natural gas stream;
- a work-producing natural gas expander that expands the additionally cooled compressed natural gas stream to a pressure less than 200 bara, but no greater than the pressure to which the natural gas compressor compresses the natural gas stream, to thereby form a chilled natural gas stream;
- and
- a second heat exchanger that at least partially condenses the chilled natural gas stream by exchanging heat between the chilled natural gas stream and the liquid nitrogen stream to form the at least partially vaporized nitrogen stream,
- further comprising a greenhouse gas removal unit configured to remove greenhouse gas from the at least partially vaporized nitrogen stream,
- wherein the greenhouse gas removal unit comprises a distillation column having a heat pump condenser and reboiler system.
7 more elements
A method of producing liquefied natural gas (LNG), the method comprising:
- providing a natural gas stream from a supply of natural gas;
- providing a liquid nitrogen stream from a liquid nitrogen supply;
- compressing the natural gas stream in a natural gas compressor to a pressure of at least 135 bara to form a compressed natural gas stream;
- cooling, through indirect heat exchange with an ambient fluid in a natural gas cooler, the compressed natural gas stream to form a cooled compressed natural gas stream;
- passing the cooled compressed natural gas stream and an at least partially vaporized nitrogen stream through a first heat exchanger that exchanges heat between the at least partially vaporized nitrogen stream and the cooled compressed natural gas stream to additionally cool the cooled compressed natural gas stream to form an additionally cooled compressed natural gas stream;
- expanding, in a work producing natural gas expander, the additionally cooled compressed natural gas stream to a pressure less than 200 bara, but no greater than the pressure to which the natural gas compressor compresses the natural gas stream, to thereby produce a chilled natural gas stream;
- and
- liquefying the chilled natural gas stream by passing the chilled natural gas stream and the liquefied nitrogen stream through a second heat exchanger that exchanges heat therebetween, wherein the liquefied nitrogen stream passes through the second heat exchanger to form the at least partially vaporized nitrogen stream;
- and
- further comprising removing greenhouse gas from the at least partially vaporized nitrogen stream using a greenhouse removal unit, wherein the greenhouse gas removal unit comprises a distillation column and a heat pump condenser and reboiler system, and further comprising:
- increasing a pressure and condensing temperature of an overhead stream of the distillation column;
- cross-exchanging the overhead stream of the distillation column and a bottoms stream of the distillation column to affect both an overhead condenser duty and a bottom reboiler duty of the distillation column;
- reducing a pressure of the distillation column overhead stream after the cross-exchanging step to produce a reduced pressure distillation column overhead stream;
- and
- separating the reduced pressure distillation column overhead stream to produce a first separator overhead stream, wherein the first separator overhead stream is gaseous nitrogen that exits the greenhouse gas removal unit having greenhouse gases removed therefrom.
12 more elements
Dependencies are inferred from the claim text.