# US 2021/0340822 A1 · Methods of forming components for earth-boring tools and related components and earth boring tools

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- Number: US 2021/0340822 A1
- Document ID: US20210340822A1
- Status: Published application
- Kind: A1
- Application number: 16/866,086
- Filed: 2020-05-04
- Published: 2021-11-04
- Earliest claimed: 2020-05-04
- Applicants: Baker Hughes Oilfield Operations LLC
- Inventors: Steven W. Webb; Eric C. Sullivan
- Web page: https://patentgrep.com/patent/US20210340822A1

## CPC

- E21B 10/5673: {having a non planar or non circular cutting face}
- B33Y 80/00: Products made by additive manufacturing
- C04B 35/532: containing a carbonisable binder
- C04B 35/62222: {obtaining ceramic coatings (coating of mortars, concrete, artificial or natural stone or ceramics C04B41/45; laminated ceramic products B32B18/00; coating of glass C03C17/00, applying ceramic coatings on silicon for semi-conductor purposes H10W; coating metallic materials C23)}
- C04B 35/62839: {Carbon}
- C04B 35/645: Pressure sintering
- E21B 10/573: characterised by support details, e.g. the substrate construction or the interface between the substrate and the cutting element
- C04B 2235/427: Diamond
- C04B 2235/48: Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
- C04B 2235/5436: micrometer sized, i.e. from 1 to 100 micron
- C04B 2235/5454: nanometer sized, i.e. below 100 nm
- C04B 2235/5472: Bimodal, multi-modal or multi-fraction
- C04B 2235/6026: Computer aided shaping, e.g. rapid prototyping
- C04B 2235/658: Atmosphere during thermal treatment
- C04B 2235/665: Local sintering, e.g. laser sintering
- C04B 2235/783: Bimodal, multi-modal or multi-fractional
- E21B 10/5735: {Interface between the substrate and the cutting element}
- E21B: EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- B33Y: ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE

## Abstract

A method of forming a superabrasive component for an earth-boring tool comprises disposing a first volume of particulate superabrasive material on a surface of a base structure. A first carbon-containing precursor material is deposited onto the first volume of unbonded particulate superabrasive material. An energy beam is directed onto the first carbon-containing precursor material to form a first volume of bonded polycrystalline superabrasive material having carbon-carbon atomic bonds between adjacent particles of the first volume of particulate superabrasive material. The method may be repeated to form a superabrasive component with multiple volumes of bonded polycrystalline superabrasive material. Additional methods of forming a superabrasive component, a superabrasive component, and an earth-boring tool are also described.

## Claims

### Claim 1

A method of forming a superabrasive component for an earth-boring tool, the method comprising:
disposing a first level of a first volume of unbonded particulate superabrasive material on a surface of a base structure;
depositing a first carbon-containing precursor material onto the first level;
directing an energy beam onto the first carbon-containing precursor material to form a first level of a first volume of bonded polycrystalline superabrasive material having carbon-carbon atomic bonds between adjacent particles;
repeating the disposing, depositing and directing to form the first level of the first volume of bonded polycrystalline superabrasive material to complete the first volume of bonded polycrystalline superabrasive material;
disposing a first level of at least a second volume of unbonded particulate superabrasive material on the first volume of bonded polycrystalline superabrasive material;
depositing a second carbon-containing precursor material onto the first level of the at least a second volume of particulate superabrasive material; and
directing an energy beam onto the second carbon-containing precursor material to form a first level of at least a second volume of bonded polycrystalline superabrasive material having carbon-carbon atomic bonds between adjacent particles and to bond with carbon-carbon atomic bonds particles of the first level of the second volume of bonded polycrystalline superabrasive material to an uppermost level of the first volume of bonded polycrystalline superabrasive material; and
repeating the disposing, depositing and directing to form the first level of the second volume of bonded polycrystalline superabrasive material to complete the at least a second volume of bonded superabrasive material.

### Claim 2 (depends on 1)

The method of claim 1, further comprising forming at least some levels of at least some of the first and second volumes of bonded polycrystalline superabrasive material to have different cross-sectional areas in a plane perpendicular to a longitudinal axis of the base structure.

### Claim 3 (depends on 1)

The method of claim 1, further comprising selecting unbonded superabrasive particles of the first volume of unbonded particulate superabrasive material to have a first grain size, and selecting the unbonded superabrasive particles of the at least a second volume of unbonded particulate superabrasive material to have a second grain size different than the first grain size.

### Claim 4 (depends on 1)

The method of claim 1, wherein forming the first volume of bonded polycrystalline superabrasive material comprises forming multiple levels each comprising a number of contiguous regions having at least one mutually different characteristic.

### Claim 5 (depends on 4)

The method of claim 4, further comprising selecting the at least one mutually different characteristic to comprise at least one of grain size or binder content.

### Claim 6 (depends on 4)

The method of claim 4, further comprising forming the multiple levels of the first volume to comprise a first number of regions having a first grain size and a second number of regions having a second grain size, the first number of regions and the second number of regions being interspersed and arranged in an ordered array.

### Claim 7 (depends on 1)

The method of claim 1, further comprising selecting the energy beam to comprise a laser beam.

### Claim 8 (depends on 1)

The method of claim 1, further comprising directing the energy beam onto the first and second carbon-containing precursor materials in an oxygen-free inert atmosphere.

### Claim 9 (depends on 1)

The method of claim 1, further comprising selecting the first and second carbon-containing precursor materials to be at least one of poly(phenylcarbyne) and poly(hydridocarbyne).

### Claim 10

A method of forming a PDC table for a cutting element for an earth-boring tool, the method comprising, using an additive manufacturing apparatus:
disposing a layer of unbonded particulate diamond material including unbonded diamond particles on a surface of a base structure;
depositing a carbon-containing precursor material onto the layer of unbonded particulate diamond material;
directing a laser beam onto the first carbon-containing precursor material to form a first level of bonded polycrystalline diamond material having carbon-carbon atomic bonds between adjacent particles;
disposing at least another layer of unbonded particulate diamond material on the first level of bonded polycrystalline diamond material;
depositing the carbon-containing precursor material onto at least another layer of particulate diamond material; and
directing a laser beam onto the carbon-containing precursor material to form at least a second level of bonded polycrystalline diamond material having carbon-carbon atomic bonds between adjacent particles thereof and to particles of the first level of bonded polycrystalline diamond material.

### Claim 11 (depends on 10)

The method of claim 10, further comprising disposing all particles of a given layer of unbonded particulate diamond material to comprise a common size.

### Claim 12 (depends on 10)

The method of claim 10, further comprising disposing particles of a given layer of unbonded particulate material to comprise at least two different sizes.

### Claim 13 (depends on 12)

The method of claim 12, further comprising mixing together particles of each of the at least two different sizes.

### Claim 14 (depends on 12)

The method of claim 12, wherein particles of a given size comprise at least one discrete region of particles of that size, and particles of another size of the at least two different sizes comprise at least another discrete region.

### Claim 15 (depends on 10)

The method of claim 10, further comprising forming additional levels of bonded superabrasive material to define at least one of a nonplanar cutting face or a nonplanar side surface of the PDC table.

### Claim 16 (depends on 10)

The method of claim 10, further comprising forming a first, second and additional levels of bonded superabrasive material having contiguous discontinuities to define at least one of an internal cavity or an internal fluid passage in the PDC table.

### Claim 17

A superabrasive component for an earth-boring tool, comprising:
a substrate; and
a PDC table secured to the substrate and comprising diamond particles mutually bonded by carbon-carbon bonds;
wherein the PDC table is entirely devoid of any catalyst.

### Claim 18 (depends on 17)

The superabrasive component of claim 17, wherein the PDC table comprises at least two different sizes of diamond grains.

### Claim 19 (depends on 18)

The superabrasive component of claim 18, wherein diamond grains of a common size comprise a discrete region of the PDC table.

### Claim 20 (depends on 17)

The superabrasive component of claim 17, wherein the PDC table comprises multiple levels of at least one of nanodiamond particles and microdiamond particles bonded together with hybridized Sp3 bonds.