COMPOSITION CONTAINING REFRIGERANT INCLUDING R32, R125, R143a AND R134a, AND REFRIGERATION METHOD USING SAID COMPOSITION, METHOD FOR OPERATING REFRIGERATOR, AND REFRIGERATOR
AssigneeDaikin Industries, Ltd.
InventorsMitsushi ITANO, Hitomi KUROKI, Shun OHKUBO, Tatsumi TSUCHIYA, Kenji GOBOU
Life of this patent
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Abstract
Provided is a composition containing a refrigerant that has a refrigerating capacity equivalent to that of widely used R404A, and a low GWP. The composition contains a refrigerant that contains difluoromethane (R32), pentafluoroethane (R125), 1,1,1-trifluoroethane (R143a), and 1,1,1,2-tetrafluoroethane (R134a) in specific concentrations.
Claims14
A composition comprising a refrigerant that contains R32, R125, R143a, and R134a
- the composition comprising one member selected from the group consisting of refrigerant 1, refrigerant 2, refrigerant 3, and refrigerant 4,
- wherein
- the total concentration of R32, R125, R143a and R134a is 100 mass %,
- the concentration of R32 is x mass %, and
- in a ternary composition diagram in which the total concentration of R125, R143a, and R134a is (100−x) mass %,
- refrigerant 1 has a compositional ratio as follows
- (1)-1 17.4 mass %≥x≥13.1 mass %,
- (1)-2 the concentration of R125, R143a, and 134a (the concentration of R125 (mass %)/the concentration of R143a (mass %)/the concentration of 134a (mass %)) falls on a point or within a triangular region that has the following points as vertices
- point A (0.35x+51.892/0.0/100−R32−R143a−R125),
- point D (−0.4309x2+0.0043x+130.4/0.2968x2+0.1331x−52.681/100−R32−R143a−R125), and
- point C (−2.2307x+90.59/0.0/100−R32−R125−R143a);
- refrigerant 2 has a compositional ratio as follows
- (2)-1 22.5 mass %≥x≥17.4 mass %,
- (2)-2 the concentration of R125, R143a, and 134a (the concentration of R125 (mass %)/the concentration of R143a (mass %)/the concentration of 134a (mass %)) falls within a quadrangular region that has the following points as vertices
- point A (0.3726x+51.526/0.0/100−R32−R125−R143a),
- point B (0.0/0.2547x+35.057/100−R32−R125−R143a),
- point D (0.0/−2.2158x+78.042/100−R32−R125−R143a), and
- point C (−2.5097x+88.978/0.0/100−R32−R125−R143a);
- refrigerant 3 has a compositional ratio as follows
- (3)-1 27.5 mass %≥x≥22.5 mass %,
- (3)-2 the concentration of R125, R143a, and 134a (the concentration of R125 (mass %)/the concentration of R143a (mass %)/the concentration of 134a (mass %)) falls within a quadrangular region that has the following points as vertices
- point A (0.36x+51.8/0.0/100−R32−R125−R143a),
- point B (0.0/0.24x+35.4/100−R32−R125−R143a),
- point D (0.0/−2.12x+75.867/100−R32−R125−R143a), and
- point C (−2.42x+86.933/0.0/100−R32−R125−R143a);
- and
- refrigerant 4 has a compositional ratio as follows
- (4)-1 32.5 mass %≥x≥27.5 mass %,
- (4)-2 the concentration of R125, R143a, and 134a (the concentration of R125 (mass %)/the concentration of R143a (mass %)/the concentration of 134a (mass %)) falls within a quadrangular region that has the following points as vertices
- point A (0.36x+51.8/0.0/100−R32−R125−R143a),
- point B (0.0/0.24x+35.4/100−R32−R125−R143a),
- point D (0.0/−2.04x+73.7/100−R32−R125−R143a), and
- point C (−2.36x+85.3/0.0/100−R32−R125−R143a).
A composition comprising a refrigerant that contains R32, R125, R143a, and R134a,
- the composition comprising one member selected from the group consisting of refrigerant A, refrigerant B, and refrigerant C,
- wherein
- the total concentration of R32, R125, and (R143a+R134a) is 100 mass %,
- the ratio of the concentration of R143a to the concentration of (R143a+R134a) is r=100×[R143a/(R143a+R134a)], and
- in a ternary composition diagram in which the total concentration of R32, R125, and (R143a+R134a) is 100 mass %,
- refrigerant A has a compositional ratio as follows
- (1)-1 11≥r≥0,
- (1)-2 the concentration of R32, R125, and (R143a+134a) (the concentration of R32 (mass %)/the concentration of R125 (mass %)/the concentration of (R143a+134a) (mass %)) falls within a triangular region that has the following points as vertices
- point I0≤r≤11 (32.5/−0.0636r+63.5/100−R32−R125),
- point G0≤r≤11 (0.0455r+13.1/−0.5091r+56.5/100−R32−R125), and
- point J0≤r≤11 (32.5/−0.8455r+9.3/100−R32−R125);
- refrigerant B has a compositional ratio as follows
- (2)-1 35.2≥r≥11,
- (2)-2 the concentration of R32, R125, and (R143a+134a) (the concentration of R32 (mass %)/the concentration of R125 (mass %)/the concentration of (R143a+134a) (mass %)) falls within a quadrangular region that has the following points as vertices
- point I11<r≤35.2 (32.5/−0.003r2−0.0072r+63.239/100−R32−R125),
- point G11<r≤35.2 (0.001r2+0.0287r+13.165/−0.0188r2−0.0718r+53.97/100−R32−R125),
- point H11<r≤35.2 (−0.0014r2−0.3292r+36.287/0.0/100−R32−R125), and
- point J11<r≤35.2 (32.5/0.0/67.5);
- and
- Refrigerant C has a compositional ratio as follows
- (3)-1 47.8≥r≥35.2,
- (3)-2 the concentration of R32, R125, and (R143a+134a) (the concentration of R32 (mass %)/the concentration of R125 (mass %)/the concentration of (R143a+134a) (mass %)) falls within a quadrangular region or triangular region that has the following points as vertices
- point I35.2<r≤47.8 (32.5/−0.0169r2+0.9999r+45.073/100−R32−R125),
- point G35.2<r≤47.8 (0.0041r2−0.1818r+16.716/−0.077r2+4.163r−23.0/100−R32−R125),
- point H35.2<r≤47.8 (−0.0011r2−0.3491r+36.712/0.0/100−R32−R125), and
- point J35.2<r≤47.8 (32.5/0.0/67.5).
A method for showing a mixture formulation composed of four refrigerant components with the total concentration of the four refrigerant components taken as 100 mass %, and the concentration of each component taken as a mass %, b mass %, c mass %, and d mass %, the method comprising
- fixing the concentration of one refrigerant component at a mass %, and setting the concentration of the three remaining refrigerant components as b mass %, c mass %, and d mass %;
- and
- showing the respective concentrations of the three refrigerant components in a ternary composition diagram (ternary diagram) in which the total concentration thereof is shown as (100−a) mass %.
A method for showing a mixture formulation composed of four refrigerant components with the total concentration of the four refrigerant components taken as 100 mass %, and the concentration of each component taken as a mass %, b mass %, c mass %, and d mass %, the method comprising
- setting the respective concentrations of the four refrigerant components as a mass %, b mass %, and (c+d) mass % as three apparent components;
- showing the respective concentrations of the three components in a ternary composition diagram (ternary diagram) in which the total concentration of the three components is shown as 100 mass %;
- further introducing the mass ratio of c mass % to (c+d) mass %, which is r=100×[c/(c+d)];
- and
- showing the concentration of each of the three components in the ternary composition diagram for each value of r.
Dependencies are inferred from the claim text.