# US 2021/0276314 A1 · Coffee stain-resistant cellulosic structures and associated containers and methods

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- Number: US 2021/0276314 A1
- Document ID: US20210276314A1
- Status: Published application
- Kind: A1
- Application number: 17/156,798
- Filed: 2021-01-25
- Published: 2021-09-09
- Earliest claimed: 2020-03-04
- Assignees: WestRock MWV, LLC
- Applicants: WestRock MWV, LLC
- Inventors: Jiebin Pang; Steven Parker; Natasha G. Melton
- Web page: https://patentgrep.com/patent/US20210276314A1

## CPC

- B32B 27/10: of paper or cardboard
- D21H 27/10: Packing paper (packaging materials of special type or form B65D65/38)
- B32B 27/20: using fillers, pigments, thixotroping agents
- B32B 27/306: {comprising vinyl acetate or vinyl alcohol (co)polymers}
- B65D 3/06: essentially conical or frusto-conical
- B65D 3/14: Discs fitting within container end and secured by bending, rolling, or folding operations
- D21H 19/52: Cellulose; Derivatives thereof
- D21H 19/58: Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
- D21H 19/60: Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
- D21H 19/82: superposed {(D21H19/84 takes precedence)}
- D21H 19/824: {two superposed coatings, both being non-pigmented}
- D21H 19/828: {two superposed coatings, the first applied being non-pigmented and the second applied being pigmented}
- D21H 19/84: on both sides of the substrate
- B32B 2250/03: 3 layers
- B32B 2250/04: 4 layers
- B32B 2255/12: on paper layer
- B32B 2255/26: Polymeric coating
- B32B 2255/28: Multiple coating on one surface
- B32B 2307/4026: within the layer by addition of a colorant, e.g. pigments, dyes
- B32B 2307/7265: Non-permeable
- B32B 2307/728: Hydrophilic
- B32B 2439/02: Open containers
- B32B 2439/62: Boxes, cartons, cases
- B32B 2439/70: Food packaging
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- D21H: PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- B65D: CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES

## Abstract

A cellulosic structure including a cellulosic substrate comprising a first major side and a second major side opposed from the first major side, an oil barrier layer on the second major side of the cellulosic substrate, and a water barrier layer on the second major side of the cellulosic substrate, wherein the oil barrier layer is positioned between the cellulosic substrate and the water barrier layer.

## Claims

### Claim 1

A cellulosic structure comprising:
a cellulosic substrate comprising a first major side and a second major side opposed from the first major side;
an oil barrier layer on the second major side of the cellulosic substrate; and
a water barrier layer on the second major side of the cellulosic substrate, wherein the oil barrier layer is positioned between the cellulosic substrate and the water barrier layer.

### Claim 2 (depends on 1)

The cellulosic structure of claim 1 wherein the oil barrier layer is hydrophilic or water-soluble.

### Claim 3 (depends on 1)

The cellulosic structure of claim 1 wherein the oil barrier layer is adjacent to the water barrier layer.

### Claim 4 (depends on 1)

The cellulosic structure of claim 1 wherein the oil barrier layer is adjacent to the cellulosic substrate.

### Claim at position 5

5-7. (canceled)

### Claim 8 (depends on 1)

The cellulosic structure of claim 1 wherein the oil barrier layer consists essentially of polyvinyl alcohol.

### Claim at position 7

9-12. (canceled)

### Claim 13 (depends on 1)

The cellulosic structure of claim 1 wherein the oil barrier layer further comprises a pigment.

### Claim 14 (depends on 13)

The cellulosic structure of claim 13 wherein the pigment comprises at least one of clay and calcium carbonate.

### Claim 15

(canceled)

### Claim 16 (depends on 1)

The cellulosic structure of claim 1 wherein the oil barrier layer has a coat weight, on a dry basis, of at least about 0.5 lb/3000 ft2.

### Claim at position 12

17-19. (canceled)

### Claim 20 (depends on 1)

The cellulosic structure of claim 1 wherein the water barrier layer comprises a single layer.

### Claim 21 (depends on 1)

The cellulosic structure of claim 1 wherein the water barrier layer comprises at least two layers.

### Claim 22 (depends on 1)

The cellulosic structure of claim 1 wherein the water barrier layer comprises a binder and a pigment.

### Claim 23 (depends on 22)

The cellulosic structure of claim 22 wherein a ratio of the pigment to the binder in the water barrier layer is at most 1:1, by weight.

### Claim 24 (depends on 22)

The cellulosic structure of claim 22 wherein a ratio of the pigment to the binder in the water barrier layer is at least about 1:1.5 to about 1:6, by weight.

### Claim 25

(canceled)

### Claim 26 (depends on 22)

The cellulosic structure of claim 22 wherein the binder comprises a latex.

### Claim at position 20

27-35. (canceled)

### Claim 36 (depends on 1)

The cellulosic structure of claim 1 wherein the water barrier layer has a coat weight, on a dry basis, of at least about 4 lb/3000 ft2.

### Claim at position 22

37-39. (canceled)

### Claim 40 (depends on 1)

The cellulosic structure of claim 1 wherein the cellulosic substrate comprises paperboard.

### Claim at position 24

41-47. (canceled)

### Claim 48 (depends on 1)

The cellulosic structure of claim 1 having a 30-minute-water-Cobb rating of at most about 20 g/m2.

### Claim at position 26

49-53. (canceled)

### Claim 54 (depends on 1)

A container comprising the cellulosic structure of claim 1.

### Claim 55

A container comprising:
a side wall having an upper end portion and a lower end portion; and
a bottom wall connected to the lower end portion of the side wall,
wherein at least the bottom wall comprises a cellulosic structure comprising:
a cellulosic substrate;
an oil barrier layer on the cellulosic substrate; and
a water barrier layer positioned over the oil barrier layer such that the oil barrier layer is positioned between the cellulosic substrate and the water barrier layer.

### Claim at position 29

56-58. (canceled)

### Claim 59

A method for manufacturing a cellulosic structure comprising:
applying an oil barrier coating formulation to a cellulosic substrate to form an oil barrier layer, the oil barrier coating formulation comprising at least one of polyvinyl alcohol, carboxymethylcellulose, alginate, and microfibrillated cellulose; and
applying a water barrier coating formulation over the oil barrier layer to form a water barrier layer, wherein the oil barrier layer is positioned between water barrier layer and the cellulosic substrate.

### Claim at position 31

60-63. (canceled)
