# US 2021/0242494 A1 · Solid electrolyte material and battery using the same

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- Number: US 2021/0242494 A1
- Document ID: US20210242494A1
- Status: Published application
- Kind: A1
- Application number: 17/237,007
- Filed: 2021-04-21
- Published: 2021-08-05
- Earliest claimed: 2018-12-28
- Assignees: Panasonic Intellectual Property Management Co., Ltd.
- Applicants: Panasonic Intellectual Property Management Co., Ltd.
- Inventors: YOSHIAKI TANAKA; AKIHIRO SAKAI; TETSUYA ASANO; AKINOBU MIYAZAKI
- Web page: https://patentgrep.com/patent/US20210242494A1

## CPC

- H01M 10/0562: Solid materials
- C01G 33/006: {Compounds containing niobium, with or without oxygen or hydrogen, and containing two or more other elements}
- C01G 35/006: {Compounds containing tantalum, with or without oxygen or hydrogen, and containing two or more other elements}
- H01B 1/06: mainly consisting of other non-metallic substances
- H01B 1/08: oxides
- H01M 10/052: Li-accumulators
- C01P 2002/50: Solid solutions
- C01P 2002/72: by d-values or two theta-values, e.g. as X-ray diagram
- C01P 2006/32: Thermal properties
- C01P 2006/40: Electric properties
- H01M 2300/0071: Oxides
- H01M 2300/008: Halides
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- C01G: COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F (metal hydrides {monoborane, diborane or addition complexes thereof} C01B6/00; salts of oxyacids of halogens C01B11/00; peroxides, salts or peroxyacids C01B15/00; thiosulfates, dithionites, polythionates C01B17/64; compounds containing selenium, or tellurium C01B19/00; binary compounds of nitrogen with metals C01B21/06; azides C01B21/08; {compounds containing nitrogen, other non-metals and metal C01B21/082}; metal amides C01B21/092; nitrites C01B21/50; {compounds of noble gases C01B23/0005}; phosphides C01B25/08; salts of oxyacids of phosphorus C01B25/16; carbides C01B32/90; compounds containing silicon C01B33/00; compounds containing boron C01B35/00; compounds having molecular sieve properties but not having base-exchange properties C01B37/00; compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites, C01B39/00; cyanides C01C3/08; salts of cyanamide C01C3/16; thiocyanates C01C3/20)
- H01B: CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES (selection for magnetic properties H01F1/00; waveguides H01P {; printed circuits H05K})
- C01P: INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

The present disclosure provides solid electrolyte materials having high lithium ion conductivity. A solid electrolyte material according to the present disclosure consists essentially of Li, M, O, and X. M is at least one element selected from the group consisting of Nb and Ta. X is at least one element selected from the group consisting of Cl, Br, and I.

## Claims

### Claim 1

A solid electrolyte material consisting essentially of Li, M, O, and X,
wherein
M is at least one element selected from the group consisting of Nb and Ta, and
X is at least one element selected from the group consisting of Cl, Br, and I.

### Claim 2 (depends on 1)

The solid electrolyte material according to claim 1, wherein X is at least one element selected from the group consisting of Cl and Br.

### Claim 3 (depends on 1)

The solid electrolyte material according to claim 1, wherein X includes Cl.

### Claim 4 (depends on 1)

The solid electrolyte material according to claim 1, wherein the solid electrolyte material has a first crystalline phase, the first crystalline phase corresponding to a peak in an X-ray diffraction pattern of the solid electrolyte material obtained by an X-ray diffraction measurement with Cu-Kα radiation, the peak existing in at least one of a first range or a second range, the first range being a range of a diffraction angle 2θ of greater than or equal to 12.9° and less than or equal to 14.1°, and the second range being a range of the diffraction angle 2θ of greater than or equal to 24.0° and less than or equal to 25.8°.

### Claim 5 (depends on 4)

The solid electrolyte material according to claim 4, wherein the peak exists in both the first range and the second range.

### Claim 6 (depends on 4)

The solid electrolyte material according to claim 4, wherein the solid electrolyte material further has a second crystalline phase, the second crystalline phase being different from the first crystalline phase.

### Claim 7 (depends on 1)

The solid electrolyte material according to claim 1, wherein a molar ratio Li/M, which is a molar ratio of Li to M, is greater than or equal to 1.0 and less than or equal to 2.0.

### Claim 8 (depends on 1)

The solid electrolyte material according to claim 1, wherein a molar ratio O/X, which is a molar ratio of O to X, is greater than or equal to 0.1 and less than or equal to 0.25.

### Claim 9 (depends on 1)

The solid electrolyte material according to claim 1, wherein the solid electrolyte material has a third crystalline phase, the third crystalline phase corresponding to a peak in an X-ray diffraction pattern of the solid electrolyte material obtained by an X-ray diffraction measurement with Cu-Kα radiation, the peak existing in a third range, and the third range being a range of a diffraction angle 2θ of greater than or equal to 12.3° and less than or equal to 15.3°.

### Claim 10 (depends on 9)

The solid electrolyte material according to claim 9, wherein the solid electrolyte material further has a fourth crystalline phase, the fourth crystalline phase being different from the third crystalline phase.

### Claim 11 (depends on 1)

The solid electrolyte material according to claim 1, wherein the solid electrolyte material is represented by composition formula (1) below,
LixMOyX(5+x−2y) (1)
wherein the following relationships are satisfied:
0.1<x<7.0, and
0.4<y<1.9.

### Claim 12 (depends on 11)

The solid electrolyte material according to claim 11, wherein the following relationships are satisfied:
0.2≤x≤6.0, and
0.5≤y≤1.8.

### Claim 13 (depends on 12)

The solid electrolyte material according to claim 12, wherein a relationship of 0.5≤x≤2.0 is satisfied.

### Claim 14 (depends on 13)

The solid electrolyte material according to claim 13, wherein a relationship of 0.9≤x≤1.1 is satisfied.

### Claim 15 (depends on 1)

A battery comprising:
a positive electrode;
a negative electrode; and
an electrolyte layer disposed between the positive electrode and the negative electrode, wherein
at least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer includes the solid electrolyte material according to claim 1.
