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US 2021/0246279 A1Published application
Hybrid systems consisting of foamed thermoplastic elastomers and polyurethanes
AssigneeBASF SE
InventorsFrank PRISSOK, Markus Schuette, Frank Braun
Life of this patent
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Abstract
A hybrid material contains a matrix of polyurethane and foamed particles of thermoplastic polyurethane contained therein. A process can be used for producing such hybrid materials and these hybrid materials can be used as bicycle saddles, upholstery and shoe soles.
Claims19
(canceled)
2:
- A saddle comprising a hybrid material,
- wherein the hybrid material comprises a matrix of polyurethane and foamed particles of thermoplastic polyurethane comprised therein,
- wherein the foamed particles have a closed surface skin.
3:
- The saddle according to claim 2, wherein the foamed particles have a diameter of from 0.1 mm to 10 cm and are spherical or ellipsoidal.
4:
- The saddle according to claim 3, wherein the foamed particles have a diameter of from 0.5 mm to 5 cm.
5:
- The saddle according to claim 2, wherein the foamed particles have a density of from 0.005 to 0.50 g/cm3.
6:
- The saddle according to claim 2, wherein the thermoplastic polyurethane of the foamed particles is based on polytetrahydrofuran having a number average molecular weight of from 600 to 2500 g/mol.
7:
- The saddle according to claim 2, wherein the thermoplastic polyurethane of the foamed particles is based on polyester alcohol having a number average molecular weight of from 500 to 2500 g/mol.
8:
- The saddle according to claim 2, wherein the matrix of polyurethane is a foam, a compact elastomeric system or a gel.
9:
- The saddle according to claim 8, wherein the matrix of polyurethane is a compact material and a weight ratio of the matrix to the foamed particles is from 1:1 to 1:20.
10:
- The saddle according to claim 2, wherein the matrix of polyurethane is a foam having a density of from 0.03 to 0.8 g/cm3.
11:
- The saddle according to claim 2, wherein a tear propagation resistance is greater than 2.5 N/mm at an average density of the hybrid material of from 0.4 to 0.5 g/cm3, greater than 2.2 N/mm at an average density of the hybrid material of from 0.3 to <0.4 g/cm3, greater than 2.0 N/mm at an average density of the hybrid material of from 0.2 to <0.3 g/cm3 and greater than 1.0 N/mm at an average density of the hybrid material of from 0.1 to <0.2 g/cm3.
12:
- A method of obtaining a saddle, the method comprising:
- forming a hybrid material into the saddle,
- wherein the hybrid material comprises a matrix of polyurethane and foamed particles of thermoplastic polyurethane comprised therein, wherein the foamed particles have a closed surface skin.
13:
- A process for producing a saddle with a hybrid material comprising a matrix of poly urethane and foamed particles of thermoplastic polyurethane comprised therein, the process comprising:
- mixing the following components, thereby obtaining a mixture:
- a) a polyisocyanate,
- b) a compound having a hydrogen atom which is reactive toward isocyanates,
- c) expanded particles (c″) of thermoplastic polyurethane,
- and, optionally,
- d) a chain extender and/or a crosslinker,
- e) a catalyst,
- f) a blowing agent, and
- g) a further additive;
- reacting the mixture to form the hybrid material;
- and
- preparing a saddle comprising the hybrid material.
10 more elements
14:
- The process for producing a saddle according to claim 13, wherein the expanded particles (c″) have a diameter of from 0.1 mm to 10 cm, and are spherical or ellipsoidal.
15:
- The process for producing a saddle according to claim 13, wherein the expanded particles (c″) have a density of from 0.005 to 0.50 g/cm3 and have a compact outer skin.
16:
- The process for producing a saddle according to claim 13, wherein no blowing agent is used.
17:
- The process for producing a saddle according to claim 16, wherein an isocyanate prepolymer having an NCO content of from 1 to 20% by weight is first prepared from the polyisocyanate a) and the compound having a hydrogen atom which is reactive toward isocyanates b), and
- optionally, the chain extender and/or crosslinker d), the catalyst e), the further additive g) and the isocyanate prepolymer are subsequently mixed with the expanded particles (c″) of thermoplastic polyurethane, to form a composite, and
- the composite is allowed to cure by action of water.
18:
- The process for producing a saddle according to claim 16, wherein the weight ratio of the components a), b) and d)-g) to the component c) is from 1:1 to 1:20.
19:
- A bicycle or a motorcycle, comprising the saddle according to claim 2.
Dependencies are inferred from the claim text.