# US 2021/0280795 A1 · Organic electroluminescent materials and devices

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- Number: US 2021/0280795 A1
- Document ID: US20210280795A1
- Status: Published application
- Kind: A1
- Application number: 17/182,611
- Filed: 2021-02-23
- Published: 2021-09-09
- Earliest claimed: 2020-02-28
- Assignees: Beijing Summer Sprout Technology Co., Ltd.
- Applicants: Beijing Summer Sprout Technology Co., Ltd.
- Inventors: Zhihao CUI; Hualong DING; Chi Yuen Raymond Kwong; Chuanjun XIA; Juntao HU; Xiao CHEN
- Web page: https://patentgrep.com/patent/US20210280795A1

## CPC

- C09K 11/06: containing organic luminescent materials
- C07D 498/04: Ortho-condensed systems
- H10K 85/657: {Polycyclic condensed heteroaromatic hydrocarbons}
- H10K 85/6572: {comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole}
- H10K 85/6574: {comprising only oxygen in the heteroaromatic polycondensed ring system, e.g. cumarine dyes}
- H10K 85/6576: {comprising only sulfur in the heteroaromatic polycondensed ring system, e.g. benzothiophene}
- C09K 2211/1018: Heterocyclic compounds
- H10K 50/131: {with spacer layers between the electroluminescent layers}
- H10K 50/15: Hole transporting layers
- H10K 50/17: Carrier injection layers
- Y02E 10/549: Organic PV cells
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C07D: HETEROCYCLIC COMPOUNDS (macromolecular compounds C08)
- H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

An organic electroluminescent material is disclosed. The organic electroluminescent material is novel dehydro-fused-ring compounds with a structure of B(A)2, which may be used as charge transporting materials, charge injection materials, and the like in organic electroluminescent devices. Such novel compounds have very deep LUMO energy level, so they are excellent electron acceptor materials and charge transfer materials. They also have the potential to be excellent hole injection materials and p-dopant materials, and have broad industrial application prospects. An electroluminescent device and a compound formulation are also disclosed.

## Claims

### Claim 1

A compound having a structure of B(A)2, wherein A has a structure of Formula 1:
wherein,
X is, at each occurrence identically or differently, selected from the group consisting of O, S, Se, NR′ and CR″R′″;
Y is, at each occurrence identically or differently, selected from the group consisting of CRY and N;
W is, at each occurrence identically or differently, selected from the group consisting of O, S, Se and NRN;
wherein, B is selected from a substituted or unsubstituted conjugated unsaturated fused aryl ring having 10 to 30 ring atoms, or a substituted or unsubstituted conjugated unsaturated fused heteroaryl ring having 10 to 30 ring atoms, or selected from the structure represented by one of Formula 2 to Formula 8, or combinations thereof:
wherein B is fused with each of A through a single bond and a double bond;
wherein Z is, at each occurrence, identically or differently, selected from the group consisting of CR and N;
n is, at each occurrence, identically or differently, selected from 0, 1, or 2;
wherein, R, R′, R″, R′″, RN and RY are, at each occurrence, identically or differently, selected from the group consisting of hydrogen, deuterium, halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF5, boranyl, sulfinyl, sulfonyl, phosphoroso, sulfanyl, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof;
wherein at least one of R, R′, R″, R′″, RN and RY is a group having at least one electron-withdrawing group;
any two adjacent substituents R, R′, R″, R′″, RN and RY can be optionally joined to form a ring;
wherein, when B is selected form Formula 2 or Formula 3, and all of Y are CRY, X is, at each occurrence identically or differently, selected from the group consisting of S, Se, NR′ and CR″R′″.

### Claim 2 (depends on 1)

The compound according to claim 1, wherein when B is selected from Formula 2 or Formula 3, the compound is selected from the structure of Formula I or Formula II:
wherein, Z1 and Z2 are, at each occurrence identically or differently, selected from the group consisting of CR and N;
wherein, X is, at each occurrence identically or differently, selected from the group consisting of O, S, Se, NR′ and CR″R′″;
wherein, Y is, at each occurrence identically or differently, selected from the group consisting of CRY and N; and when all of Y are CRY, X is, at each occurrence identically or differently, selected from the group consisting of S, Se, NR′ and CR″R′″;
wherein, W is, at each occurrence identically or differently, selected from the group consisting of O, S, Se and NRN;
wherein, R, R′, R″, R′″, RN and RY are, at each occurrence identically or differently, selected from the group consisting of hydrogen, deuterium, halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF5, boranyl, sulfinyl, sulfonyl, phosphoroso, sulfanyl, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof;
wherein at least one of R, R′, R″, R′″, RN and RY is a group having at least one electron-withdrawing group; and
any two adjacent substituents R, R′, R″, R′″, RN and RY can be optionally joined to form a ring;
or wherein when B is selected from a substituted or unsubstituted conjugated unsaturated fused aryl ring having 10 to 30 ring atoms, or a substituted or unsubstituted conjugated unsaturated fused heteroaryl ring having 10 to 30 ring atoms, the compound is selected from the structure of any one of Formula III to Formula XVIII:
wherein,
X is, at each occurrence identically or differently, selected from the group consisting of O, S, Se, NR′ and CR″R′″;
Y is, at each occurrence identically or differently, selected from the group consisting of CRY and N; wherein, when the compound is selected from Formula III, VI or VII, all of Y are N;
W is, at each occurrence identically or differently, selected from the group consisting of O, S, Se and NRN;
wherein Z1 to Z6 are, at each occurrence identically or differently, selected from the group consisting of CR and N;
wherein, R, R′, R″, R′″, RN and RY are, at each occurrence identically or differently, selected from the group consisting of hydrogen, deuterium, halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF5, boranyl, sulfinyl, sulfonyl, phosphoroso, sulfanyl, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof;
wherein at least one of R, R′, R″, R′″, RN and RY is a group having at least one electron-withdrawing group;
any two adjacent substituents R, R′, R″, R′″, RN and RY can be optionally joined to form a ring;
or wherein when B is selected from Formula 4 to Formula 8, n is 0 or 1, and the compound has the structure of any one of Formula XIX to Formula XXIV:
wherein,
X is, at each occurrence identically or differently, selected from the group consisting of O, S, Se, NR′ and CR″R′″;
Y is, at each occurrence identically or differently, selected from the group consisting of CRY and N;
W is, at each occurrence identically or differently, selected from the group consisting of O, S, Se and NRN;
wherein Z1 to Z10 are, at each occurrence identically or differently, selected from the group consisting of CR and N;
wherein, R, R′, R″, R′″, RN and RY are, at each occurrence identically or differently, selected from the group consisting of hydrogen, deuterium, halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF5, boranyl, sulfinyl, sulfonyl, phosphoroso, sulfanyl, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof;
wherein at least one of R, R′, R″, R′″, RN and RY is a group having at least one electron-withdrawing group; and
any two adjacent substituents R, R′, R″, R′″, RN and RY can be optionally joined to form a ring.

### Claim 3 (depends on 1)

The compound according to claim 1, wherein X is, at each occurrence identically or differently, selected from S, Se, NR′ or CR″R″′; preferably, X is, at each occurrence identically or differently, selected from CR″R′″.

### Claim 4 (depends on 1)

The compound according to claim 1, wherein W is, at each occurrence identically or differently, selected from O, S or Se; preferably, W is, at each occurrence identically or differently, selected from O or S; more preferably, all of W are O.

### Claim 5 (depends on 1)

The compound according to claim 1, wherein all of Y are N.

### Claim 6 (depends on 1)

The compound according to claim 1, when B is selected from a substituted or unsubstituted conjugated unsaturated fused aryl ring having 10 to 30 ring atoms, or a substituted or unsubstituted conjugated unsaturated fused heteroaryl ring having 10 to 30 ring atoms, Y are N.

### Claim 7 (depends on 1)

The compound according to claim 1, wherein W is, at each occurrence identically or differently, selected from NRN, RN is, at each occurrence identically or differently, selected from the group consisting of a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof;
preferably, RN is, at each occurrence identically or differently, selected from the group consisting of a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, and combinations thereof.

### Claim 8 (depends on 1)

The compound according to claim 1, wherein at least one of Z is selected from N.

### Claim 9 (depends on 2)

The compound according to claim 2, wherein in the Formula I to Formula XXII, at least one of Z1 to Zx is selected from N, x in Zx corresponds to the largest number of Z existing in Formula I to Formula XXII.

### Claim 10 (depends on 1)

The compound according to claim 1, wherein Z is, at each occurrence identically or differently, selected from CR; preferably, Z is, at each occurrence identically or differently, selected from CR, and wherein at least one of R is selected from the group having at least one electron-withdrawing group; more preferably, Z is, at each occurrence identically or differently, selected from CR, and wherein R is, at each occurrence identically or differently, selected from the group having at least one electron-withdrawing group.

### Claim 11 (depends on 1)

The compound according to claim 1, wherein at least one of R, R′, R″ and R′″ is the group having at least one electron-withdrawing group; preferably, each of R, R′, R″ and R′″ is the group having at least one electron-withdrawing group; more preferably, each of R, R′, R″, R′″, RN and RY is the group having at least one electron-withdrawing group.

### Claim 12 (depends on 1)

The compound according to claim 1, wherein the Hammett's constant of the electron-withdrawing group is ≥0.05, preferably ≥0.3, more preferably ≥0.5.

### Claim 13 (depends on 1)

The compound according to claim 1, wherein the electron-withdrawing group is selected from the group consisting of halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF5, boranyl, sulfinyl, sulfonyl, phosphoroso, an aza-aromatic ring group, or is any one of an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 ring carbon atoms, a heteroalkyl group having 1 to 20 carbon atoms, an arylalkyl group having 7 to 30 carbon atoms, an alkoxyl group having 1 to 20 carbon atoms, an aryloxy group having 6 to 30 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an alkynyl group having 2 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, a heteroaryl group having 3 to 30 carbon atoms, an alkylsilyl group having 3 to 20 carbon atoms and an arylsilyl group having 6 to 20 carbon atoms which are substituted with one or more of halogen, nitroso, nitro, acyl, carbonyl, carboxylic acid group, ester group, cyano, isocyano, SCN, OCN, SF5, boranyl, sulfinyl, sulfonyl, phosphoroso, aza-aromatic ring group, and combinations thereof;
preferably, the electron-withdrawing group is selected from the group consisting of F, CF3, OCF3, SF5, SO2CF3, cyano, isocyano, SCN, OCN, pyrimidinyl, triazinyl, and combinations thereof.

### Claim 14 (depends on 2)

The compound according to claim 2, wherein X is, at each occurrence identically or differently, selected from the group consisting of the following structures:
wherein R1 is selected, at each occurrence, identically or differently, from the group consisting of hydrogen, deuterium, halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF5, boranyl, sulfinyl, sulfonyl, phosphoroso, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof;
preferably, R1 is selected, at each occurrence, identically or differently, from the group consisting of F, CF3, OCF3, SF5, SO2CF3, cyano, isocyano, SCN, OCN, pentafluorophenyl, 4-cyanotetrafluorophenyl, tetrafluoropyridyl, pyrimidinyl, triazinyl, and combinations thereof;
wherein V and U are selected, at each occurrence, identically or differently, from the group consisting of CRvRu, NRv, O, S and Se;
wherein Ar is selected, at each occurrence, identically or differently, from a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, and a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms;
wherein Q, Ra, Rb, Rc, Rd, Re, Rf, Rg, Rh, Rv and Ru are selected, at each occurrence, identically or differently, from the group consisting of hydrogen, deuterium, halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF5, boranyl, sulfinyl, sulfonyl, phosphoroso, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof;
wherein Q is a group having at least one electron-withdrawing group, and for any one of the structures, when one or more of Ra, Rb, Re, Rd, Re, Rf, Rg, Rh, Rv and Ru is(are) appear, at least one of Ra, Rb, Re, Rd, Re, Rf, Rg, Rh, Rv and Ru is a group having at least one electron-withdrawing group; preferably, the group having at least one electron-withdrawing group is selected from the group consisting of F, CF3, OCF3, SF5, SO2CF3, cyano, isocyano, SCN, OCN, pentafluorophenyl, 4-cyanotetrafluorophenyl, tetrafluoropyridyl, pyrimidinyl, triazinyl, and combinations thereof.

### Claim 15 (depends on 2)

The compound according to claim 2, wherein X is, at each occurrence identically or differently, selected from the group consisting of:
preferably, wherein X is selected from A1.

### Claim 16 (depends on 15)

The compound according to claim 15, wherein R is, at each occurrence identically or differently, selected from the group consisting of hydrogen, deuterium, halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF5, boranyl, sulfinyl, sulfonyl, phosphoroso, sulfanyl, an unsubstituted alkyl group having 1 to 20 carbon atoms, an unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, an unsubstituted alkoxyl group having 1 to 20 carbon atoms, an unsubstituted alkenyl group having 2 to 20 carbon atoms, an unsubstituted aryl group having 6 to 30 carbon atoms, and an unsubstituted heteroaryl group having 3 to 30 carbon atoms, and any one of an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 ring carbon atoms, an alkoxyl group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms and a heteroaryl group having 3 to 30 carbon atoms which are substituted with one or more groups selected from the group consisting of halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF5, boranyl, sulfinyl, sulfonyl, phosphoroso, and combinations thereof;
preferably, R is, at each occurrence identically or differently, selected from the group consisting of hydrogen, deuterium, methyl, isopropyl, NO2, SO2CH3, SCF3, C2F5, OC2F5, OCH3, p-methylphenyl, diphenylmethylsilyl, phenyl, methoxyphenyl, 2,6-diisopropylphenyl, biphenyl, polyfluorophenyl, difluoropyridyl, nitrophenyl, dimethylthiazolyl, CN, vinyl substituted with one or more of CN and CF3, ethynyl substituted with one of CN and CF3, dimethylphosphoroso, diphenylphosphoroso, F, CF3, OCF3, SF5, SO2CF3, cyano, isocyano, SCN, OCN, trifluoromethylphenyl, trifluoromethoxyphenyl, bi s(trifluoromethyl)phenyl, bis(trifluoromethoxy)phenyl, 4-cyanotetrafluorophenyl, phenyl or biphenyl substituted with one or more of F, CN and CF3, tetrafluoropyridyl, pyrimidinyl, triazinyl, pyridyl, diphenylboranyl, oxaboraanthryl, and combinations thereof.

### Claim 17 (depends on 16)

The compound according to claim 16, wherein R is, at each occurrence identically or differently, selected from the group consisting of:

### Claim 18 (depends on 17)

The compound according to claim 17, wherein the compound is selected from the group consisting of Compound I-1 to Compound I-128, Compound II-1 to Compound II-128, Compound III-1 to Compound III-64, Compound IV-1 to Compound IV-128, Compound V-1 to Compound V-128, Compound VI-1 to Compound VI-64, Compound VII-1 to Compound VII-64, Compound VIII-1 to Compound VIII-128, Compound IX-1 to Compound IX-128, Compound X-1 to Compound X-128, Compound XI-1 to Compound XI-128, Compound XII-1 to Compound XII-128, Compound XIII-1 to Compound XIII-128, Compound XIV-1 to Compound XIV-128, Compound XV-1 to Compound XV-128, Compound XVI-1 to Compound XVI-128, Compound XVII-1 to Compound XVII-128, Compound XVIII-1 to Compound XVIII-128, Compound XIX-1 to Compound XIX-128:
wherein, Compound I-1 to Compound I-128 have the structure of Formula I:
in Formula I, both of X are the same, both of Y are the same, both of W are the same, Z1 and Z2 are the same, and X, Y, W, Z1 and Z2 are correspondingly selected from the atoms or groups as shown in the following table:
No.
X
Y
W
Z1 = Z2
No.
X
Y
W
Z1 = Z2
I-1
Al
N
O
C-B1
I-2
Al
N
O
C-B13
I-3
Al
N
O
C-B16
I-4
Al
N
O
C-B17
I-5
Al
N
O
C-B25
I-6
Al
N
O
C-B52
I-7
Al
N
O
C-B54
I-8
Al
N
O
C-B55
I-9
Al
N
O
C-B63
I-10
Al
N
O
C-B68
I-11
Al
N
O
C-B69
I-12
Al
N
O
C-B70
I-13
Al
N
O
C-B71
I-14
Al
N
O
C-B89
I-15
Al
N
O
C-B90
I-16
Al
N
O
C-B91
I-17
Al
N
S
C-B1
I-18
Al
N
S
C-B13
I-19
Al
N
S
C-B16
I-20
Al
N
S
C-B17
I-21
Al
N
S
C-B25
I-22
Al
N
S
C-B52
I-23
Al
N
S
C-B54
I-24
Al
N
S
C-B55
I-25
Al
N
S
C-B63
I-26
Al
N
S
C-B68
I-27
Al
N
S
C-B69
I-28
Al
N
S
C-B70
I-29
Al
N
S
C-B71
I-30
Al
N
S
C-B89
I-31
Al
N
S
C-B90
I-32
Al
N
S
C-B91
I-33
Al
N
Se
C-B1
I-34
Al
N
Se
C-B13
I-35
Al
N
Se
C-B16
I-36
Al
N
Se
C-B17
I-37
Al
N
Se
C-B25
I-38
Al
N
Se
C-B52
I-39
Al
N
Se
C-B54
I-40
Al
N
Se
C-B55
I-41
Al
N
Se
C-B63
I-42
Al
N
Se
C-B68
I-43
Al
N
Se
C-B69
I-44
Al
N
Se
C-B70
I-45
Al
N
Se
C-B71
I-46
Al
N
Se
C-B89
I-47
Al
N
Se
C-B90
I-48
Al
N
Se
C-B91
I-49
Al
N
NMe
C-B1
I-50
Al
N
NMe
C-B13
I-51
Al
N
NMe
C-B16
I-52
Al
N
NMe
C-B17
I-53
Al
N
NMe
C-B25
I-54
Al
N
NMe
C-B52
I-55
Al
N
NMe
C-B54
I-56
Al
N
NMe
C-B55
I-57
Al
N
NMe
C-B63
I-58
Al
N
NMe
C-B68
I-59
Al
N
NMe
C-B69
I-60
Al
N
NMe
C-B70
I-61
Al
N
NMe
C-B71
I-62
Al
N
NMe
C-B89
I-63
Al
N
NMe
C-B90
I-64
Al
N
NMe
C-B91
I-65
Al
CH
O
C-B1
I-66
Al
CH
O
C-B13
I-67
Al
CH
O
C-B16
I-68
Al
CH
O
C-B17
I-69
Al
CH
O
C-B25
I-70
Al
CH
O
C-B52
I-71
Al
CH
O
C-B54
I-72
Al
CH
O
C-B55
I-73
Al
CH
O
C-B63
I-74
Al
CH
O
C-B68
I-75
Al
CH
O
C-B69
I-76
Al
CH
O
C-B70
I-77
Al
CH
O
C-B71
I-78
Al
CH
O
C-B89
I-79
Al
CH
O
C-B90
I-80
Al
CH
O
C-B91
I-81
Al
CH
S
C-B1
I-82
Al
CH
S
C-B13
I-83
Al
CH
S
C-B16
I-84
Al
CH
S
C-B17
I-85
Al
CH
S
C-B25
I-86
Al
CH
S
C-B52
I-87
Al
CH
S
C-B54
I-88
Al
CH
S
C-B55
I-89
Al
CH
S
C-B63
I-90
Al
CH
S
C-B68
I-91
Al
CH
S
C-B69
I-92
Al
CH
S
C-B70
I-93
Al
CH
S
C-B71
I-94
Al
CH
S
C-B89
I-95
Al
CH
S
C-B90
I-96
Al
CH
S
C-B91
I-97
Al
CH
Se
C-B1
I-98
Al
CH
Se
C-B13
I-99
Al
CH
Se
C-B16
I-100
Al
CH
Se
C-B17
I-101
Al
CH
Se
C-B25
I-102
Al
CH
Se
C-B52
I-103
Al
CH
Se
C-B54
I-104
Al
CH
Se
C-B55
I-105
Al
CH
Se
C-B63
I-106
Al
CH
Se
C-B68
I-107
Al
CH
Se
C-B69
I-108
Al
CH
Se
C-B70
I-109
Al
CH
Se
C-B71
I-110
Al
CH
Se
C-B89
I-111
Al
CH
Se
C-B90
I-112
Al
CH
Se
C-B91
I-113
Al
CH
NMe
C-B1
I-114
Al
CH
NMe
C-B13
I-115
Al
CH
NMe
C-B16
I-116
Al
CH
NMe
C-B17
I-117
Al
CH
NMe
C-B25
I-118
Al
CH
NMe
C-B52
I-119
Al
CH
NMe
C-B54
I-120
Al
CH
NMe
C-B55
I-121
Al
CH
NMe
C-B63
I-122
Al
CH
NMe
C-B68
I-123
Al
CH
NMe
C-B69
I-124
Al
CH
NMe
C-B70
I-125
Al
CH
NMe
C-B71
I-126
Al
CH
NMe
C-B89
I-127
Al
CH
NMe
C-B90
I-128
Al
CH
NMe
C-B91
wherein, Compound II-1 to Compound II-128 have the structure of Formula II:
in Formula II, both of X are the same, both of Y are the same, both of W are the same, Z1 and Z2 are the same, and X, Y, W, Z1 and Z2 are correspondingly selected from the atoms or groups as shown in the following table:
No.
X
Y
W
Z1 = Z2
No.
X
Y
W
Z1 = Z2
II-1
Al
N
O
C-B1
II-2
Al
N
O
C-B13
II-3
Al
N
O
C-B16
II-4
Al
N
O
C-B17
II-5
Al
N
O
C-B25
II-6
Al
N
O
C-B52
II-7
Al
N
O
C-B54
II-8
Al
N
O
C-B55
II-9
Al
N
O
C-B63
II-10
Al
N
O
C-B68
II-11
Al
N
O
C-B69
II-12
Al
N
O
C-B70
II-13
Al
N
O
C-B71
II-14
Al
N
O
C-B89
II-15
Al
N
O
C-B90
II-16
Al
N
O
C-B91
II-17
Al
N
S
C-B1
II-18
Al
N
S
C-B13
II-19
Al
N
S
C-B16
II-20
Al
N
S
C-B17
II-21
Al
N
S
C-B25
II-22
Al
N
S
C-B52
II-23
Al
N
S
C-B54
II-24
Al
N
S
C-B55
II-25
Al
N
S
C-B63
II-26
Al
N
S
C-B68
II-27
Al
N
S
C-B69
II-28
Al
N
S
C-B70
II-29
Al
N
S
C-B71
II-30
Al
N
S
C-B89
II-31
Al
N
S
C-B90
II-32
Al
N
S
C-B91
II-33
Al
N
Se
C-B1
II-34
Al
N
Se
C-B13
II-35
Al
N
Se
C-B16
II-36
Al
N
Se
C-B17
II-37
Al
N
Se
C-B25
II-38
Al
N
Se
C-B52
II-39
Al
N
Se
C-B54
II-40
Al
N
Se
C-B55
II-41
Al
N
Se
C-B63
II-42
Al
N
Se
C-B68
II-43
Al
N
Se
C-B69
II-44
Al
N
Se
C-B70
II-45
Al
N
Se
C-B71
II-46
Al
N
Se
C-B89
II-47
Al
N
Se
C-B90
II-48
Al
N
Se
C-B91
II-49
Al
N
NMe
C-B1
II-50
Al
N
NMe
C-B13
II-51
Al
N
NMe
C-B16
II-52
Al
N
NMe
C-B17
II-53
Al
N
NMe
C-B25
II-54
Al
N
NMe
C-B52
II-55
Al
N
NMe
C-B54
II-56
Al
N
NMe
C-B55
II-57
Al
N
NMe
C-B63
II-58
Al
N
NMe
C-B68
II-59
Al
N
NMe
C-B69
II-60
Al
N
NMe
C-B70
II-61
Al
N
NMe
C-B71
II-62
Al
N
NMe
C-B89
II-63
Al
N
NMe
C-B90
II-64
Al
N
NMe
C-B91
II-65
Al
CH
O
C-B1
II-66
Al
CH
O
C-B13
II-67
Al
CH
O
C-B16
II-68
Al
CH
O
C-B17
II-69
Al
CH
O
C-B25
II-70
Al
CH
O
C-B52
II-71
Al
CH
O
C-B54
II-72
Al
CH
O
C-B55
II-73
Al
CH
O
C-B63
II-74
Al
CH
O
C-B68
II-75
Al
CH
O
C-B69
II-76
Al
CH
O
C-B70
II-77
Al
CH
O
C-B71
II-78
Al
CH
O
C-B89
II-79
Al
CH
O
C-B90
II-80
Al
CH
O
C-B91
II-81
Al
CH
S
C-B1
II-82
Al
CH
S
C-B13
II-83
Al
CH
S
C-B16
II-84
Al
CH
S
C-B17
II-85
Al
CH
S
C-B25
II-86
Al
CH
S
C-B52
II-87
Al
CH
S
C-B54
II-88
Al
CH
S
C-B55
II-89
Al
CH
S
C-B63
II-90
Al
CH
S
C-B68
II-91
Al
CH
S
C-B69
II-92
Al
CH
S
C-B70
II-93
Al
CH
S
C-B71
II-94
Al
CH
S
C-B89
II-95
Al
CH
S
C-B90
II-96
Al
CH
S
C-B91
II-97
Al
CH
Se
C-B1
II-98
Al
CH
Se
C-B13
II-99
Al
CH
Se
C-B16
II-100
Al
CH
Se
C-B17
II-101
Al
CH
Se
C-B25
II-102
Al
CH
Se
C-B52
II-103
Al
CH
Se
C-B54
II-104
Al
CH
Se
C-B55
II-105
Al
CH
Se
C-B63
II-106
Al
CH
Se
C-B68
II-107
Al
CH
Se
C-B69
II-108
Al
CH
Se
C-B70
II-109
Al
CH
Se
C-B71
II-110
Al
CH
Se
C-B89
II-111
Al
CH
Se
C-B90
II-112
Al
CH
Se
C-B91
II-113
Al
CH
NMe
C-B1
II-114
Al
CH
NMe
C-B13
II-115
Al
CH
NMe
C-B16
II-116
Al
CH
NMe
C-B17
II-117
Al
CH
NMe
C-B25
II-118
Al
CH
NMe
C-B52
II-119
Al
CH
NMe
C-B54
II-120
Al
CH
NMe
C-B55
II-121
Al
CH
NMe
C-B63
II-122
Al
CH
NMe
C-B68
II-123
Al
CH
NMe
C-B69
II-124
Al
CH
NMe
C-B70
II-125
Al
CH
NMe
C-B71
II-126
Al
CH
NMe
C-B89
II-127
Al
CH
NMe
C-B90
II-128
Al
CH
NMe
C-B91
wherein, Compound III-1 to Compound III-64 have the structure of Formula III:
in Formula III, both of X are the same, both of Y are the same, both of W are the same, Z1 and Z2 are the same, Z3 and Z4 are the same, and X, Y, W, Z1, Z2, Z3 and Z4 are correspondingly selected from the atoms or groups as shown in the following table:
No.
X
Y
W
Z1 = Z2
Z3 = Z4
No.
X
Y
W
Z1 = Z2
Z3 = Z4
III-1
Al
N
O
C-B1
C-B1
III-2
Al
N
O
C-B13
C-B13
III-3
Al
N
O
C-B16
C-B13
III-4
Al
N
O
C-B17
C-B13
III-5
Al
N
O
C-B25
C-B13
III-6
Al
N
O
C-B52
C-B13
III-7
Al
N
O
C-B54
C-B13
III-8
Al
N
O
C-B55
C-B13
III-9
Al
N
O
C-B63
C-B13
III-10
Al
N
O
C-B68
C-B13
III-11
Al
N
O
C-B69
C-B13
III-12
Al
N
O
C-B70
C-B13
III-13
Al
N
O
C-B71
C-B13
III-14
Al
N
O
C-B89
C-B13
III-15
Al
N
O
C-B90
C-B13
III-16
Al
N
O
C-B91
C-B13
III-17
Al
N
S
C-B1
C-B1
III-18
Al
N
S
C-B13
C-B13
III-19
Al
N
S
C-B16
C-B13
III-20
Al
N
S
C-B17
C-B13
III-21
Al
N
S
C-B25
C-B13
III-22
Al
N
S
C-B52
C-B13
III-23
Al
N
S
C-B54
C-B13
III-24
Al
N
S
C-B55
C-B13
III-25
Al
N
S
C-B63
C-B13
III-26
Al
N
S
C-B68
C-B13
III-27
Al
N
S
C-B69
C-B13
III-28
Al
N
S
C-B70
C-B13
III-29
Al
N
S
C-B71
C-B13
III-30
Al
N
S
C-B89
C-B13
III-31
Al
N
S
C-B90
C-B13
III-32
Al
N
S
C-B91
C-B13
III-33
Al
N
Se
C-B1
C-B1
III-34
Al
N
Se
C-B13
C-B13
III-35
Al
N
Se
C-B16
C-B13
III-36
Al
N
Se
C-B17
C-B13
III-37
Al
N
Se
C-B25
C-B13
III-38
Al
N
Se
C-B52
C-B13
III-39
Al
N
Se
C-B54
C-B13
III-40
Al
N
Se
C-B55
C-B13
III-41
Al
N
Se
C-B63
C-B13
III-42
Al
N
Se
C-B68
C-B13
III-43
Al
N
Se
C-B69
C-B13
III-44
Al
N
Se
C-B70
C-B13
III-45
Al
N
Se
C-B71
C-B13
III-46
Al
N
Se
C-B89
C-B13
III-47
Al
N
Se
C-B90
C-B13
III-48
Al
N
Se
C-B91
C-B13
III-49
Al
N
NMe
C-B1
C-B1
III-50
Al
N
NMe
C-B13
C-B13
III-51
Al
N
NMe
C-B16
C-B13
III-52
Al
N
NMe
C-B17
C-B13
III-53
Al
N
NMe
C-B25
C-B13
III-54
Al
N
NMe
C-B52
C-B13
III-55
Al
N
NMe
C-B54
C-B13
III-56
Al
N
NMe
C-B55
C-B13
III-57
Al
N
NMe
C-B63
C-B13
III-58
Al
N
NMe
C-B68
C-B13
III-59
Al
N
NMe
C-B69
C-B13
III-60
Al
N
NMe
C-B70
C-B13
III-61
Al
N
NMe
C-B71
C-B13
III-62
Al
N
NMe
C-B89
C-B13
III-63
Al
N
NMe
C-B90
C-B13
III-64
Al
N
NMe
C-B91
C-B13
wherein, Compound IV-1 to Compound IV-128 have the structure of Formula IV:
in Formula IV, both of X are the same, both of Y are the same, both of W are the same, Z1 and Z2 are the same, Z3 and Z4 are the same, and X, Y, W, Z1, Z2, Z3 and Z4 are correspondingly selected from the atoms or groups as shown in the following table:
No.
X
Y
W
Z1 = Z2
Z3 = Z4
No.
X
Y
W
Z1 = Z2
Z3 = Z4
IV-1
Al
N
O
C-B1
C-B1
IV-2
Al
N
O
C-B13
C-B13
IV-3
Al
N
O
C-B16
C-B13
IV-4
Al
N
O
C-B17
C-B13
IV-5
Al
N
O
C-B25
C-B13
IV-6
Al
N
O
C-B52
C-B13
IV-7
Al
N
O
C-B54
C-B13
IV-8
Al
N
O
C-B55
C-B13
IV-9
Al
N
O
C-B63
C-B13
IV-10
Al
N
O
C-B68
C-B13
IV-11
Al
N
O
C-B69
C-B13
IV-12
Al
N
O
C-B70
C-B13
IV-13
Al
N
O
C-B71
C-B13
IV-14
Al
N
O
C-B89
C-B13
IV-15
Al
N
O
C-B90
C-B13
IV-16
Al
N
O
C-B91
C-B13
IV-17
Al
N
S
C-B1
C-B1
IV-18
Al
N
S
C-B13
C-B13
IV-19
Al
N
S
C-B16
C-B13
IV-20
Al
N
S
C-B17
C-B13
IV-21
Al
N
S
C-B25
C-B13
IV-22
Al
N
S
C-B52
C-B13
IV-23
Al
N
S
C-B54
C-B13
IV-24
Al
N
S
C-B55
C-B13
IV-25
Al
N
S
C-B63
C-B13
IV-26
Al
N
S
C-B68
C-B13
IV-27
Al
N
S
C-B69
C-B13
IV-28
Al
N
S
C-B70
C-B13
IV-29
Al
N
S
C-B71
C-B13
IV-30
Al
N
S
C-B89
C-B13
IV-31
Al
N
S
C-B90
C-B13
IV-32
Al
N
S
C-B91
C-B13
IV-33
Al
N
Se
C-B1
C-B1
IV-34
Al
N
Se
C-B13
C-B13
IV-35
Al
N
Se
C-B16
C-B13
IV-36
Al
N
Se
C-B17
C-B13
IV-37
Al
N
Se
C-B25
C-B13
IV-38
Al
N
Se
C-B52
C-B13
IV-39
Al
N
Se
C-B54
C-B13
IV-40
Al
N
Se
C-B55
C-B13
IV-41
Al
N
Se
C-B63
C-B13
IV-42
Al
N
Se
C-B68
C-B13
IV-43
Al
N
Se
C-B69
C-B13
IV-44
Al
N
Se
C-B70
C-B13
IV-45
Al
N
Se
C-B71
C-B13
IV-46
Al
N
Se
C-B89
C-B13
IV-47
Al
N
Se
C-B90
C-B13
IV-48
Al
N
Se
C-B91
C-B13
IV-49
Al
N
NMe
C-B1
C-B1
IV-50
Al
N
NMe
C-B13
C-B13
IV-51
Al
N
NMe
C-B16
C-B13
IV-52
Al
N
NMe
C-B17
C-B13
IV-53
Al
N
NMe
C-B25
C-B13
IV-54
Al
N
NMe
C-B52
C-B13
IV-55
Al
N
NMe
C-B54
C-B13
IV-56
Al
N
NMe
C-B55
C-B13
IV-57
Al
N
NMe
C-B63
C-B13
IV-58
Al
N
NMe
C-B68
C-B13
IV-59
Al
N
NMe
C-B69
C-B13
IV-60
Al
N
NMe
C-B70
C-B13
IV-61
Al
N
NMe
C-B71
C-B13
IV-62
Al
N
NMe
C-B89
C-B13
IV-63
Al
N
NMe
C-B90
C-B13
IV-64
Al
N
NMe
C-B91
C-B13
IV-65
Al
CH
O
C-B1
C-B1
IV-66
Al
CH
O
C-B13
C-B13
IV-67
Al
CH
O
C-B16
C-B13
IV-68
Al
CH
O
C-B17
C-B13
IV-69
Al
CH
O
C-B25
C-B13
IV-70
Al
CH
O
C-B52
C-B13
IV-71
Al
CH
O
C-B54
C-B13
IV-72
Al
CH
O
C-B55
C-B13
IV-73
Al
CH
O
C-B63
C-B13
IV-74
Al
CH
O
C-B68
C-B13
IV-75
Al
CH
O
C-B69
C-B13
IV-76
Al
CH
O
C-B70
C-B13
IV-77
Al
CH
O
C-B71
C-B13
IV-78
Al
CH
O
C-B89
C-B13
IV-79
Al
CH
O
C-B90
C-B13
IV-80
Al
CH
O
C-B91
C-B13
IV-81
Al
CH
S
C-B1
C-B1
IV-82
Al
CH
S
C-B13
C-B13
IV-83
Al
CH
S
C-B16
C-B13
IV-84
Al
CH
S
C-B17
C-B13
IV-85
Al
CH
S
C-B25
C-B13
IV-86
Al
CH
S
C-B52
C-B13
IV-87
Al
CH
S
C-B54
C-B13
IV-88
Al
CH
S
C-B55
C-B13
IV-89
Al
CH
S
C-B63
C-B13
IV-90
Al
CH
S
C-B68
C-B13
IV-91
Al
CH
S
C-B69
C-B13
IV-92
Al
CH
S
C-B70
C-B13
IV-93
Al
CH
S
C-B71
C-B13
IV-94
Al
CH
S
C-B89
C-B13
IV-95
Al
CH
S
C-B90
C-B13
IV-96
Al
CH
S
C-B91
C-B13
IV-97
Al
CH
Se
C-B1
C-B1
IV-98
Al
CH
Se
C-B13
C-B13
IV-99
Al
CH
Se
C-B16
C-B13
IV-100
Al
CH
Se
C-B17
C-B13
IV-101
Al
CH
Se
C-B25
C-B13
IV-102
Al
CH
Se
C-B52
C-B13
IV-103
Al
CH
Se
C-B54
C-B13
IV-104
Al
CH
Se
C-B55
C-B13
IV-105
Al
CH
Se
C-B63
C-B13
IV-106
Al
CH
Se
C-B68
C-B13
IV-107
Al
CH
Se
C-B69
C-B13
IV-108
Al
CH
Se
C-B70
C-B13
IV-109
Al
CH
Se
C-B71
C-B13
IV-110
Al
CH
Se
C-B89
C-B13
IV-111
Al
CH
Se
C-B90
C-B13
IV-112
Al
CH
Se
C-B91
C-B13
IV-113
Al
CH
NMe
C-B1
C-B1
IV-114
Al
CH
NMe
C-B13
C-B13
IV-115
Al
CH
NMe
C-B16
C-B13
IV-116
Al
CH
NMe
C-B17
C-B13
IV-117
Al
CH
NMe
C-B25
C-B13
IV-118
Al
CH
NMe
C-B52
C-B13
IV-119
Al
CH
NMe
C-B54
C-B13
IV-120
Al
CH
NMe
C-B55
C-B13
IV-121
Al
CH
NMe
C-B63
C-B13
IV-122
Al
CH
NMe
C-B68
C-B13
IV-123
Al
CH
NMe
C-B69
C-B13
IV-124
Al
CH
NMe
C-B70
C-B13
IV-125
Al
CH
NMe
C-B71
C-B13
IV-126
Al
CH
NMe
C-B89
C-B13
IV-127
Al
CH
NMe
C-B90
C-B13
IV-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound V-1 to Compound V-128 have the structure of Formula V:
in Formula V, both of X are the same, both of Y are the same, both of W are the same, Z1 and Z2 are the same, Z3 and Z4 are the same, and X, Y, W, Z1, Z2, Z3 and Z4 are correspondingly selected from the atoms or groups as shown in the following table:
No.
X
Y
W
Z1 = Z2
Z3 = Z4
No.
X
Y
W
Z1 = Z2
Z3 = Z4
V-1
Al
N
O
C-B1
C-B1
V-2
Al
N
O
C-B13
C-B13
V-3
Al
N
O
C-B16
C-B13
V-4
Al
N
O
C-B17
C-B13
V-5
Al
N
O
C-B25
C-B13
V-6
Al
N
O
C-B52
C-B13
V-7
Al
N
O
C-B54
C-B13
V-8
Al
N
O
C-B55
C-B13
V-9
Al
N
O
C-B63
C-B13
V-10
Al
N
O
C-B68
C-B13
V-11
Al
N
O
C-B69
C-B13
V-12
Al
N
O
C-B70
C-B13
V-13
Al
N
O
C-B71
C-B13
V-14
Al
N
O
C-B89
C-B13
V-15
Al
N
O
C-B90
C-B13
V-16
Al
N
O
C-B91
C-B13
V-17
Al
N
S
C-B1
C-B1
V-18
Al
N
S
C-B13
C-B13
V-19
Al
N
S
C-B16
C-B13
V-20
Al
N
S
C-B17
C-B13
V-21
Al
N
S
C-B25
C-B13
V-22
Al
N
S
C-B52
C-B13
V-23
Al
N
S
C-B54
C-B13
V-24
Al
N
S
C-B55
C-B13
V-25
Al
N
S
C-B63
C-B13
V-26
Al
N
S
C-B68
C-B13
V-27
Al
N
S
C-B69
C-B13
V-28
Al
N
S
C-B70
C-B13
V-29
Al
N
S
C-B71
C-B13
V-30
Al
N
S
C-B89
C-B13
V-31
Al
N
S
C-B90
C-B13
V-32
Al
N
S
C-B91
C-B13
V-33
Al
N
Se
C-B1
C-B1
V-34
Al
N
Se
C-B13
C-B13
V-35
Al
N
Se
C-B16
C-B13
V-36
Al
N
Se
C-B17
C-B13
V-37
Al
N
Se
C-B25
C-B13
V-38
Al
N
Se
C-B52
C-B13
V-39
Al
N
Se
C-B54
C-B13
V-40
Al
N
Se
C-B55
C-B13
V-41
Al
N
Se
C-B63
C-B13
V-42
Al
N
Se
C-B68
C-B13
V-43
Al
N
Se
C-B69
C-B13
V-44
Al
N
Se
C-B70
C-B13
V-45
Al
N
Se
C-B71
C-B13
V-46
Al
N
Se
C-B89
C-B13
V-47
Al
N
Se
C-B90
C-B13
V-48
Al
N
Se
C-B91
C-B13
V-49
Al
N
NMe
C-B1
C-B1
V-50
Al
N
NMe
C-B13
C-B13
V-51
Al
N
NMe
C-B16
C-B13
V-52
Al
N
NMe
C-B17
C-B13
V-53
Al
N
NMe
C-B25
C-B13
V-54
Al
N
NMe
C-B52
C-B13
V-55
Al
N
NMe
C-B54
C-B13
V-56
Al
N
NMe
C-B55
C-B13
V-57
Al
N
NMe
C-B63
C-B13
V-58
Al
N
NMe
C-B68
C-B13
V-59
Al
N
NMe
C-B69
C-B13
V-60
Al
N
NMe
C-B70
C-B13
V-61
Al
N
NMe
C-B71
C-B13
V-62
Al
N
NMe
C-B89
C-B13
V-63
Al
N
NMe
C-B90
C-B13
V-64
Al
N
NMe
C-B91
C-B13
V-65
Al
CH
O
C-B1
C-B1
V-66
Al
CH
O
C-B13
C-B13
V-67
Al
CH
O
C-B16
C-B13
V-68
Al
CH
O
C-B17
C-B13
V-69
Al
CH
O
C-B25
C-B13
V-70
Al
CH
O
C-B52
C-B13
V-71
Al
CH
O
C-B54
C-B13
V-72
Al
CH
O
C-B55
C-B13
V-73
Al
CH
O
C-B63
C-B13
V-74
Al
CH
O
C-B68
C-B13
V-75
Al
CH
O
C-B69
C-B13
V-76
Al
CH
O
C-B70
C-B13
V-77
Al
CH
O
C-B71
C-B13
V-78
Al
CH
O
C-B89
C-B13
V-79
Al
CH
O
C-B90
C-B13
V-80
Al
CH
O
C-B91
C-B13
V-81
Al
CH
S
C-B1
C-B1
V-82
Al
CH
S
C-B13
C-B13
V-83
Al
CH
S
C-B16
C-B13
V-84
Al
CH
S
C-B17
C-B13
V-85
Al
CH
S
C-B25
C-B13
V-86
Al
CH
S
C-B52
C-B13
V-87
Al
CH
S
C-B54
C-B13
V-88
Al
CH
S
C-B55
C-B13
V-89
Al
CH
S
C-B63
C-B13
V-90
Al
CH
S
C-B68
C-B13
V-91
Al
CH
S
C-B69
C-B13
V-92
Al
CH
S
C-B70
C-B13
V-93
Al
CH
S
C-B71
C-B13
V-94
Al
CH
S
C-B89
C-B13
V-95
Al
CH
S
C-B90
C-B13
V-96
Al
CH
S
C-B91
C-B13
V-97
Al
CH
Se
C-B1
C-B1
V-98
Al
CH
Se
C-B13
C-B13
V-99
Al
CH
Se
C-B16
C-B13
V-100
Al
CH
Se
C-B17
C-B13
V-101
Al
CH
Se
C-B25
C-B13
V-102
Al
CH
Se
C-B52
C-B13
V-103
Al
CH
Se
C-B54
C-B13
V-104
Al
CH
Se
C-B55
C-B13
V-105
Al
CH
Se
C-B63
C-B13
V-106
Al
CH
Se
C-B68
C-B13
V-107
Al
CH
Se
C-B69
C-B13
V-108
Al
CH
Se
C-B70
C-B13
V-109
Al
CH
Se
C-B71
C-B13
V-110
Al
CH
Se
C-B89
C-B13
V-111
Al
CH
Se
C-B90
C-B13
V-112
Al
CH
Se
C-B91
C-B13
V-113
Al
CH
NMe
C-B1
C-B1
V-114
Al
CH
NMe
C-B13
C-B13
V-115
Al
CH
NMe
C-B16
C-B13
V-116
Al
CH
NMe
C-B17
C-B13
V-117
Al
CH
NMe
C-B25
C-B13
V-118
Al
CH
NMe
C-B52
C-B13
V-119
Al
CH
NMe
C-B54
C-B13
V-120
Al
CH
NMe
C-B55
C-B13
V-121
Al
CH
NMe
C-B63
C-B13
V-122
Al
CH
NMe
C-B68
C-B13
V-123
Al
CH
NMe
C-B69
C-B13
V-124
Al
CH
NMe
C-B70
C-B13
V-125
Al
CH
NMe
C-B71
C-B13
V-126
Al
CH
NMe
C-B89
C-B13
V-127
Al
CH
NMe
C-B90
C-B13
V-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound VI-1 to Compound VI-64 have the structure of Formula VI:
in Formula VI, both of X are the same, both of Y are the same, both of W are the same, Z1 and Z2 are the same, Z3 and Z4 are the same, and X, Y, W, Z1, Z2, Z3 and Z4 are correspondingly selected from the atoms or groups as shown in the following table:
No.
X
Y
W
Z1 = Z2
Z3 = Z4
No.
X
Y
W
Z1 = Z2
Z3 = Z4
VI-1
Al
N
O
C-B1
C-B1
VI-2
Al
N
O
C-B13
C-B13
VI-3
Al
N
O
C-B16
C-B13
VI-4
Al
N
O
C-B17
C-B13
VI-5
Al
N
O
C-B25
C-B13
VI-6
Al
N
O
C-B52
C-B13
VI-7
Al
N
O
C-B54
C-B13
VI-8
Al
N
O
C-B55
C-B13
VI-9
Al
N
O
C-B63
C-B13
VI-10
Al
N
O
C-B68
C-B13
VI-11
Al
N
O
C-B69
C-B13
VI-12
Al
N
O
C-B70
C-B13
VI-13
Al
N
O
C-B71
C-B13
VI-14
Al
N
O
C-B89
C-B13
VI-15
Al
N
O
C-B90
C-B13
VI-16
Al
N
O
C-B91
C-B13
VI-17
Al
N
S
C-B1
C-B1
VI-18
Al
N
S
C-B13
C-B13
VI-19
Al
N
S
C-B16
C-B13
VI-20
Al
N
S
C-B17
C-B13
VI-21
Al
N
S
C-B25
C-B13
VI-22
Al
N
S
C-B52
C-B13
VI-23
Al
N
S
C-B54
C-B13
VI-24
Al
N
S
C-B55
C-B13
VI-25
Al
N
S
C-B63
C-B13
VI-26
Al
N
S
C-B68
C-B13
VI-27
Al
N
S
C-B69
C-B13
VI-28
Al
N
S
C-B70
C-B13
VI-29
Al
N
S
C-B71
C-B13
VI-30
Al
N
S
C-B89
C-B13
VI-31
Al
N
S
C-B90
C-B13
VI-32
Al
N
S
C-B91
C-B13
VI-33
Al
N
Se
C-B1
C-B1
VI-34
Al
N
Se
C-B13
C-B13
VI-35
Al
N
Se
C-B16
C-B13
VI-36
Al
N
Se
C-B17
C-B13
VI-37
Al
N
Se
C-B25
C-B13
VI-38
Al
N
Se
C-B52
C-B13
VI-39
Al
N
Se
C-B54
C-B13
VI-40
Al
N
Se
C-B55
C-B13
VI-41
Al
N
Se
C-B63
C-B13
VI-42
Al
N
Se
C-B68
C-B13
VI-43
Al
N
Se
C-B69
C-B13
VI-44
Al
N
Se
C-B70
C-B13
VI-45
Al
N
Se
C-B71
C-B13
VI-46
Al
N
Se
C-B89
C-B13
VI-47
Al
N
Se
C-B90
C-B13
VI-48
Al
N
Se
C-B91
C-B13
VI-49
Al
N
NMe
C-B1
C-B1
VI-50
Al
N
NMe
C-B13
C-B13
VI-51
Al
N
NMe
C-B16
C-B13
VI-52
Al
N
NMe
C-B17
C-B13
VI-53
Al
N
NMe
C-B25
C-B13
VI-54
Al
N
NMe
C-B52
C-B13
VI-55
Al
N
NMe
C-B54
C-B13
VI-56
Al
N
NMe
C-B55
C-B13
VI-57
Al
N
NMe
C-B63
C-B13
VI-58
Al
N
NMe
C-B68
C-B13
VI-59
Al
N
NMe
C-B69
C-B13
VI-60
Al
N
NMe
C-B70
C-B13
VI-61
Al
N
NMe
C-B71
C-B13
VI-62
Al
N
NMe
C-B89
C-B13
VI-63
Al
N
NMe
C-B90
C-B13
VI-64
Al
N
NMe
C-B91
C-B13
wherein, Compound VII-1 to Compound VII-64 have the structure of Formula VII:
in Formula VII, both of X are the same, both of Y are the same, both of W are the same, Z1, Z2, Z5 and Z6 are the same, Z3 and Z4 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z1 = Z2 =
Z1 = Z2 =
No.
X
Y
W
Z3 = Z4
Z5 = Z6
No.
X
Y
W
Z3 = Z4
Z5 = Z6
VII-1
Al
N
O
C-B1
C-B1
VII-2
Al
N
O
C-B13
C-B13
VII-3
Al
N
O
C-B16
C-B13
VII-4
Al
N
O
C-B17
C-B13
VII-5
Al
N
O
C-B25
C-B13
VII-6
Al
N
O
C-B52
C-B13
VII-7
Al
N
O
C-B54
C-B13
VII-8
Al
N
O
C-B55
C-B13
VII-9
Al
N
O
C-B63
C-B13
VII-10
Al
N
O
C-B68
C-B13
VII-11
Al
N
O
C-B69
C-B13
VII-12
Al
N
O
C-B70
C-B13
VII-13
Al
N
O
C-B71
C-B13
VII-14
Al
N
O
C-B89
C-B13
VII-15
Al
N
O
C-B90
C-B13
VII-16
Al
N
O
C-B91
C-B13
VII-17
Al
N
S
C-B1
C-B1
VII-18
Al
N
S
C-B13
C-B13
VII-19
Al
N
S
C-B16
C-B13
VII-20
Al
N
S
C-B17
C-B13
VII-21
Al
N
S
C-B25
C-B13
VII-22
Al
N
S
C-B52
C-B13
VII-23
Al
N
S
C-B54
C-B13
VII-24
Al
N
S
C-B55
C-B13
VII-25
Al
N
S
C-B63
C-B13
VII-26
Al
N
S
C-B68
C-B13
VII-27
Al
N
S
C-B69
C-B13
VII-28
Al
N
S
C-B70
C-B13
VII-29
Al
N
S
C-B71
C-B13
VII-30
Al
N
S
C-B89
C-B13
VII-31
Al
N
S
C-B90
C-B13
VII-32
Al
N
S
C-B91
C-B13
VII-33
Al
N
Se
C-B1
C-B1
VII-34
Al
N
Se
C-B13
C-B13
VII-35
Al
N
Se
C-B16
C-B13
VII-36
Al
N
Se
C-B17
C-B13
VII-37
Al
N
Se
C-B25
C-B13
VII-38
Al
N
Se
C-B52
C-B13
VII-39
Al
N
Se
C-B54
C-B13
VII-40
Al
N
Se
C-B55
C-B13
VII-41
Al
N
Se
C-B63
C-B13
VII-42
Al
N
Se
C-B68
C-B13
VII-43
Al
N
Se
C-B69
C-B13
VII-44
Al
N
Se
C-B70
C-B13
VII-45
Al
N
Se
C-B71
C-B13
VII-46
Al
N
Se
C-B89
C-B13
VII-47
Al
N
Se
C-B90
C-B13
VII-48
Al
N
Se
C-B91
C-B13
VII-49
Al
N
NMe
C-B1
C-B1
VII-50
Al
N
NMe
C-B13
C-B13
VII-51
Al
N
NMe
C-B16
C-B13
VII-52
Al
N
NMe
C-B17
C-B13
VII-53
Al
N
NMe
C-B25
C-B13
VII-54
Al
N
NMe
C-B52
C-B13
VII-55
Al
N
NMe
C-B54
C-B13
VII-56
Al
N
NMe
C-B55
C-B13
VII-57
Al
N
NMe
C-B63
C-B13
VII-58
Al
N
NMe
C-B68
C-B13
VII-59
Al
N
NMe
C-B69
C-B13
VII-60
Al
N
NMe
C-B70
C-B13
VII-61
Al
N
NMe
C-B71
C-B13
VII-62
Al
N
NMe
C-B89
C-B13
VII-63
Al
N
NMe
C-B90
C-B13
VII-64
Al
N
NMe
C-B91
C-B13
wherein, Compound VIII-1 to Compound VIII-128 have the structure of Formula VIII:
in Formula VIII, both of X are the same, both of Y are the same, both of W are the same, Z1, Z2, Z5 and Z6 are the same, Z3 and Z4 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z1 = Z2 =
Z1 = Z2 =
No.
X
Y
W
Z3 = Z4
Z5 = Z6
No.
X
Y
W
Z3 = Z4
Z5 = Z6
VIII-1
Al
N
O
C-B1
C-B1
VIII-2
Al
N
O
C-B13
C-B13
VIII-3
Al
N
O
C-B16
C-B13
VIII-4
Al
N
O
C-B17
C-B13
VIII-5
Al
N
O
C-B25
C-B13
VIII-6
Al
N
O
C-B52
C-B13
VIII-7
Al
N
O
C-B54
C-B13
VIII-8
Al
N
O
C-B55
C-B13
VIII-9
Al
N
O
C-B63
C-B13
VIII-10
Al
N
O
C-B68
C-B13
VIII-11
Al
N
O
C-B69
C-B13
VIII-12
Al
N
O
C-B70
C-B13
VIII-13
Al
N
O
C-B71
C-B13
VIII-14
Al
N
O
C-B89
C-B13
VIII-15
Al
N
O
C-B90
C-B13
VIII-16
Al
N
O
C-B91
C-B13
VIII-17
Al
N
S
C-B1
C-B1
VIII-18
Al
N
S
C-B13
C-B13
VIII-19
Al
N
S
C-B16
C-B13
VIII-20
Al
N
S
C-B17
C-B13
VIII-21
Al
N
S
C-B25
C-B13
VIII-22
Al
N
S
C-B52
C-B13
VIII-23
Al
N
S
C-B54
C-B13
VIII-24
Al
N
S
C-B55
C-B13
VIII-25
Al
N
S
C-B63
C-B13
VIII-26
Al
N
S
C-B68
C-B13
VIII-27
Al
N
S
C-B69
C-B13
VIII-28
Al
N
S
C-B70
C-B13
VIII-29
Al
N
S
C-B71
C-B13
VIII-30
Al
N
S
C-B89
C-B13
VIII-31
Al
N
S
C-B90
C-B13
VIII-32
Al
N
S
C-B91
C-B13
VIII-33
Al
N
Se
C-B1
C-B1
VIII-34
Al
N
Se
C-B13
C-B13
VIII-35
Al
N
Se
C-B16
C-B13
VIII-36
Al
N
Se
C-B17
C-B13
VIII-37
Al
N
Se
C-B25
C-B13
VIII-38
Al
N
Se
C-B52
C-B13
VIII-39
Al
N
Se
C-B54
C-B13
VIII-40
Al
N
Se
C-B55
C-B13
VIII-41
Al
N
Se
C-B63
C-B13
VIII-42
Al
N
Se
C-B68
C-B13
VIII-43
Al
N
Se
C-B69
C-B13
VIII-44
Al
N
Se
C-B70
C-B13
VIII-45
Al
N
Se
C-B71
C-B13
VIII-46
Al
N
Se
C-B89
C-B13
VIII-47
Al
N
Se
C-B90
C-B13
VIII-48
Al
N
Se
C-B91
C-B13
VIII-49
Al
N
NMe
C-B1
C-B1
VIII-50
Al
N
NMe
C-B13
C-B13
VIII-51
Al
N
NMe
C-B16
C-B13
VIII-52
Al
N
NMe
C-B17
C-B13
VIII-53
Al
N
NMe
C-B25
C-B13
VIII-54
Al
N
NMe
C-B52
C-B13
VIII-55
Al
N
NMe
C-B54
C-B13
VIII-56
Al
N
NMe
C-B55
C-B13
VIII-57
Al
N
NMe
C-B63
C-B13
VIII-58
Al
N
NMe
C-B68
C-B13
VIII-59
Al
N
NMe
C-B69
C-B13
VIII-60
Al
N
NMe
C-B70
C-B13
VIII-61
Al
N
NMe
C-B71
C-B13
VIII-62
Al
N
NMe
C-B89
C-B13
VIII-63
Al
N
NMe
C-B90
C-B13
VIII-64
Al
N
NMe
C-B91
C-B13
VIII-65
Al
CH
O
C-B1
C-B1
VIII-66
Al
CH
O
C-B13
C-B13
VIII-67
Al
CH
O
C-B16
C-B13
VIII-68
Al
CH
O
C-B17
C-B13
VIII-69
Al
CH
O
C-B25
C-B13
VIII-70
Al
CH
O
C-B52
C-B13
VIII-71
Al
CH
O
C-B54
C-B13
VIII-72
Al
CH
O
C-B55
C-B13
VIII-73
Al
CH
O
C-B63
C-B13
VIII-74
Al
CH
O
C-B68
C-B13
VIII-75
Al
CH
O
C-B69
C-B13
VIII-76
Al
CH
O
C-B70
C-B13
VIII-77
Al
CH
O
C-B71
C-B13
VIII-78
Al
CH
O
C-B89
C-B13
VIII-79
Al
CH
O
C-B90
C-B13
VIII-80
Al
CH
O
C-B91
C-B13
VIII-81
Al
CH
S
C-B1
C-B1
VIII-82
Al
CH
S
C-B13
C-B13
VIII-83
Al
CH
S
C-B16
C-B13
VIII-84
Al
CH
S
C-B17
C-B13
VIII-85
Al
CH
S
C-B25
C-B13
VIII-86
Al
CH
S
C-B52
C-B13
VIII-87
Al
CH
S
C-B54
C-B13
VIII-88
Al
CH
S
C-B55
C-B13
VIII-89
Al
CH
S
C-B63
C-B13
VIII-90
Al
CH
S
C-B68
C-B13
VIII-91
Al
CH
S
C-B69
C-B13
VIII-92
Al
CH
S
C-B70
C-B13
VIII-93
Al
CH
S
C-B71
C-B13
VIII-94
Al
CH
S
C-B89
C-B13
VIII-95
Al
CH
S
C-B90
C-B13
VIII-96
Al
CH
S
C-B91
C-B13
VIII-97
Al
CH
Se
C-B1
C-B1
VIII-98
Al
CH
Se
C-B13
C-B13
VIII-99
Al
CH
Se
C-B16
C-B13
VIII-100
Al
CH
Se
C-B17
C-B13
VIII-101
Al
CH
Se
C-B25
C-B13
VIII-102
Al
CH
Se
C-B52
C-B13
VIII-103
Al
CH
Se
C-B54
C-B13
VIII-104
Al
CH
Se
C-B55
C-B13
VIII-105
Al
CH
Se
C-B63
C-B13
VIII-106
Al
CH
Se
C-B68
C-B13
VIII-107
Al
CH
Se
C-B69
C-B13
VIII-108
Al
CH
Se
C-B70
C-B13
VIII-109
Al
CH
Se
C-B71
C-B13
VIII-110
Al
CH
Se
C-B89
C-B13
VIII-111
Al
CH
Se
C-B90
C-B13
VIII-112
Al
CH
Se
C-B91
C-B13
VIII-113
Al
CH
NMe
C-B1
C-B1
VIII-114
Al
CH
NMe
C-B13
C-B13
VIII-115
Al
CH
NMe
C-B16
C-B13
VIII-116
Al
CH
NMe
C-B17
C-B13
VIII-117
Al
CH
NMe
C-B25
C-B13
VIII-118
Al
CH
NMe
C-B52
C-B13
VIII-119
Al
CH
NMe
C-B54
C-B13
VIII-120
Al
CH
NMe
C-B55
C-B13
VIII-121
Al
CH
NMe
C-B63
C-B13
VIII-122
Al
CH
NMe
C-B68
C-B13
VIII-123
Al
CH
NMe
C-B69
C-B13
VIII-124
Al
CH
NMe
C-B70
C-B13
VIII-125
Al
CH
NMe
C-B71
C-B13
VIII-126
Al
CH
NMe
C-B89
C-B13
VIII-127
Al
CH
NMe
C-B90
C-B13
VIII-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound IX-1 to Compound IX-128 have the structure of Formula IX:
in Formula IX, both of X are the same, both of Y are the same, both of W are the same, Z3, Z4, Z5 and Z6 are the same, Z1 and Z2 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z3 = Z4 =
Z3 = Z4 =
No.
X
Y
W
Z1 = Z2
Z5 = Z6
No.
X
Y
W
Z1 = Z2
Z5 = Z6
IX-1
Al
N
O
C-B1
C-B1
IX-2
Al
N
O
C-B13
C-B13
IX-3
Al
N
O
C-B16
C-B13
IX-4
Al
N
O
C-B17
C-B13
IX-5
Al
N
O
C-B25
C-B13
IX-6
Al
N
O
C-B52
C-B13
IX-7
Al
N
O
C-B54
C-B13
IX-8
Al
N
O
C-B55
C-B13
IX-9
Al
N
O
C-B63
C-B13
IX-10
Al
N
O
C-B68
C-B13
IX-11
Al
N
O
C-B69
C-B13
IX-12
Al
N
O
C-B70
C-B13
IX-13
Al
N
O
C-B71
C-B13
IX-14
Al
N
O
C-B89
C-B13
IX-15
Al
N
O
C-B90
C-B13
IX-16
Al
N
O
C-B91
C-B13
IX-17
Al
N
S
C-B1
C-B1
IX-18
Al
N
S
C-B13
C-B13
IX-19
Al
N
S
C-B16
C-B13
IX-20
Al
N
S
C-B17
C-B13
IX-21
Al
N
S
C-B25
C-B13
IX-22
Al
N
S
C-B52
C-B13
IX-23
Al
N
S
C-B54
C-B13
IX-24
Al
N
S
C-B55
C-B13
IX-25
Al
N
S
C-B63
C-B13
IX-26
Al
N
S
C-B68
C-B13
IX-27
Al
N
S
C-B69
C-B13
IX-28
Al
N
S
C-B70
C-B13
IX-29
Al
N
S
C-B71
C-B13
IX-30
Al
N
S
C-B89
C-B13
IX-31
Al
N
S
C-B90
C-B13
IX-32
Al
N
S
C-B91
C-B13
IX-33
Al
N
Se
C-B1
C-B1
IX-34
Al
N
Se
C-B13
C-B13
IX-35
Al
N
Se
C-B16
C-B13
IX-36
Al
N
Se
C-B17
C-B13
IX-37
Al
N
Se
C-B25
C-B13
IX-38
Al
N
Se
C-B52
C-B13
IX-39
Al
N
Se
C-B54
C-B13
IX-40
Al
N
Se
C-B55
C-B13
IX-41
Al
N
Se
C-B63
C-B13
IX-42
Al
N
Se
C-B68
C-B13
IX-43
Al
N
Se
C-B69
C-B13
IX-44
Al
N
Se
C-B70
C-B13
IX-45
Al
N
Se
C-B71
C-B13
IX-46
Al
N
Se
C-B89
C-B13
IX-47
Al
N
Se
C-B90
C-B13
IX-48
Al
N
Se
C-B91
C-B13
IX-49
Al
N
NMe
C-B1
C-B1
IX-50
Al
N
NMe
C-B13
C-B13
IX-51
Al
N
NMe
C-B16
C-B13
IX-52
Al
N
NMe
C-B17
C-B13
IX-53
Al
N
NMe
C-B25
C-B13
IX-54
Al
N
NMe
C-B52
C-B13
IX-55
Al
N
NMe
C-B54
C-B13
IX-56
Al
N
NMe
C-B55
C-B13
IX-57
Al
N
NMe
C-B63
C-B13
IX-58
Al
N
NMe
C-B68
C-B13
IX-59
Al
N
NMe
C-B69
C-B13
IX-60
Al
N
NMe
C-B70
C-B13
IX-61
Al
N
NMe
C-B71
C-B13
IX-62
Al
N
NMe
C-B89
C-B13
IX-63
Al
N
NMe
C-B90
C-B13
IX-64
Al
N
NMe
C-B91
C-B13
IX-65
Al
CH
O
C-B1
C-B1
IX-66
Al
CH
O
C-B13
C-B13
IX-67
Al
CH
O
C-B16
C-B13
IX-68
Al
CH
O
C-B17
C-B13
IX-69
Al
CH
O
C-B25
C-B13
IX-70
Al
CH
O
C-B52
C-B13
IX-71
Al
CH
O
C-B54
C-B13
IX-72
Al
CH
O
C-B55
C-B13
IX-73
Al
CH
O
C-B63
C-B13
IX-74
Al
CH
O
C-B68
C-B13
IX-75
Al
CH
O
C-B69
C-B13
IX-76
Al
CH
O
C-B70
C-B13
IX-77
Al
CH
O
C-B71
C-B13
IX-78
Al
CH
O
C-B89
C-B13
IX-79
Al
CH
O
C-B90
C-B13
IX-80
Al
CH
O
C-B91
C-B13
IX-81
Al
CH
S
C-B1
C-B1
IX-82
Al
CH
S
C-B13
C-B13
IX-83
Al
CH
S
C-B16
C-B13
IX-84
Al
CH
S
C-B17
C-B13
IX-85
Al
CH
S
C-B25
C-B13
IX-86
Al
CH
S
C-B52
C-B13
IX-87
Al
CH
S
C-B54
C-B13
IX-88
Al
CH
S
C-B55
C-B13
IX-89
Al
CH
S
C-B63
C-B13
IX-90
Al
CH
S
C-B68
C-B13
IX-91
Al
CH
S
C-B69
C-B13
IX-92
Al
CH
S
C-B70
C-B13
IX-93
Al
CH
S
C-B71
C-B13
IX-94
Al
CH
S
C-B89
C-B13
IX-95
Al
CH
S
C-B90
C-B13
IX-96
Al
CH
S
C-B91
C-B13
IX-97
Al
CH
Se
C-B1
C-B1
IX-98
Al
CH
Se
C-B13
C-B13
IX-99
Al
CH
Se
C-B16
C-B13
IX-100
Al
CH
Se
C-B17
C-B13
IX-101
Al
CH
Se
C-B25
C-B13
IX-102
Al
CH
Se
C-B52
C-B13
IX-103
Al
CH
Se
C-B54
C-B13
IX-104
Al
CH
Se
C-B55
C-B13
IX-105
Al
CH
Se
C-B63
C-B13
IX-106
Al
CH
Se
C-B68
C-B13
IX-107
Al
CH
Se
C-B69
C-B13
IX-108
Al
CH
Se
C-B70
C-B13
IX-109
Al
CH
Se
C-B71
C-B13
IX-110
Al
CH
Se
C-B89
C-B13
IX-111
Al
CH
Se
C-B90
C-B13
IX-112
Al
CH
Se
C-B91
C-B13
IX-113
Al
CH
NMe
C-B1
C-B1
IX-114
Al
CH
NMe
C-B13
C-B13
IX-115
Al
CH
NMe
C-B16
C-B13
IX-116
Al
CH
NMe
C-B17
C-B13
IX-117
Al
CH
NMe
C-B25
C-B13
IX-118
Al
CH
NMe
C-B52
C-B13
IX-119
Al
CH
NMe
C-B54
C-B13
IX-120
Al
CH
NMe
C-B55
C-B13
IX-121
Al
CH
NMe
C-B63
C-B13
IX-122
Al
CH
NMe
C-B68
C-B13
IX-123
Al
CH
NMe
C-B69
C-B13
IX-124
Al
CH
NMe
C-B70
C-B13
IX-125
Al
CH
NMe
C-B71
C-B13
IX-126
Al
CH
NMe
C-B89
C-B13
IX-127
Al
CH
NMe
C-B90
C-B13
IX-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound X-1 to Compound X-128 have the structure of Formula X:
in Formula X, both of X are the same, both of Y are the same, both of W are the same, Z3, Z4, Z5 and Z6 are the same, Z1 and Z2 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z3 = Z4 =
Z3 = Z4 =
No.
X
Y
W
Z1 = Z2
Z5 = Z6
No.
X
Y
W
Z1 = Z2
Z5 = Z6
X-1
Al
N
O
C-B1
C-B1
X-2
Al
N
O
C-B13
C-B13
X-3
Al
N
O
C-B16
C-B13
X-4
Al
N
O
C-B17
C-B13
X-5
Al
N
O
C-B25
C-B13
X-6
Al
N
O
C-B52
C-B13
X-7
Al
N
O
C-B54
C-B13
X-8
Al
N
O
C-B55
C-B13
X-9
Al
N
O
C-B63
C-B13
X-10
Al
N
O
C-B68
C-B13
X-11
Al
N
O
C-B69
C-B13
X-12
Al
N
O
C-B70
C-B13
X-13
Al
N
O
C-B71
C-B13
X-14
Al
N
O
C-B89
C-B13
X-15
Al
N
O
C-B90
C-B13
X-16
Al
N
O
C-B91
C-B13
X-17
Al
N
S
C-B1
C-B1
X-18
Al
N
S
C-B13
C-B13
X-19
Al
N
S
C-B16
C-B13
X-20
Al
N
S
C-B17
C-B13
X-21
Al
N
S
C-B25
C-B13
X-22
Al
N
S
C-B52
C-B13
X-23
Al
N
S
C-B54
C-B13
X-24
Al
N
S
C-B55
C-B13
X-25
Al
N
S
C-B63
C-B13
X-26
Al
N
S
C-B68
C-B13
X-27
Al
N
S
C-B69
C-B13
X-28
Al
N
S
C-B70
C-B13
X-29
Al
N
S
C-B71
C-B13
X-30
Al
N
S
C-B89
C-B13
X-31
Al
N
S
C-B90
C-B13
X-32
Al
N
S
C-B91
C-B13
X-33
Al
N
Se
C-B1
C-B1
X-34
Al
N
Se
C-B13
C-B13
X-35
Al
N
Se
C-B16
C-B13
X-36
Al
N
Se
C-B17
C-B13
X-37
Al
N
Se
C-B25
C-B13
X-38
Al
N
Se
C-B52
C-B13
X-39
Al
N
Se
C-B54
C-B13
X-40
Al
N
Se
C-B55
C-B13
X-41
Al
N
Se
C-B63
C-B13
X-42
Al
N
Se
C-B68
C-B13
X-43
Al
N
Se
C-B69
C-B13
X-44
Al
N
Se
C-B70
C-B13
X-45
Al
N
Se
C-B71
C-B13
X-46
Al
N
Se
C-B89
C-B13
X-47
Al
N
Se
C-B90
C-B13
X-48
Al
N
Se
C-B91
C-B13
X-49
Al
N
NMe
C-B1
C-B1
X-50
Al
N
NMe
C-B13
C-B13
X-51
Al
N
NMe
C-B16
C-B13
X-52
Al
N
NMe
C-B17
C-B13
X-53
Al
N
NMe
C-B25
C-B13
X-54
Al
N
NMe
C-B52
C-B13
X-55
Al
N
NMe
C-B54
C-B13
X-56
Al
N
NMe
C-B55
C-B13
X-57
Al
N
NMe
C-B63
C-B13
X-58
Al
N
NMe
C-B68
C-B13
X-59
Al
N
NMe
C-B69
C-B13
X-60
Al
N
NMe
C-B70
C-B13
X-61
Al
N
NMe
C-B71
C-B13
X-62
Al
N
NMe
C-B89
C-B13
X-63
Al
N
NMe
C-B90
C-B13
X-64
Al
N
NMe
C-B91
C-B13
X-65
Al
CH
O
C-B1
C-B1
X-66
Al
CH
O
C-B13
C-B13
X-67
Al
CH
O
C-B16
C-B13
X-68
Al
CH
O
C-B17
C-B13
X-69
Al
CH
O
C-B25
C-B13
X-70
Al
CH
O
C-B52
C-B13
X-71
Al
CH
O
C-B54
C-B13
X-72
Al
CH
O
C-B55
C-B13
X-73
Al
CH
O
C-B63
C-B13
X-74
Al
CH
O
C-B68
C-B13
X-75
Al
CH
O
C-B69
C-B13
X-76
Al
CH
O
C-B70
C-B13
X-77
Al
CH
O
C-B71
C-B13
X-78
Al
CH
O
C-B89
C-B13
X-79
Al
CH
O
C-B90
C-B13
X-80
Al
CH
O
C-B91
C-B13
X-81
Al
CH
S
C-B1
C-B1
X-82
Al
CH
S
C-B13
C-B13
X-83
Al
CH
S
C-B16
C-B13
X-84
Al
CH
S
C-B17
C-B13
X-85
Al
CH
S
C-B25
C-B13
X-86
Al
CH
S
C-B52
C-B13
X-87
Al
CH
S
C-B54
C-B13
X-88
Al
CH
S
C-B55
C-B13
X-89
Al
CH
S
C-B63
C-B13
X-90
Al
CH
S
C-B68
C-B13
X-91
Al
CH
S
C-B69
C-B13
X-92
Al
CH
S
C-B70
C-B13
X-93
Al
CH
S
C-B71
C-B13
X-94
Al
CH
S
C-B89
C-B13
X-95
Al
CH
S
C-B90
C-B13
X-96
Al
CH
S
C-B91
C-B13
X-97
Al
CH
Se
C-B1
C-B1
X-98
Al
CH
Se
C-B13
C-B13
X-99
Al
CH
Se
C-B16
C-B13
X-100
Al
CH
Se
C-B17
C-B13
X-101
Al
CH
Se
C-B25
C-B13
X-102
Al
CH
Se
C-B52
C-B13
X-103
Al
CH
Se
C-B54
C-B13
X-104
Al
CH
Se
C-B55
C-B13
X-105
Al
CH
Se
C-B63
C-B13
X-106
Al
CH
Se
C-B68
C-B13
X-107
Al
CH
Se
C-B69
C-B13
X-108
Al
CH
Se
C-B70
C-B13
X-109
Al
CH
Se
C-B71
C-B13
X-110
Al
CH
Se
C-B89
C-B13
X-111
Al
CH
Se
C-B90
C-B13
X-112
Al
CH
Se
C-B91
C-B13
X-113
Al
CH
NMe
C-B1
C-B1
X-114
Al
CH
NMe
C-B13
C-B13
X-115
Al
CH
NMe
C-B16
C-B13
X-116
Al
CH
NMe
C-B17
C-B13
X-117
Al
CH
NMe
C-B25
C-B13
X-118
Al
CH
NMe
C-B52
C-B13
X-119
Al
CH
NMe
C-B54
C-B13
X-120
Al
CH
NMe
C-B55
C-B13
X-121
Al
CH
NMe
C-B63
C-B13
X-122
Al
CH
NMe
C-B68
C-B13
X-123
Al
CH
NMe
C-B69
C-B13
X-124
Al
CH
NMe
C-B70
C-B13
X-125
Al
CH
NMe
C-B71
C-B13
X-126
Al
CH
NMe
C-B89
C-B13
X-127
Al
CH
NMe
C-B90
C-B13
X-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound XI-1 to Compound XI-128 have the structure of Formula XI:
in Formula XI, both of X are the same, both of Y are the same, both of W are the same, Z1, Z2, Z5 and Z6 are the same, Z3 and Z4 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z1 = Z2 =
Z1 = Z2 =
No.
X
Y
W
Z3 = Z4
Z5 = Z6
No.
X
Y
W
Z3 = Z4
Z5 = Z6
XI-1
Al
N
O
C-B1
C-B1
XI-2
Al
N
O
C-B13
C-B13
XI-3
Al
N
O
C-B16
C-B13
XI-4
Al
N
O
C-B17
C-B13
XI-5
Al
N
O
C-B25
C-B13
XI-6
Al
N
O
C-B52
C-B13
XI-7
Al
N
O
C-B54
C-B13
XI-8
Al
N
O
C-B55
C-B13
XI-9
Al
N
O
C-B63
C-B13
XI-10
Al
N
O
C-B68
C-B13
XI-11
Al
N
O
C-B69
C-B13
XI-12
Al
N
O
C-B70
C-B13
XI-13
Al
N
O
C-B71
C-B13
XI-14
Al
N
O
C-B89
C-B13
XI-15
Al
N
O
C-B90
C-B13
XI-16
Al
N
O
C-B91
C-B13
XI-17
Al
N
S
C-B1
C-B1
XI-18
Al
N
S
C-B13
C-B13
XI-19
Al
N
S
C-B16
C-B13
XI-20
Al
N
S
C-B17
C-B13
XI-21
Al
N
S
C-B25
C-B13
XI-22
Al
N
S
C-B52
C-B13
XI-23
Al
N
S
C-B54
C-B13
XI-24
Al
N
S
C-B55
C-B13
XI-25
Al
N
S
C-B63
C-B13
XI-26
Al
N
S
C-B68
C-B13
XI-27
Al
N
S
C-B69
C-B13
XI-28
Al
N
S
C-B70
C-B13
XI-29
Al
N
S
C-B71
C-B13
XI-30
Al
N
S
C-B89
C-B13
XI-31
Al
N
S
C-B90
C-B13
XI-32
Al
N
S
C-B91
C-B13
XI-33
Al
N
Se
C-B1
C-B1
XI-34
Al
N
Se
C-B13
C-B13
XI-35
Al
N
Se
C-B16
C-B13
XI-36
Al
N
Se
C-B17
C-B13
XI-37
Al
N
Se
C-B25
C-B13
XI-38
Al
N
Se
C-B52
C-B13
XI-39
Al
N
Se
C-B54
C-B13
XI-40
Al
N
Se
C-B55
C-B13
XI-41
Al
N
Se
C-B63
C-B13
XI-42
Al
N
Se
C-B68
C-B13
XI-43
Al
N
Se
C-B69
C-B13
XI-44
Al
N
Se
C-B70
C-B13
XI-45
Al
N
Se
C-B71
C-B13
XI-46
Al
N
Se
C-B89
C-B13
XI-47
Al
N
Se
C-B90
C-B13
XI-48
Al
N
Se
C-B91
C-B13
XI-49
Al
N
NMe
C-B1
C-B1
XI-50
Al
N
NMe
C-B13
C-B13
XI-51
Al
N
NMe
C-B16
C-B13
XI-52
Al
N
NMe
C-B17
C-B13
XI-53
Al
N
NMe
C-B25
C-B13
XI-54
Al
N
NMe
C-B52
C-B13
XI-55
Al
N
NMe
C-B54
C-B13
XI-56
Al
N
NMe
C-B55
C-B13
XI-57
Al
N
NMe
C-B63
C-B13
XI-58
Al
N
NMe
C-B68
C-B13
XI-59
Al
N
NMe
C-B69
C-B13
XI-60
Al
N
NMe
C-B70
C-B13
XI-61
Al
N
NMe
C-B71
C-B13
XI-62
Al
N
NMe
C-B89
C-B13
XI-63
Al
N
NMe
C-B90
C-B13
XI-64
Al
N
NMe
C-B91
C-B13
XI-65
Al
CH
O
C-B1
C-B1
XI-66
Al
CH
O
C-B13
C-B13
XI-67
Al
CH
O
C-B16
C-B13
XI-68
Al
CH
O
C-B17
C-B13
XI-69
Al
CH
O
C-B25
C-B13
XI-70
Al
CH
O
C-B52
C-B13
XI-71
Al
CH
O
C-B54
C-B13
XI-72
Al
CH
O
C-B55
C-B13
XI-73
Al
CH
O
C-B63
C-B13
XI-74
Al
CH
O
C-B68
C-B13
XI-75
Al
CH
O
C-B69
C-B13
XI-76
Al
CH
O
C-B70
C-B13
XI-77
Al
CH
O
C-B71
C-B13
XI-78
Al
CH
O
C-B89
C-B13
XI-79
Al
CH
O
C-B90
C-B13
XI-80
Al
CH
O
C-B91
C-B13
XI-81
Al
CH
S
C-B1
C-B1
XI-82
Al
CH
S
C-B13
C-B13
XI-83
Al
CH
S
C-B16
C-B13
XI-84
Al
CH
S
C-B17
C-B13
XI-85
Al
CH
S
C-B25
C-B13
XI-86
Al
CH
S
C-B52
C-B13
XI-87
Al
CH
S
C-B54
C-B13
XI-88
Al
CH
S
C-B55
C-B13
XI-89
Al
CH
S
C-B63
C-B13
XI-90
Al
CH
S
C-B68
C-B13
XI-91
Al
CH
S
C-B69
C-B13
XI-92
Al
CH
S
C-B70
C-B13
XI-93
Al
CH
S
C-B71
C-B13
XI-94
Al
CH
S
C-B89
C-B13
XI-95
Al
CH
S
C-B90
C-B13
XI-96
Al
CH
S
C-B91
C-B13
XI-97
Al
CH
Se
C-B1
C-B1
XI-98
Al
CH
Se
C-B13
C-B13
XI-99
Al
CH
Se
C-B16
C-B13
XI-100
Al
CH
Se
C-B17
C-B13
XI-101
Al
CH
Se
C-B25
C-B13
XI-102
Al
CH
Se
C-B52
C-B13
XI-103
Al
CH
Se
C-B54
C-B13
XI-104
Al
CH
Se
C-B55
C-B13
XI-105
Al
CH
Se
C-B63
C-B13
XI-106
Al
CH
Se
C-B68
C-B13
XI-107
Al
CH
Se
C-B69
C-B13
XI-108
Al
CH
Se
C-B70
C-B13
XI-109
Al
CH
Se
C-B71
C-B13
XI-110
Al
CH
Se
C-B89
C-B13
XI-111
Al
CH
Se
C-B90
C-B13
XI-112
Al
CH
Se
C-B91
C-B13
XI-113
Al
CH
NMe
C-B1
C-B1
XI-114
Al
CH
NMe
C-B13
C-B13
XI-115
Al
CH
NMe
C-B16
C-B13
XI-116
Al
CH
NMe
C-B17
C-B13
XI-117
Al
CH
NMe
C-B25
C-B13
XI-118
Al
CH
NMe
C-B52
C-B13
XI-119
Al
CH
NMe
C-B54
C-B13
XI-120
Al
CH
NMe
C-B55
C-B13
XI-121
Al
CH
NMe
C-B63
C-B13
XI-122
Al
CH
NMe
C-B68
C-B13
XI-123
Al
CH
NMe
C-B69
C-B13
XI-124
Al
CH
NMe
C-B70
C-B13
XI-125
Al
CH
NMe
C-B71
C-B13
XI-126
Al
CH
NMe
C-B89
C-B13
XI-127
Al
CH
NMe
C-B90
C-B13
XI-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound XII-1 to Compound XII-128 have the structure of Formula XII:
in Formula XII, both of X are the same, both of Y are the same, both of W are the same, Z1, Z2, Z5 and Z6 are the same, Z3 and Z4 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z1 = Z2 =
Z1 = Z2 =
No.
X
Y
W
Z3 = Z4
Z5 = Z6
No.
X
Y
W
Z3 = Z4
Z5 = Z6
XII-1
Al
N
O
C-B1
C-B1
XII-2
Al
N
O
C-B13
C-B13
XII-3
Al
N
O
C-B16
C-B13
XII-4
Al
N
O
C-B17
C-B13
XII-5
Al
N
O
C-B25
C-B13
XII-6
Al
N
O
C-B52
C-B13
XII-7
Al
N
O
C-B54
C-B13
XII-8
Al
N
O
C-B55
C-B13
XII-9
Al
N
O
C-B63
C-B13
XII-10
Al
N
O
C-B68
C-B13
XII-11
Al
N
O
C-B69
C-B13
XII-12
Al
N
O
C-B70
C-B13
XII-13
Al
N
O
C-B71
C-B13
XII-14
Al
N
O
C-B89
C-B13
XII-15
Al
N
O
C-B90
C-B13
XII-16
Al
N
O
C-B91
C-B13
XII-17
Al
N
S
C-B1
C-B1
XII-18
Al
N
S
C-B13
C-B13
XII-19
Al
N
S
C-B16
C-B13
XII-20
Al
N
S
C-B17
C-B13
XII-21
Al
N
S
C-B25
C-B13
XII-22
Al
N
S
C-B52
C-B13
XII-23
Al
N
S
C-B54
C-B13
XII-24
Al
N
S
C-B55
C-B13
XII-25
Al
N
S
C-B63
C-B13
XII-26
Al
N
S
C-B68
C-B13
XII-27
Al
N
S
C-B69
C-B13
XII-28
Al
N
S
C-B70
C-B13
XII-29
Al
N
S
C-B71
C-B13
XII-30
Al
N
S
C-B89
C-B13
XII-31
Al
N
S
C-B90
C-B13
XII-32
Al
N
S
C-B91
C-B13
XII-33
Al
N
Se
C-B1
C-B1
XII-34
Al
N
Se
C-B13
C-B13
XII-35
Al
N
Se
C-B16
C-B13
XII-36
Al
N
Se
C-B17
C-B13
XII-37
Al
N
Se
C-B25
C-B13
XII-38
Al
N
Se
C-B52
C-B13
XII-39
Al
N
Se
C-B54
C-B13
XII-40
Al
N
Se
C-B55
C-B13
XII-41
Al
N
Se
C-B63
C-B13
XII-42
Al
N
Se
C-B68
C-B13
XII-43
Al
N
Se
C-B69
C-B13
XII-44
Al
N
Se
C-B70
C-B13
XII-45
Al
N
Se
C-B71
C-B13
XII-46
Al
N
Se
C-B89
C-B13
XII-47
Al
N
Se
C-B90
C-B13
XII-48
Al
N
Se
C-B91
C-B13
XII-49
Al
N
NMe
C-B1
C-B1
XII-50
Al
N
NMe
C-B13
C-B13
XII-51
Al
N
NMe
C-B16
C-B13
XII-52
Al
N
NMe
C-B17
C-B13
XII-53
Al
N
NMe
C-B25
C-B13
XII-54
Al
N
NMe
C-B52
C-B13
XII-55
Al
N
NMe
C-B54
C-B13
XII-56
Al
N
NMe
C-B55
C-B13
XII-57
Al
N
NMe
C-B63
C-B13
XII-58
Al
N
NMe
C-B68
C-B13
XII-59
Al
N
NMe
C-B69
C-B13
XII-60
Al
N
NMe
C-B70
C-B13
XII-61
Al
N
NMe
C-B71
C-B13
XII-62
Al
N
NMe
C-B89
C-B13
XII-63
Al
N
NMe
C-B90
C-B13
XII-64
Al
N
NMe
C-B91
C-B13
XII-65
Al
CH
O
C-B1
C-B1
XII-66
Al
CH
O
C-B13
C-B13
XII-67
Al
CH
O
C-B16
C-B13
XII-68
Al
CH
O
C-B17
C-B13
XII-69
Al
CH
O
C-B25
C-B13
XII-70
Al
CH
O
C-B52
C-B13
XII-71
Al
CH
O
C-B54
C-B13
XII-72
Al
CH
O
C-B55
C-B13
XII-73
Al
CH
O
C-B63
C-B13
XII-74
Al
CH
O
C-B68
C-B13
XII-75
Al
CH
O
C-B69
C-B13
XII-76
Al
CH
O
C-B70
C-B13
XII-77
Al
CH
O
C-B71
C-B13
XII-78
Al
CH
O
C-B89
C-B13
XII-79
Al
CH
O
C-B90
C-B13
XII-80
Al
CH
O
C-B91
C-B13
XII-81
Al
CH
S
C-B1
C-B1
XII-82
Al
CH
S
C-B13
C-B13
XII-83
Al
CH
S
C-B16
C-B13
XII-84
Al
CH
S
C-B17
C-B13
XII-85
Al
CH
S
C-B25
C-B13
XII-86
Al
CH
S
C-B52
C-B13
XII-87
Al
CH
S
C-B54
C-B13
XII-88
Al
CH
S
C-B55
C-B13
XII-89
Al
CH
S
C-B63
C-B13
XII-90
Al
CH
S
C-B68
C-B13
XII-91
Al
CH
S
C-B69
C-B13
XII-92
Al
CH
S
C-B70
C-B13
XII-93
Al
CH
S
C-B71
C-B13
XII-94
Al
CH
S
C-B89
C-B13
XII-95
Al
CH
S
C-B90
C-B13
XII-96
Al
CH
S
C-B91
C-B13
XII-97
Al
CH
Se
C-B1
C-B1
XII-98
Al
CH
Se
C-B13
C-B13
XII-99
Al
CH
Se
C-B16
C-B13
XII-100
Al
CH
Se
C-B17
C-B13
XII-101
Al
CH
Se
C-B25
C-B13
XII-102
Al
CH
Se
C-B52
C-B13
XII-103
Al
CH
Se
C-B54
C-B13
XII-104
Al
CH
Se
C-B55
C-B13
XII-105
Al
CH
Se
C-B63
C-B13
XII-106
Al
CH
Se
C-B68
C-B13
XII-107
Al
CH
Se
C-B69
C-B13
XII-108
Al
CH
Se
C-B70
C-B13
XII-109
Al
CH
Se
C-B71
C-B13
XII-110
Al
CH
Se
C-B89
C-B13
XII-111
Al
CH
Se
C-B90
C-B13
XII-112
Al
CH
Se
C-B91
C-B13
XII-113
Al
CH
NMe
C-B1
C-B1
XII-114
Al
CH
NMe
C-B13
C-B13
XII-115
Al
CH
NMe
C-B16
C-B13
XII-116
Al
CH
NMe
C-B17
C-B13
XII-117
Al
CH
NMe
C-B25
C-B13
XII-118
Al
CH
NMe
C-B52
C-B13
XII-119
Al
CH
NMe
C-B54
C-B13
XII-120
Al
CH
NMe
C-B55
C-B13
XII-121
Al
CH
NMe
C-B63
C-B13
XII-122
Al
CH
NMe
C-B68
C-B13
XII-123
Al
CH
NMe
C-B69
C-B13
XII-124
Al
CH
NMe
C-B70
C-B13
XII-125
Al
CH
NMe
C-B71
C-B13
XII-126
Al
CH
NMe
C-B89
C-B13
XII-127
Al
CH
NMe
C-B90
C-B13
XII-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound XIII-1 to Compound XIII-128 have the structure of Formula XIII:
in Formula XIII, both of X are the same, both of Y are the same, both of W are the same, Z1, Z2, Z5 and Z6 are the same, Z3 and Z4 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z1 = Z2 =
Z1 = Z2 =
No.
X
Y
W
Z3 = Z4
Z5 = Z6
No.
X
Y
W
Z3 = Z4
Z5 = Z6
XIII-1
Al
N
O
C-B1
C-B1
XIII-2
Al
N
O
C-B13
C-B13
XIII-3
Al
N
O
C-B16
C-B13
XIII-4
Al
N
O
C-B17
C-B13
XIII-5
Al
N
O
C-B25
C-B13
XIII-6
Al
N
O
C-B52
C-B13
XIII-7
Al
N
O
C-B54
C-B13
XIII-8
Al
N
O
C-B55
C-B13
XIII-9
Al
N
O
C-B63
C-B13
XIII-10
Al
N
O
C-B68
C-B13
XIII-11
Al
N
O
C-B69
C-B13
XIII-12
Al
N
O
C-B70
C-B13
XIII-13
Al
N
O
C-B71
C-B13
XIII-14
Al
N
O
C-B89
C-B13
XIII-15
Al
N
O
C-B90
C-B13
XIII-16
Al
N
O
C-B91
C-B13
XIII-17
Al
N
S
C-B1
C-B1
XIII-18
Al
N
S
C-B13
C-B13
XIII-19
Al
N
S
C-B16
C-B13
XIII-20
Al
N
S
C-B17
C-B13
XIII-21
Al
N
S
C-B25
C-B13
XIII-22
Al
N
S
C-B52
C-B13
XIII-23
Al
N
S
C-B54
C-B13
XIII-24
Al
N
S
C-B55
C-B13
XIII-25
Al
N
S
C-B63
C-B13
XIII-26
Al
N
S
C-B68
C-B13
XIII-27
Al
N
S
C-B69
C-B13
XIII-28
Al
N
S
C-B70
C-B13
XIII-29
Al
N
S
C-B71
C-B13
XIII-30
Al
N
S
C-B89
C-B13
XIII-31
Al
N
S
C-B90
C-B13
XIII-32
Al
N
S
C-B91
C-B13
XIII-33
Al
N
Se
C-B1
C-B1
XIII-34
Al
N
Se
C-B13
C-B13
XIII-35
Al
N
Se
C-B16
C-B13
XIII-36
Al
N
Se
C-B17
C-B13
XIII-37
Al
N
Se
C-B25
C-B13
XIII-38
Al
N
Se
C-B52
C-B13
XIII-39
Al
N
Se
C-B54
C-B13
XIII-40
Al
N
Se
C-B55
C-B13
XIII-41
Al
N
Se
C-B63
C-B13
XIII-42
Al
N
Se
C-B68
C-B13
XIII-43
Al
N
Se
C-B69
C-B13
XIII-44
Al
N
Se
C-B70
C-B13
XIII-45
Al
N
Se
C-B71
C-B13
XIII-46
Al
N
Se
C-B89
C-B13
XIII-47
Al
N
Se
C-B90
C-B13
XIII-48
Al
N
Se
C-B91
C-B13
XIII-49
Al
N
NMe
C-B1
C-B1
XIII-50
Al
N
NMe
C-B13
C-B13
XIII-51
Al
N
NMe
C-B16
C-B13
XIII-52
Al
N
NMe
C-B17
C-B13
XIII-53
Al
N
NMe
C-B25
C-B13
XIII-54
Al
N
NMe
C-B52
C-B13
XIII-55
Al
N
NMe
C-B54
C-B13
XIII-56
Al
N
NMe
C-B55
C-B13
XIII-57
Al
N
NMe
C-B63
C-B13
XIII-58
Al
N
NMe
C-B68
C-B13
XIII-59
Al
N
NMe
C-B69
C-B13
XIII-60
Al
N
NMe
C-B70
C-B13
XIII-61
Al
N
NMe
C-B71
C-B13
XIII-62
Al
N
NMe
C-B89
C-B13
XIII-63
Al
N
NMe
C-B90
C-B13
XIII-64
Al
N
NMe
C-B91
C-B13
XIII-65
Al
CH
O
C-B1
C-B1
XIII-66
Al
CH
O
C-B13
C-B13
XIII-67
Al
CH
O
C-B16
C-B13
XIII-68
Al
CH
O
C-B17
C-B13
XIII-69
Al
CH
O
C-B25
C-B13
XIII-70
Al
CH
O
C-B52
C-B13
XIII-71
Al
CH
O
C-B54
C-B13
XIII-72
Al
CH
O
C-B55
C-B13
XIII-73
Al
CH
O
C-B63
C-B13
XIII-74
Al
CH
O
C-B68
C-B13
XIII-75
Al
CH
O
C-B69
C-B13
XIII-76
Al
CH
O
C-B70
C-B13
XIII-77
Al
CH
O
C-B71
C-B13
XIII-78
Al
CH
O
C-B89
C-B13
XIII-79
Al
CH
O
C-B90
C-B13
XIII-80
Al
CH
O
C-B91
C-B13
XIII-81
Al
CH
S
C-B1
C-B1
XIII-82
Al
CH
S
C-B13
C-B13
XIII-83
Al
CH
S
C-B16
C-B13
XIII-84
Al
CH
S
C-B17
C-B13
XIII-85
Al
CH
S
C-B25
C-B13
XIII-86
Al
CH
S
C-B52
C-B13
XIII-87
Al
CH
S
C-B54
C-B13
XIII-88
Al
CH
S
C-B55
C-B13
XIII-89
Al
CH
S
C-B63
C-B13
XIII-90
Al
CH
S
C-B68
C-B13
XIII-91
Al
CH
S
C-B69
C-B13
XIII-92
Al
CH
S
C-B70
C-B13
XIII-93
Al
CH
S
C-B71
C-B13
XIII-94
Al
CH
S
C-B89
C-B13
XIII-95
Al
CH
S
C-B90
C-B13
XIII-96
Al
CH
S
C-B91
C-B13
XIII-97
Al
CH
Se
C-B1
C-B1
XIII-98
Al
CH
Se
C-B13
C-B13
XIII-99
Al
CH
Se
C-B16
C-B13
XIII-100
Al
CH
Se
C-B17
C-B13
XIII-101
Al
CH
Se
C-B25
C-B13
XIII-102
Al
CH
Se
C-B52
C-B13
XIII-103
Al
CH
Se
C-B54
C-B13
XIII-104
Al
CH
Se
C-B55
C-B13
XIII-105
Al
CH
Se
C-B63
C-B13
XIII-106
Al
CH
Se
C-B68
C-B13
XIII-107
Al
CH
Se
C-B69
C-B13
XIII-108
Al
CH
Se
C-B70
C-B13
XIII-109
Al
CH
Se
C-B71
C-B13
XIII-110
Al
CH
Se
C-B89
C-B13
XIII-111
Al
CH
Se
C-B90
C-B13
XIII-112
Al
CH
Se
C-B91
C-B13
XIII-113
Al
CH
NMe
C-B1
C-B1
XIII-114
Al
CH
NMe
C-B13
C-B13
XIII-115
Al
CH
NMe
C-B16
C-B13
XIII-116
Al
CH
NMe
C-B17
C-B13
XIII-117
Al
CH
NMe
C-B25
C-B13
XIII-118
Al
CH
NMe
C-B52
C-B13
XIII-119
Al
CH
NMe
C-B54
C-B13
XIII-120
Al
CH
NMe
C-B55
C-B13
XIII-121
Al
CH
NMe
C-B63
C-B13
XIII-122
Al
CH
NMe
C-B68
C-B13
XIII-123
Al
CH
NMe
C-B69
C-B13
XIII-124
Al
CH
NMe
C-B70
C-B13
XIII-125
Al
CH
NMe
C-B71
C-B13
XIII-126
Al
CH
NMe
C-B89
C-B13
XIII-127
Al
CH
NMe
C-B90
C-B13
XIII-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound XIV-1 to Compound XIV-128 have the structure of Formula XIV:
in Formula XIV, both of X are the same, both of Y are the same, both of W are the same, Z3, Z4, Z5 and Z6 are the same, Z1 and Z2 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z3 = Z4 =
Z3 = Z4 =
No.
X
Y
W
Z1 = Z2
Z5 = Z6
No.
X
Y
W
Z1 = Z2
Z5 = Z6
XIV-1
Al
N
O
C-B1
C-B1
XIV-2
Al
N
O
C-B13
C-B13
XIV-3
Al
N
O
C-B16
C-B13
XIV-4
Al
N
O
C-B17
C-B13
XIV-5
Al
N
O
C-B25
C-B13
XIV-6
Al
N
O
C-B52
C-B13
XIV-7
Al
N
O
C-B54
C-B13
XIV-8
Al
N
O
C-B55
C-B13
XIV-9
Al
N
O
C-B63
C-B13
XIV-10
Al
N
O
C-B68
C-B13
XIV-11
Al
N
O
C-B69
C-B13
XIV-12
Al
N
O
C-B70
C-B13
XIV-13
Al
N
O
C-B71
C-B13
XIV-14
Al
N
O
C-B89
C-B13
XIV-15
Al
N
O
C-B90
C-B13
XIV-16
Al
N
O
C-B91
C-B13
XIV-17
Al
N
S
C-B1
C-B1
XIV-18
Al
N
S
C-B13
C-B13
XIV-19
Al
N
S
C-B16
C-B13
XIV-20
Al
N
S
C-B17
C-B13
XIV-21
Al
N
S
C-B25
C-B13
XIV-22
Al
N
S
C-B52
C-B13
XIV-23
Al
N
S
C-B54
C-B13
XIV-24
Al
N
S
C-B55
C-B13
XIV-25
Al
N
S
C-B63
C-B13
XIV-26
Al
N
S
C-B68
C-B13
XIV-27
Al
N
S
C-B69
C-B13
XIV-28
Al
N
S
C-B70
C-B13
XIV-29
Al
N
S
C-B71
C-B13
XIV-3O
Al
N
S
C-B89
C-B13
XIV-31
Al
N
S
C-B90
C-B13
XIV-32
Al
N
S
C-B91
C-B13
XIV-33
Al
N
Se
C-B1
C-B1
XIV-34
Al
N
Se
C-B13
C-B13
XIV-35
Al
N
Se
C-B16
C-B13
XIV-36
Al
N
Se
C-B17
C-B13
XIV-37
Al
N
Se
C-B25
C-B13
XIV-38
Al
N
Se
C-B52
C-B13
XIV-39
Al
N
Se
C-B54
C-B13
XIV-40
Al
N
Se
C-B55
C-B13
XIV-41
Al
N
Se
C-B63
C-B13
XIV-42
Al
N
Se
C-B68
C-B13
XIV-43
Al
N
Se
C-B69
C-B13
XIV-44
Al
N
Se
C-B70
C-B13
XIV-45
Al
N
Se
C-B71
C-B13
XIV-46
Al
N
Se
C-B89
C-B13
XIV-47
Al
N
Se
C-B90
C-B13
XIV-48
Al
N
Se
C-B91
C-B13
XIV-49
Al
N
NMe
C-B1
C-B1
XIV-50
Al
N
NMe
C-B13
C-B13
XIV-51
Al
N
NMe
C-B16
C-B13
XIV-52
Al
N
NMe
C-B17
C-B13
XIV-53
Al
N
NMe
C-B25
C-B13
XIV-54
Al
N
NMe
C-B52
C-B13
XIV-55
Al
N
NMe
C-B54
C-B13
XIV-56
Al
N
NMe
C-B55
C-B13
XIV-57
Al
N
NMe
C-B63
C-B13
XIV-58
Al
N
NMe
C-B68
C-B13
XIV-59
Al
N
NMe
C-B69
C-B13
XIV-60
Al
N
NMe
C-B70
C-B13
XIV-61
Al
N
NMe
C-B71
C-B13
XIV-62
Al
N
NMe
C-B89
C-B13
XIV-63
Al
N
NMe
C-B90
C-B13
XIV-64
Al
N
NMe
C-B91
C-B13
XIV-65
Al
CH
O
C-B1
C-B1
XIV-66
Al
CH
O
C-B13
C-B13
XIV-67
Al
CH
O
C-B16
C-B13
XIV-68
Al
CH
O
C-B17
C-B13
XIV-69
Al
CH
O
C-B25
C-B13
XIV-70
Al
CH
O
C-B52
C-B13
XIV-71
Al
CH
O
C-B54
C-B13
XIV-72
Al
CH
O
C-B55
C-B13
XIV-73
Al
CH
O
C-B63
C-B13
XIV-74
Al
CH
O
C-B68
C-B13
XIV-75
Al
CH
O
C-B69
C-B13
XIV-76
Al
CH
O
C-B70
C-B13
XIV-77
Al
CH
O
C-B71
C-B13
XIV-78
Al
CH
O
C-B89
C-B13
XIV-79
Al
CH
O
C-B90
C-B13
XIV-80
Al
CH
O
C-B91
C-B13
XIV-81
Al
CH
S
C-B1
C-B1
XIV-82
Al
CH
S
C-B13
C-B13
XIV-83
Al
CH
S
C-B16
C-B13
XIV-84
Al
CH
S
C-B17
C-B13
XIV-85
Al
CH
S
C-B25
C-B13
XIV-86
Al
CH
S
C-B52
C-B13
XIV-87
Al
CH
S
C-B54
C-B13
XIV-88
Al
CH
S
C-B55
C-B13
XIV-89
Al
CH
S
C-B63
C-B13
XIV-90
Al
CH
S
C-B68
C-B13
XIV-91
Al
CH
S
C-B69
C-B13
XIV-92
Al
CH
S
C-B70
C-B13
XIV-93
Al
CH
S
C-B71
C-B13
XIV-94
Al
CH
S
C-B89
C-B13
XIV-95
Al
CH
S
C-B90
C-B13
XIV-96
Al
CH
S
C-B91
C-B13
XIV-97
Al
CH
Se
C-B1
C-B1
XIV-98
Al
CH
Se
C-B13
C-B13
XIV-99
Al
CH
Se
C-B16
C-B13
XIV-100
Al
CH
Se
C-B17
C-B13
XIV-101
Al
CH
Se
C-B25
C-B13
XIV-102
Al
CH
Se
C-B52
C-B13
XIV-103
Al
CH
Se
C-B54
C-B13
XIV-104
Al
CH
Se
C-B55
C-B13
XIV-105
Al
CH
Se
C-B63
C-B13
XIV-106
Al
CH
Se
C-B68
C-B13
XIV-107
Al
CH
Se
C-B69
C-B13
XIV-108
Al
CH
Se
C-B70
C-B13
XIV-109
Al
CH
Se
C-B71
C-B13
XIV-110
Al
CH
Se
C-B89
C-B13
XIV-111
Al
CH
Se
C-B90
C-B13
XIV-112
Al
CH
Se
C-B91
C-B13
XIV-113
Al
CH
NMe
C-B1
C-B1
XIV-114
Al
CH
NMe
C-B13
C-B13
XIV-115
Al
CH
NMe
C-B16
C-B13
XIV-116
Al
CH
NMe
C-B17
C-B13
XIV-117
Al
CH
NMe
C-B25
C-B13
XIV-118
Al
CH
NMe
C-B52
C-B13
XIV-119
Al
CH
NMe
C-B54
C-B13
XIV-120
Al
CH
NMe
C-B55
C-B13
XIV-121
Al
CH
NMe
C-B63
C-B13
XIV-122
Al
CH
NMe
C-B68
C-B13
XIV-123
Al
CH
NMe
C-B69
C-B13
XIV-124
Al
CH
NMe
C-B70
C-B13
XIV-125
Al
CH
NMe
C-B71
C-B13
XIV-126
Al
CH
NMe
C-B89
C-B13
XIV-127
Al
CH
NMe
C-B90
C-B13
XIV-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound XV-1 to Compound XV-128 have the structure of Formula XV:
in Formula XV, both of X are the same, both of Y are the same, both of W are the same, Z3, Z4, Z5 and Z6 are the same, Z1 and Z2 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z3 = Z4 =
Z3 = Z4 =
No.
X
Y
W
Z1 = Z2
Z5 = Z6
No.
X
Y
W
Z1 = Z2
Z5 = Z6
XV-1
Al
N
O
C-B1
C-B1
XV-2
Al
N
O
C-B13
C-B13
XV-3
Al
N
O
C-B16
C-B13
XV-4
Al
N
O
C-B17
C-B13
XV-5
Al
N
O
C-B25
C-B13
XV-6
Al
N
O
C-B52
C-B13
XV-7
Al
N
O
C-B54
C-B13
XV-8
Al
N
O
C-B55
C-B13
XV-9
Al
N
O
C-B63
C-B13
XV-10
Al
N
O
C-B68
C-B13
XV-11
Al
N
O
C-B69
C-B13
XV-12
Al
N
O
C-B70
C-B13
XV-13
Al
N
O
C-B71
C-B13
XV-14
Al
N
O
C-B89
C-B13
XV-15
Al
N
O
C-B90
C-B13
XV-16
Al
N
O
C-B91
C-B13
XV-17
Al
N
S
C-B1
C-B1
XV-18
Al
N
S
C-B13
C-B13
XV-19
Al
N
S
C-B16
C-B13
XV-20
Al
N
S
C-B17
C-B13
XV-21
Al
N
S
C-B25
C-B13
XV-22
Al
N
S
C-B52
C-B13
XV-23
Al
N
S
C-B54
C-B13
XV-24
Al
N
S
C-B55
C-B13
XV-25
Al
N
S
C-B63
C-B13
XV-26
Al
N
S
C-B68
C-B13
XV-27
Al
N
S
C-B69
C-B13
XV-28
Al
N
S
C-B70
C-B13
XV-29
Al
N
S
C-B71
C-B13
XV-30
Al
N
S
C-B89
C-B13
XV-31
Al
N
S
C-B90
C-B13
XV-32
Al
N
S
C-B91
C-B13
XV-33
Al
N
Se
C-B1
C-B1
XV-34
Al
N
Se
C-B13
C-B13
XV-35
Al
N
Se
C-B16
C-B13
XV-36
Al
N
Se
C-B17
C-B13
XV-37
Al
N
Se
C-B25
C-B13
XV-38
Al
N
Se
C-B52
C-B13
XV-39
Al
N
Se
C-B54
C-B13
XV-40
Al
N
Se
C-B55
C-B13
XV-41
Al
N
Se
C-B63
C-B13
XV-42
Al
N
Se
C-B68
C-B13
XV-43
Al
N
Se
C-B69
C-B13
XV-44
Al
N
Se
C-B70
C-B13
XV-45
Al
N
Se
C-B71
C-B13
XV-46
Al
N
Se
C-B89
C-B13
XV-47
Al
N
Se
C-B90
C-B13
XV-48
Al
N
Se
C-B91
C-B13
XV-49
Al
N
NMe
C-B1
C-B1
XV-50
Al
N
NMe
C-B13
C-B13
XV-51
Al
N
NMe
C-B16
C-B13
XV-52
Al
N
NMe
C-B17
C-B13
XV-53
Al
N
NMe
C-B25
C-B13
XV-54
Al
N
NMe
C-B52
C-B13
XV-55
Al
N
NMe
C-B54
C-B13
XV-56
Al
N
NMe
C-B55
C-B13
XV-57
Al
N
NMe
C-B63
C-B13
XV-58
Al
N
NMe
C-B68
C-B13
XV-59
Al
N
NMe
C-B69
C-B13
XV-60
Al
N
NMe
C-B70
C-B13
XV-61
Al
N
NMe
C-B71
C-B13
XV-62
Al
N
NMe
C-B89
C-B13
XV-63
Al
N
NMe
C-B90
C-B13
XV-64
Al
N
NMe
C-B91
C-B13
XV-65
Al
CH
O
C-B1
C-B1
XV-66
Al
CH
O
C-B13
C-B13
XV-67
Al
CH
O
C-B16
C-B13
XV-68
Al
CH
O
C-B17
C-B13
XV-69
Al
CH
O
C-B25
C-B13
XV-70
Al
CH
O
C-B52
C-B13
XV-71
Al
CH
O
C-B54
C-B13
XV-72
Al
CH
O
C-B55
C-B13
XV-73
Al
CH
O
C-B63
C-B13
XV-74
Al
CH
O
C-B68
C-B13
XV-75
Al
CH
O
C-B69
C-B13
XV-76
Al
CH
O
C-B70
C-B13
XV-77
Al
CH
O
C-B71
C-B13
XV-78
Al
CH
O
C-B89
C-B13
XV-79
Al
CH
O
C-B90
C-B13
XV-80
Al
CH
O
C-B91
C-B13
XV-81
Al
CH
S
C-B1
C-B1
XV-82
Al
CH
S
C-B13
C-B13
XV-83
Al
CH
S
C-B16
C-B13
XV-84
Al
CH
S
C-B17
C-B13
XV-85
Al
CH
S
C-B25
C-B13
XV-86
Al
CH
S
C-B52
C-B13
XV-87
Al
CH
S
C-B54
C-B13
XV-88
Al
CH
S
C-B55
C-B13
XV-89
Al
CH
S
C-B63
C-B13
XV-90
Al
CH
S
C-B68
C-B13
XV-91
Al
CH
S
C-B69
C-B13
XV-92
Al
CH
S
C-B70
C-B13
XV-93
Al
CH
S
C-B71
C-B13
XV-94
Al
CH
S
C-B89
C-B13
XV-95
Al
CH
S
C-B90
C-B13
XV-96
Al
CH
S
C-B91
C-B13
XV-97
Al
CH
Se
C-B1
C-B1
XV-98
Al
CH
Se
C-B13
C-B13
XV-99
Al
CH
Se
C-B16
C-B13
XV-100
Al
CH
Se
C-B17
C-B13
XV-101
Al
CH
Se
C-B25
C-B13
XV-102
Al
CH
Se
C-B52
C-B13
XV-103
Al
CH
Se
C-B54
C-B13
XV-104
Al
CH
Se
C-B55
C-B13
XV-105
Al
CH
Se
C-B63
C-B13
XV-106
Al
CH
Se
C-B68
C-B13
XV-107
Al
CH
Se
C-B69
C-B13
XV-108
Al
CH
Se
C-B70
C-B13
XV-109
Al
CH
Se
C-B71
C-B13
XV-110
Al
CH
Se
C-B89
C-B13
XV-111
Al
CH
Se
C-B90
C-B13
XV-112
Al
CH
Se
C-B91
C-B13
XV-113
Al
CH
NMe
C-B1
C-B1
XV-114
Al
CH
NMe
C-B13
C-B13
XV-115
Al
CH
NMe
C-B16
C-B13
XV-116
Al
CH
NMe
C-B17
C-B13
XV-117
Al
CH
NMe
C-B25
C-B13
XV-118
Al
CH
NMe
C-B52
C-B13
XV-119
Al
CH
NMe
C-B54
C-B13
XV-120
Al
CH
NMe
C-B55
C-B13
XV-121
Al
CH
NMe
C-B63
C-B13
XV-122
Al
CH
NMe
C-B68
C-B13
XV-123
Al
CH
NMe
C-B69
C-B13
XV-124
Al
CH
NMe
C-B70
C-B13
XV-125
Al
CH
NMe
C-B71
C-B13
XV-126
Al
CH
NMe
C-B89
C-B13
XV-127
Al
CH
NMe
C-B90
C-B13
XV-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound XVI-1 to Compound XVI-128 have the structure of Formula XVI:
in Formula XVI, both of X are the same, both of Y are the same, both of W are the same, Z3, Z4, Z5 and Z6 are the same, Z1 and Z2 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z3 = Z4 =
Z3 = Z4 =
No.
X
Y
W
Z1 = Z2
Z5 = Z6
No.
X
Y
W
Z1 = Z2
Z5 = Z6
XVI-1
Al
N
O
C-B1
C-B1
XVI-2
Al
N
O
C-B13
C-B13
XVI-3
Al
N
O
C-B16
C-B13
XVI-4
Al
N
O
C-B17
C-B13
XVI-5
Al
N
O
C-B25
C-B13
XVI-6
Al
N
O
C-B52
C-B13
XVI-7
Al
N
O
C-B54
C-B13
XVI-8
Al
N
O
C-B55
C-B13
XVI-9
Al
N
O
C-B63
C-B13
XVI-10
Al
N
O
C-B68
C-B13
XVI-11
Al
N
O
C-B69
C-B13
XVI-12
Al
N
O
C-B70
C-B13
XVI-13
Al
N
O
C-B71
C-B13
XVI-14
Al
N
O
C-B89
C-B13
XVI-15
Al
N
O
C-B90
C-B13
XVI-16
Al
N
O
C-B91
C-B13
XVI-17
Al
N
S
C-B1
C-B1
XVI-18
Al
N
S
C-B13
C-B13
XVI-19
Al
N
S
C-B16
C-B13
XVI-20
Al
N
S
C-B17
C-B13
XVI-21
Al
N
S
C-B25
C-B13
XVI-22
Al
N
S
C-B52
C-B13
XVI-23
Al
N
S
C-B54
C-B13
XVI-24
Al
N
S
C-B55
C-B13
XVI-25
Al
N
S
C-B63
C-B13
XVI-26
Al
N
S
C-B68
C-B13
XVI-27
Al
N
S
C-B69
C-B13
XVI-28
Al
N
S
C-B70
C-B13
XVI-29
Al
N
S
C-B71
C-B13
XVI-30
Al
N
S
C-B89
C-B13
XVI-31
Al
N
S
C-B90
C-B13
XVI-32
Al
N
S
C-B91
C-B13
XVI-33
Al
N
Se
C-B1
C-B1
XVI-34
Al
N
Se
C-B13
C-B13
XVI-35
Al
N
Se
C-B16
C-B13
XVI-36
Al
N
Se
C-B17
C-B13
XVI-37
Al
N
Se
C-B25
C-B13
XVI-38
Al
N
Se
C-B52
C-B13
XVI-39
Al
N
Se
C-B54
C-B13
XVI-40
Al
N
Se
C-B55
C-B13
XVI-41
Al
N
Se
C-B63
C-B13
XVI-42
Al
N
Se
C-B68
C-B13
XVI-43
Al
N
Se
C-B69
C-B13
XVI-44
Al
N
Se
C-B70
C-B13
XVI-45
Al
N
Se
C-B71
C-B13
XVI-46
Al
N
Se
C-B89
C-B13
XVI-47
Al
N
Se
C-B90
C-B13
XVI-48
Al
N
Se
C-B91
C-B13
XVI-49
Al
N
NMe
C-B1
C-B1
XVI-50
Al
N
NMe
C-B13
C-B13
XVI-51
Al
N
NMe
C-B16
C-B13
XVI-52
Al
N
NMe
C-B17
C-B13
XVI-53
Al
N
NMe
C-B25
C-B13
XVI-54
Al
N
NMe
C-B52
C-B13
XVI-55
Al
N
NMe
C-B54
C-B13
XVI-56
Al
N
NMe
C-B55
C-B13
XVI-57
Al
N
NMe
C-B63
C-B13
XVI-58
Al
N
NMe
C-B68
C-B13
XVI-59
Al
N
NMe
C-B69
C-B13
XVI-60
Al
N
NMe
C-B70
C-B13
XVI-61
Al
N
NMe
C-B71
C-B13
XVI-62
Al
N
NMe
C-B89
C-B13
XVI-63
Al
N
NMe
C-B90
C-B13
XVI-64
Al
N
NMe
C-B91
C-B13
XVI-65
Al
CH
O
C-B1
C-B1
XVI-66
Al
CH
O
C-B13
C-B13
XVI-67
Al
CH
O
C-B16
C-B13
XVI-68
Al
CH
O
C-B17
C-B13
XVI-69
Al
CH
O
C-B25
C-B13
XVI-70
Al
CH
O
C-B52
C-B13
XVI-71
Al
CH
O
C-B54
C-B13
XVI-72
Al
CH
O
C-B55
C-B13
XVI-73
Al
CH
O
C-B63
C-B13
XVI-74
Al
CH
O
C-B68
C-B13
XVI-75
Al
CH
O
C-B69
C-B13
XVI-76
Al
CH
O
C-B70
C-B13
XVI-77
Al
CH
O
C-B71
C-B13
XVI-78
Al
CH
O
C-B89
C-B13
XVI-79
Al
CH
O
C-B90
C-B13
XVI-80
Al
CH
O
C-B91
C-B13
XVI-81
Al
CH
S
C-B1
C-B1
XVI-82
Al
CH
S
C-B13
C-B13
XVI-83
Al
CH
S
C-B16
C-B13
XVI-84
Al
CH
S
C-B17
C-B13
XVI-85
Al
CH
S
C-B25
C-B13
XVI-86
Al
CH
S
C-B52
C-B13
XVI-87
Al
CH
S
C-B54
C-B13
XVI-88
Al
CH
S
C-B55
C-B13
XVI-89
Al
CH
S
C-B63
C-B13
XVI-90
Al
CH
S
C-B68
C-B13
XVI-91
Al
CH
S
C-B69
C-B13
XVI-92
Al
CH
S
C-B70
C-B13
XVI-93
Al
CH
S
C-B71
C-B13
XVI-94
Al
CH
S
C-B89
C-B13
XVI-95
Al
CH
S
C-B90
C-B13
XVI-96
Al
CH
S
C-B91
C-B13
XVI-97
Al
CH
Se
C-B1
C-B1
XVI-98
Al
CH
Se
C-B13
C-B13
XVI-99
Al
CH
Se
C-B16
C-B13
XVI-100
Al
CH
Se
C-B17
C-B13
XVI-101
Al
CH
Se
C-B25
C-B13
XVI-102
Al
CH
Se
C-B52
C-B13
XVI-103
Al
CH
Se
C-B54
C-B13
XVI-104
Al
CH
Se
C-B55
C-B13
XVI-105
Al
CH
Se
C-B63
C-B13
XVI-106
Al
CH
Se
C-B68
C-B13
XVI-107
Al
CH
Se
C-B69
C-B13
XVI-108
Al
CH
Se
C-B70
C-B13
XVI-109
Al
CH
Se
C-B71
C-B13
XVI-110
Al
CH
Se
C-B89
C-B13
XVI-111
Al
CH
Se
C-B90
C-B13
XVI-112
Al
CH
Se
C-B91
C-B13
XVI-113
Al
CH
NMe
C-B1
C-B1
XVI-114
Al
CH
NMe
C-B13
C-B13
XVI-115
Al
CH
NMe
C-B16
C-B13
XVI-116
Al
CH
NMe
C-B17
C-B13
XVI-117
Al
CH
NMe
C-B25
C-B13
XVI-118
Al
CH
NMe
C-B52
C-B13
XVI-119
Al
CH
NMe
C-B54
C-B13
XVI-120
Al
CH
NMe
C-B55
C-B13
XVI-121
Al
CH
NMe
C-B63
C-B13
XVI-122
Al
CH
NMe
C-B68
C-B13
XVI-123
Al
CH
NMe
C-B69
C-B13
XVI-124
Al
CH
NMe
C-B70
C-B13
XVI-125
Al
CH
NMe
C-B71
C-B13
XVI-126
Al
CH
NMe
C-B89
C-B13
XVI-127
Al
CH
NMe
C-B90
C-B13
XVI-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound XVII-1 to Compound XVII-128 have the structure of Formula XVII:
in Formula XVII, both of X are the same, both of Y are the same, both of W are the same, Z3, Z4, Z5 and Z6 are the same, Z1 and Z2 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z3 = Z4 =
Z3 = Z4 =
No.
X
Y
W
Z1 = Z2
Z5 = Z6
No.
X
Y
W
Z1 = Z2
Z5 = Z6
XVII-1
Al
N
O
C-B1
C-B1
XVII-2
Al
N
O
C-B13
C-B13
XVII-3
Al
N
O
C-B16
C-B13
XVII-4
Al
N
O
C-B17
C-B13
XVII-5
Al
N
O
C-B25
C-B13
XVII-6
Al
N
O
C-B52
C-B13
XVII-7
Al
N
O
C-B54
C-B13
XVII-8
Al
N
O
C-B55
C-B13
XVII-9
Al
N
O
C-B63
C-B13
XVII-10
Al
N
O
C-B68
C-B13
XVII-11
Al
N
O
C-B69
C-B13
XVII-12
Al
N
O
C-B70
C-B13
XVII-13
Al
N
O
C-B71
C-B13
XVII-14
Al
N
O
C-B89
C-B13
XVII-15
Al
N
O
C-B90
C-B13
XVII-16
Al
N
O
C-B91
C-B13
XVII-17
Al
N
S
C-B1
C-B1
XVII-18
Al
N
S
C-B13
C-B13
XVII-19
Al
N
S
C-B16
C-B13
XVII-20
Al
N
S
C-B17
C-B13
XVII-21
Al
N
S
C-B25
C-B13
XVII-22
Al
N
S
C-B52
C-B13
XVII-23
Al
N
S
C-B54
C-B13
XVII-24
Al
N
S
C-B55
C-B13
XVII-25
Al
N
S
C-B63
C-B13
XVII-26
Al
N
S
C-B68
C-B13
XVII-27
Al
N
S
C-B69
C-B13
XVII-28
Al
N
S
C-B70
C-B13
XVII-29
Al
N
S
C-B71
C-B13
XVII-30
Al
N
S
C-B89
C-B13
XVII-31
Al
N
S
C-B90
C-B13
XVII-32
Al
N
S
C-B91
C-B13
XVII-33
Al
N
Se
C-B1
C-B1
XVII-34
Al
N
Se
C-B13
C-B13
XVII-35
Al
N
Se
C-B16
C-B13
XVII-36
Al
N
Se
C-B17
C-B13
XVII-37
Al
N
Se
C-B25
C-B13
XVII-38
Al
N
Se
C-B52
C-B13
XVII-39
Al
N
Se
C-B54
C-B13
XVII-40
Al
N
Se
C-B55
C-B13
XVII-41
Al
N
Se
C-B63
C-B13
XVII-42
Al
N
Se
C-B68
C-B13
XVII-43
Al
N
Se
C-B69
C-B13
XVII-44
Al
N
Se
C-B70
C-B13
XVII-45
Al
N
Se
C-B71
C-B13
XVII-46
Al
N
Se
C-B89
C-B13
XVII-47
Al
N
Se
C-B90
C-B13
XVII-48
Al
N
Se
C-B91
C-B13
XVII-49
Al
N
NMe
C-B1
C-B1
XVII-50
Al
N
NMe
C-B13
C-B13
XVII-51
Al
N
NMe
C-B16
C-B13
XVII-52
Al
N
NMe
C-B17
C-B13
XVII-53
Al
N
NMe
C-B25
C-B13
XVII-54
Al
N
NMe
C-B52
C-B13
XVII-55
Al
N
NMe
C-B54
C-B13
XVII-56
Al
N
NMe
C-B55
C-B13
XVII-57
Al
N
NMe
C-B63
C-B13
XVII-58
Al
N
NMe
C-B68
C-B13
XVII-59
Al
N
NMe
C-B69
C-B13
XVII-60
Al
N
NMe
C-B70
C-B13
XVII-61
Al
N
NMe
C-B71
C-B13
XVII-62
Al
N
NMe
C-B89
C-B13
XVII-63
Al
N
NMe
C-B90
C-B13
XVII-64
Al
N
NMe
C-B91
C-B13
XVII-65
Al
CH
O
C-B1
C-B1
XVII-66
Al
CH
O
C-B13
C-B13
XVII-67
Al
CH
O
C-B16
C-B13
XVII-68
Al
CH
O
C-B17
C-B13
XVII-69
Al
CH
O
C-B25
C-B13
XVII-70
Al
CH
O
C-B52
C-B13
XVII-71
Al
CH
O
C-B54
C-B13
XVII-72
Al
CH
O
C-B55
C-B13
XVII-73
Al
CH
O
C-B63
C-B13
XVII-74
Al
CH
O
C-B68
C-B13
XVII-75
Al
CH
O
C-B69
C-B13
XVII-76
Al
CH
O
C-B70
C-B13
XVII-77
Al
CH
O
C-B71
C-B13
XVII-78
Al
CH
O
C-B89
C-B13
XVII-79
Al
CH
O
C-B90
C-B13
XVII-80
Al
CH
O
C-B91
C-B13
XVII-81
Al
CH
S
C-B1
C-B1
XVII-82
Al
CH
S
C-B13
C-B13
XVII-83
Al
CH
S
C-B16
C-B13
XVII-84
Al
CH
S
C-B17
C-B13
XVII-85
Al
CH
S
C-B25
C-B13
XVII-86
Al
CH
S
C-B52
C-B13
XVII-87
Al
CH
S
C-B54
C-B13
XVII-88
Al
CH
S
C-B55
C-B13
XVII-89
Al
CH
S
C-B63
C-B13
XVII-90
Al
CH
S
C-B68
C-B13
XVII-91
Al
CH
S
C-B69
C-B13
XVII-92
Al
CH
S
C-B70
C-B13
XVII-93
Al
CH
S
C-B71
C-B13
XVII-94
Al
CH
S
C-B89
C-B13
XVII-95
Al
CH
S
C-B90
C-B13
XVII-96
Al
CH
S
C-B91
C-B13
XVII-97
Al
CH
Se
C-B1
C-B1
XVII-98
Al
CH
Se
C-B13
C-B13
XVII-99
Al
CH
Se
C-B16
C-B13
XVII-100
Al
CH
Se
C-B17
C-B13
XVII-101
Al
CH
Se
C-B25
C-B13
XVII-102
Al
CH
Se
C-B52
C-B13
XVII-103
Al
CH
Se
C-B54
C-B13
XVII-104
Al
CH
Se
C-B55
C-B13
XVII-105
Al
CH
Se
C-B63
C-B13
XVII-106
Al
CH
Se
C-B68
C-B13
XVII-107
Al
CH
Se
C-B69
C-B13
XVII-108
Al
CH
Se
C-B70
C-B13
XVII-109
Al
CH
Se
C-B71
C-B13
XVII-110
Al
CH
Se
C-B89
C-B13
XVII-111
Al
CH
Se
C-B90
C-B13
XVII-112
Al
CH
Se
C-B91
C-B13
XVII-113
Al
CH
NMe
C-B1
C-B1
XVII-114
Al
CH
NMe
C-B13
C-B13
XVII-115
Al
CH
NMe
C-B16
C-B13
XVII-116
Al
CH
NMe
C-B17
C-B13
XVII-117
Al
CH
NMe
C-B25
C-B13
XVII-118
Al
CH
NMe
C-B52
C-B13
XVII-119
Al
CH
NMe
C-B54
C-B13
XVII-120
Al
CH
NMe
C-B55
C-B13
XVII-121
Al
CH
NMe
C-B63
C-B13
XVII-122
Al
CH
NMe
C-B68
C-B13
XVII-123
Al
CH
NMe
C-B69
C-B13
XVII-124
Al
CH
NMe
C-B70
C-B13
XVII-125
Al
CH
NMe
C-B71
C-B13
XVII-126
Al
CH
NMe
C-B89
C-B13
XVII-127
Al
CH
NMe
C-B90
C-B13
XVII-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound XVIII-1 to Compound XVIII-128 have the structure of Formula XVIII:
in Formula XVIII, both of X are the same, both of Y are the same, both of W are the same, Z3, Z4, Z5 and Z6 are the same, Z1 and Z2 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z3 = Z4 =
Z3 = Z4 =
No.
X
Y
W
Z1 = Z2
Z5 = Z6
No.
X
Y
W
Z1 = Z2
Z5 = Z6
XVIII-1
Al
N
O
C-B1
C-B1
XVIII-2
Al
N
O
C-B13
C-B13
XVIII-3
Al
N
O
C-B16
C-B13
XVIII-4
Al
N
O
C-B17
C-B13
XVIII-5
Al
N
O
C-B25
C-B13
XVIII-6
Al
N
O
C-B52
C-B13
XVIII-7
Al
N
O
C-B54
C-B13
XVIII-8
Al
N
O
C-B55
C-B13
XVIII-9
Al
N
O
C-B63
C-B13
XVIII-10
Al
N
O
C-B68
C-B13
XVIII-11
Al
N
O
C-B69
C-B13
XVIII-12
Al
N
O
C-B70
C-B13
XVIII-13
Al
N
O
C-B71
C-B13
XVIII-14
Al
N
O
C-B89
C-B13
XVIII-15
Al
N
O
C-B90
C-B13
XVIII-16
Al
N
O
C-B91
C-B13
XVIII-17
Al
N
S
C-B1
C-B1
XVIII-18
Al
N
S
C-B13
C-B13
XVIII-19
Al
N
S
C-B16
C-B13
XVIII-20
Al
N
S
C-B17
C-B13
XVIII-21
Al
N
S
C-B25
C-B13
XVIII-22
Al
N
S
C-B52
C-B13
XVIII-23
Al
N
S
C-B54
C-B13
XVIII-24
Al
N
S
C-B55
C-B13
XVIII-25
Al
N
S
C-B63
C-B13
XVIII-26
Al
N
S
C-B68
C-B13
XVIII-27
Al
N
S
C-B69
C-B13
XVIII-28
Al
N
S
C-B70
C-B13
XVIII-29
Al
N
S
C-B71
C-B13
XVIII-30
Al
N
S
C-B89
C-B13
XVIII-31
Al
N
S
C-B90
C-B13
XVIII-32
Al
N
S
C-B91
C-B13
XVIII-33
Al
N
Se
C-B1
C-B1
XVIII-34
Al
N
Se
C-B13
C-B13
XVIII-35
Al
N
Se
C-B16
C-B13
XVIII-36
Al
N
Se
C-B17
C-B13
XVIII-37
Al
N
Se
C-B25
C-B13
XVIII-38
Al
N
Se
C-B52
C-B13
XVIII-39
Al
N
Se
C-B54
C-B13
XVIII-40
Al
N
Se
C-B55
C-B13
XVIII-41
Al
N
Se
C-B63
C-B13
XVIII-42
Al
N
Se
C-B68
C-B13
XVIII-43
Al
N
Se
C-B69
C-B13
XVIII-44
Al
N
Se
C-B70
C-B13
XVIII-45
Al
N
Se
C-B71
C-B13
XVIII-46
Al
N
Se
C-B89
C-B13
XVIII-47
Al
N
Se
C-B90
C-B13
XVIII-48
Al
N
Se
C-B91
C-B13
XVIII-49
Al
N
NMe
C-B1
C-B1
XVIII-50
Al
N
NMe
C-B13
C-B13
XVIII-51
Al
N
NMe
C-B16
C-B13
XVIII-52
Al
N
NMe
C-B17
C-B13
XVIII-53
Al
N
NMe
C-B25
C-B13
XVIII-54
Al
N
NMe
C-B52
C-B13
XVIII-55
Al
N
NMe
C-B54
C-B13
XVIII-56
Al
N
NMe
C-B55
C-B13
XVIII-57
Al
N
NMe
C-B63
C-B13
XVIII-58
Al
N
NMe
C-B68
C-B13
XVIII-59
Al
N
NMe
C-B69
C-B13
XVIII-60
Al
N
NMe
C-B70
C-B13
XVIII-61
Al
N
NMe
C-B71
C-B13
XVIII-62
Al
N
NMe
C-B89
C-B13
XVIII-63
Al
N
NMe
C-B90
C-B13
XVIII-64
Al
N
NMe
C-B91
C-B13
XVIII-65
Al
CH
O
C-B1
C-B1
XVIII-66
Al
CH
O
C-B13
C-B13
XVIII-67
Al
CH
O
C-B16
C-B13
XVIII-68
Al
CH
O
C-B17
C-B13
XVIII-69
Al
CH
O
C-B25
C-B13
XVIII-70
Al
CH
O
C-B52
C-B13
XVIII-71
Al
CH
O
C-B54
C-B13
XVIII-72
Al
CH
O
C-B55
C-B13
XVIII-73
Al
CH
O
C-B63
C-B13
XVIII-74
Al
CH
O
C-B68
C-B13
XVIII-75
Al
CH
O
C-B69
C-B13
XVIII-76
Al
CH
O
C-B70
C-B13
XVIII-77
Al
CH
O
C-B71
C-B13
XVIII-78
Al
CH
O
C-B89
C-B13
XVIII-79
Al
CH
O
C-B90
C-B13
XVIII-80
Al
CH
O
C-B91
C-B13
XVIII-81
Al
CH
S
C-B1
C-B1
XVIII-82
Al
CH
S
C-B13
C-B13
XVIII-83
Al
CH
S
C-B16
C-B13
XVIII-84
Al
CH
S
C-B17
C-B13
XVIII-85
Al
CH
S
C-B25
C-B13
XVIII-86
Al
CH
S
C-B52
C-B13
XVIII-87
Al
CH
S
C-B54
C-B13
XVIII-88
Al
CH
S
C-B55
C-B13
XVIII-89
Al
CH
S
C-B63
C-B13
XVIII-90
Al
CH
S
C-B68
C-B13
XVIII-91
Al
CH
S
C-B69
C-B13
XVIII-92
Al
CH
S
C-B70
C-B13
XVIII-93
Al
CH
S
C-B71
C-B13
XVIII-94
Al
CH
S
C-B89
C-B13
XVIII-95
Al
CH
S
C-B90
C-B13
XVIII-96
Al
CH
S
C-B91
C-B13
XVIII-97
Al
CH
Se
C-B1
C-B1
XVIII-98
Al
CH
Se
C-B13
C-B13
XVIII-99
Al
CH
Se
C-B16
C-B13
XVIII-100
Al
CH
Se
C-B17
C-B13
XVIII-101
Al
CH
Se
C-B25
C-B13
XVIII-102
Al
CH
Se
C-B52
C-B13
XVIII-103
Al
CH
Se
C-B54
C-B13
XVIII-104
Al
CH
Se
C-B55
C-B13
XVIII-105
Al
CH
Se
C-B63
C-B13
XVIII-106
Al
CH
Se
C-B68
C-B13
XVIII-107
Al
CH
Se
C-B69
C-B13
XVIII-108
Al
CH
Se
C-B70
C-B13
XVIII-109
Al
CH
Se
C-B71
C-B13
XVIII-110
Al
CH
Se
C-B89
C-B13
XVIII-111
Al
CH
Se
C-B90
C-B13
XVIII-112
Al
CH
Se
C-B91
C-B13
XVIII-113
Al
CH
NMe
C-B1
C-B1
XVIII-114
Al
CH
NMe
C-B13
C-B13
XVIII-115
Al
CH
NMe
C-B16
C-B13
XVIII-116
Al
CH
NMe
C-B17
C-B13
XVIII-117
Al
CH
NMe
C-B25
C-B13
XVIII-118
Al
CH
NMe
C-B52
C-B13
XVIII-119
Al
CH
NMe
C-B54
C-B13
XVIII-120
Al
CH
NMe
C-B55
C-B13
XVIII-121
Al
CH
NMe
C-B63
C-B13
XVIII-122
Al
CH
NMe
C-B68
C-B13
XVIII-123
Al
CH
NMe
C-B69
C-B13
XVIII-124
Al
CH
NMe
C-B70
C-B13
XVIII-125
Al
CH
NMe
C-B71
C-B13
XVIII-126
Al
CH
NMe
C-B89
C-B13
XVIII-127
Al
CH
NMe
C-B90
C-B13
XVIII-128
Al
CH
NMe
C-B91
C-B13
wherein, Compound XIX-1 to Compound XIX-128 have the structure of Formula XIX:
in Formula XIX, both of X are the same, both of Y are the same, both of W are the same, Z1, Z2, Z5 and Z6 are the same, Z3 and Z4 are the same, and X, Y, W, Z1, Z2, Z3, Z4, Z5 and Z6 are correspondingly selected from the atoms or groups as shown in the following table:
Z1 = Z2 =
Z1 = Z2 =
No.
X
Y
W
Z3 = Z4
Z5 = Z6
No.
X
Y
W
Z3 = Z4
Z5 = Z6
XIX-1
Al
N
O
C-B1
C-B1
XIX-2
Al
N
O
C-B13
C-B13
XIX-3
Al
N
O
C-B16
C-B13
XIX-4
Al
N
O
C-B17
C-B13
XIX-5
Al
N
O
C-B25
C-B13
XIX-6
Al
N
O
C-B52
C-B13
XIX-7
Al
N
O
C-B54
C-B13
XIX-8
Al
N
O
C-B55
C-B13
XIX-9
Al
N
O
C-B63
C-B13
XIX-10
Al
N
O
C-B68
C-B13
XIX-11
Al
N
O
C-B69
C-B13
XIX-12
Al
N
O
C-B70
C-B13
XIX-13
Al
N
O
C-B71
C-B13
XIX-14
Al
N
O
C-B89
C-B13
XIX-15
Al
N
O
C-B90
C-B13
XIX-16
Al
N
O
C-B91
C-B13
XIX-17
Al
N
S
C-B1
C-B1
XIX-18
Al
N
S
C-B13
C-B13
XIX-19
Al
N
S
C-B16
C-B13
XIX-20
Al
N
S
C-B17
C-B13
XIX-21
Al
N
S
C-B25
C-B13
XIX-22
Al
N
S
C-B52
C-B13
XIX-23
Al
N
S
C-B54
C-B13
XIX-24
Al
N
S
C-B55
C-B13
XIX-25
Al
N
S
C-B63
C-B13
XIX-26
Al
N
S
C-B68
C-B13
XIX-27
Al
N
S
C-B69
C-B13
XIX-28
Al
N
S
C-B70
C-B13
XIX-29
Al
N
S
C-B71
C-B13
XIX-30
Al
N
S
C-B89
C-B13
XIX-31
Al
N
S
C-B90
C-B13
XIX-32
Al
N
S
C-B91
C-B13
XIX-33
Al
N
Se
C-B1
C-B1
XIX-34
Al
N
Se
C-B13
C-B13
XIX-35
Al
N
Se
C-B16
C-B13
XIX-36
Al
N
Se
C-B17
C-B13
XIX-37
Al
N
Se
C-B25
C-B13
XIX-38
Al
N
Se
C-B52
C-B13
XIX-39
Al
N
Se
C-B54
C-B13
XIX-40
Al
N
Se
C-B55
C-B13
XIX-41
Al
N
Se
C-B63
C-B13
XIX-42
Al
N
Se
C-B68
C-B13
XIX-43
Al
N
Se
C-B69
C-B13
XIX-44
Al
N
Se
C-B70
C-B13
XIX-45
Al
N
Se
C-B71
C-B13
XIX-46
Al
N
Se
C-B89
C-B13
XIX-47
Al
N
Se
C-B90
C-B13
XIX-48
Al
N
Se
C-B91
C-B13
XIX-49
Al
N
NMe
C-B1
C-B1
XIX-50
Al
N
NMe
C-B13
C-B13
XIX-51
Al
N
NMe
C-B16
C-B13
XIX-52
Al
N
NMe
C-B17
C-B13
XIX-53
Al
N
NMe
C-B25
C-B13
XIX-54
Al
N
NMe
C-B52
C-B13
XIX-55
Al
N
NMe
C-B54
C-B13
XIX-56
Al
N
NMe
C-B55
C-B13
XIX-57
Al
N
NMe
C-B63
C-B13
XIX-58
Al
N
NMe
C-B68
C-B13
XIX-59
Al
N
NMe
C-B69
C-B13
XIX-60
Al
N
NMe
C-B70
C-B13
XIX-61
Al
N
NMe
C-B71
C-B13
XIX-62
Al
N
NMe
C-B89
C-B13
XIX-63
Al
N
NMe
C-B90
C-B13
XIX-64
Al
N
NMe
C-B91
C-B13
XIX-65
Al
CH
O
C-B1
C-B1
XIX-66
Al
CH
O
C-B13
C-B13
XIX-67
Al
CH
O
C-B16
C-B13
XIX-68
Al
CH
O
C-B17
C-B13
XIX-69
Al
CH
O
C-B25
C-B13
XIX-70
Al
CH
O
C-B52
C-B13
XIX-71
Al
CH
O
C-B54
C-B13
XIX-72
Al
CH
O
C-B55
C-B13
XIX-73
Al
CH
O
C-B63
C-B13
XIX-74
Al
CH
O
C-B68
C-B13
XIX-75
Al
CH
O
C-B69
C-B13
XIX-76
Al
CH
O
C-B70
C-B13
XIX-77
Al
CH
O
C-B71
C-B13
XIX-78
Al
CH
O
C-B89
C-B13
XIX-79
Al
CH
O
C-B90
C-B13
XIX-80
Al
CH
O
C-B91
C-B13
XIX-81
Al
CH
S
C-B1
C-B1
XIX-82
Al
CH
S
C-B13
C-B13
XIX-83
Al
CH
S
C-B16
C-B13
XIX-84
Al
CH
S
C-B17
C-B13
XIX-85
Al
CH
S
C-B25
C-B13
XIX-86
Al
CH
S
C-B52
C-B13
XIX-87
Al
CH
S
C-B54
C-B13
XIX-88
Al
CH
S
C-B55
C-B13
XIX-89
Al
CH
S
C-B63
C-B13
XIX-90
Al
CH
S
C-B68
C-B13
XIX-91
Al
CH
S
C-B69
C-B13
XIX-92
Al
CH
S
C-B70
C-B13
XIX-93
Al
CH
S
C-B71
C-B13
XIX-94
Al
CH
S
C-B89
C-B13
XIX-95
Al
CH
S
C-B90
C-B13
XIX-96
Al
CH
S
C-B91
C-B13
XIX-97
Al
CH
Se
C-B1
C-B1
XIX-98
Al
CH
Se
C-B13
C-B13
XIX-99
Al
CH
Se
C-B16
C-B13
XIX-100
Al
CH
Se
C-B17
C-B13
XIX-101
Al
CH
Se
C-B25
C-B13
XIX-102
Al
CH
Se
C-B52
C-B13
XIX-103
Al
CH
Se
C-B54
C-B13
XIX-104
Al
CH
Se
C-B55
C-B13
XIX-105
Al
CH
Se
C-B63
C-B13
XIX-106
Al
CH
Se
C-B68
C-B13
XIX-107
Al
CH
Se
C-B69
C-B13
XIX-108
Al
CH
Se
C-B70
C-B13
XIX-109
Al
CH
Se
C-B71
C-B13
XIX-110
Al
CH
Se
C-B89
C-B13
XIX-111
Al
CH
Se
C-B90
C-B13
XIX-112
Al
CH
Se
C-B91
C-B13
XIX-113
Al
CH
NMe
C-B1
C-B1
XIX-114
Al
CH
NMe
C-B13
C-B13
XIX-115
Al
CH
NMe
C-B16
C-B13
XIX-116
Al
CH
NMe
C-B17
C-B13
XIX-117
Al
CH
NMe
C-B25
C-B13
XIX-118
Al
CH
NMe
C-B52
C-B13
XIX-119
Al
CH
NMe
C-B54
C-B13
XIX-120
Al
CH
NMe
C-B55
C-B13
XIX-121
Al
CH
NMe
C-B63
C-B13
XIX-122
Al
CH
NMe
C-B68
C-B13
XIX-123
Al
CH
NMe
C-B69
C-B13
XIX-124
Al
CH
NMe
C-B70
C-B13
XIX-125
Al
CH
NMe
C-B71
C-B13
XIX-126
Al
CH
NMe
C-B89
C-B13
XIX-127
Al
CH
NMe
C-B90
C-B13
XIX-128
Al
CH
NMe
C-B91
C-B13

### Claim 19 (depends on 1)

An electroluminescent device comprising:
an anode,
a cathode, and
an organic layer disposed between the anode and the cathode, wherein the organic layer comprises the compound of claim 1.

### Claim 20 (depends on 19)

The electroluminescent device according to claim 19, wherein the organic layer is a hole injection layer or a hole transporting layer, and the hole injection layer or the hole transporting layer is formed by the compound alone.

### Claim 21 (depends on 19)

The electroluminescent device according to claim 19, wherein the organic layer is a hole injection layer or a hole transporting layer, and the hole injection layer or the hole transporting layer further comprises at least one hole transporting material; and wherein the molar doping ratio of the compound to the hole transporting material is from 10000:1 to 1:10000; preferably, the molar doping ratio of the compound to the hole transporting material is from 10:1 to 1:100.

### Claim 22 (depends on 21)

The electroluminescent device according to claim 21, wherein the hole transporting material comprises a compound having a triarylamine unit, a spirobifluorene compound, a pentacene compound, an oligothiophene compound, an oligophenyl compound, an oligophenylene vinyl compound, an oligofluorene compound, a porphyrin complex or a metal phthalocyanine complex.

### Claim 23 (depends on 19)

The electroluminescent device according to claim 19, the electroluminescent device comprises a plurality of stacks disposed between the anode and the cathode, wherein the stacks comprise a first light-emitting layer and a second light-emitting layer, wherein the first stack comprises a first light-emitting layer, and the second stack comprises a second light-emitting layer, and a charge generation layer is disposed between the first stack and the second stack, wherein the charge generation layer comprises a p-type charge generation layer and an n-type charge generation layer;
wherein the p-type charge generating layer comprises the compound; preferably, the p-type charge generation layer further comprises at least one hole transporting material, wherein the molar doping ratio of the compound to the hole transporting material is from 10000:1 to 1:10000; preferably, wherein the molar doping ratio of the compound to the hole transporting material is from 10:1 to 1:100.

### Claim 24 (depends on 23)

The electroluminescent device according to claim 23, wherein the hole transporting material comprises a compound having a triarylamine unit, a spirobifluorene compound, a pentacene compound, an oligothiophene compound, an oligophenyl compound, an oligophenylene vinyl compound, an oligofluorene compound, a porphyrin complex or a metal phthalocyanine complex.

### Claim 25 (depends on 23)

The electroluminescent device according to claim 23, the charge generation layer further includes a buffer layer disposed between the p-type charge generation layer and the n-type charge generation layer, wherein the buffer layer comprises the compound.

### Claim 26 (depends on 19)

The electroluminescent device according to claim 19, the electroluminescent device is fabricated via vacuum deposition methods.

### Claim 27 (depends on 1)

A compound formulation comprising the compound of claim 1.