A method for producing an electrically conductive thin film, comprising (a) mixing a solution of tetraoctylammonium bromide (TOABr) in a non-polar solvent with a solution of a silver precursor in a polar solvent to prepare a mixture, (b) adding a thiosulfate salt to the mixture such that silver-thiosulfate anions ([Ag(S2O3)2]3−) are phase transferred to the non-polar solvent layer, (c) separating the non-polar solvent layer containing the phase-transferred silver-thiosulfate anions and adding a reducing agent thereto to synthesize silver nanoparticles, (d) immersing a substrate in the dispersion of the silver nanoparticles in the non-polar solvent to form a particle layer on the substrate, and (e) immersing the substrate formed with the particle layer in a dispersion of a monomolecular material having amine groups in an organic solvent to form a linker layer on the particle layer.