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US 2021/0230320 A1Published application
Polymerizable composition for optical material, molded product, optical material, and plastic lens and method for manufacturing same
AssigneeMitsui Chemicals, Inc.
InventorsTatsuya OGAWA, Masayuki FURUYA
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Abstract
A polymerizable composition for an optical material includes: an allyl carbonate compound (A) including two or more allyloxycarbonyl groups at a terminal which is represented by General Formula (1); and a radical polymerization initiator (B). The radical polymerization initiator (B) includes at least one kind of radical polymerization initiator (B1) which is a peroxyester-based radical polymerization initiator, and a radical polymerization initiator (B2).
Claims9
A polymerizable composition for an optical material, comprising:
- an allyl carbonate compound (A) including two or more allyloxycarbonyl groups at a terminal which is represented by General Formula (1);
- and
- a radical polymerization initiator (B),
- wherein the radical polymerization initiator (B) includes
- at least one kind of radical polymerization initiator (B1) which is a peroxyester-based radical polymerization initiator in which a radical residual ratio after 5 hours at 50° C. is 10% or more and 90% or less, and which has an alkyl group having 5 or more carbon atoms and including a tertiary carbon atom directly connected to an O—O bond, and
- a radical polymerization initiator (B2) in which a residual radical ratio after 5 hours at 95° C. is 10% or more and 90% or less and which is at least one kind selected from the group consisting of a peroxyester-based radical polymerization initiator, a peroxyketal-based radical polymerization initiator, and a peroxymonocarbonate-based radical polymerization initiator,
- wherein, in General Formula (1), R1 represents a divalent to 20 valent group derived from a chained or branched aliphatic polyol with 3 to 35 carbon atoms which optionally include a hetero atom, or a divalent to 20 valent group derived from a cycloaliphatic polyol with 5 to 40 carbon atoms which optionally include a hetero atom, n represents an integer of 2 to 20, and R1 does not include an allyloxycarbonyl group.
4 more elements
A method for manufacturing a plastic lens, comprising:
- a step of preparing a polymerizable composition for an optical material by mixing an allyl Patent carbonate compound (A) including two or more allyloxycarbonyl groups at a terminal which is represented by General Formula (1) with a radical polymerization initiator (B);
- and
- a step of forming a lens base material by cast polymerization of the polymerizable composition for an optical material,
- wherein the radical polymerization initiator (B) includes at least one kind of radical polymerization initiator (B1) which is a peroxyester-based radical polymerization initiator in which a radical residual ratio after 5 hours at 50° C. is 10% or more and 90% or less and which has an alkyl group having 5 or more carbon atoms and including a tertiary carbon atom directly connected to an O—O bond, and
- a radical polymerization initiator (B2) in which a residual radical ratio after 5 hours at 95° C. is 10% or more and 90% or less and which is at least one kind selected from the group consisting of a peroxyester-based radical polymerization initiator, a peroxyketal-based radical polymerization initiator, and a peroxymonocarbonate-based radical polymerization initiator,
- wherein, in General Formula (1), R1 represents a chained or branched divalent to 20 valent group derived from an aliphatic polyol with 3 to 35 carbon atoms which optionally include a hetero atom, or a divalent to 20 valent group derived from a cycloaliphatic polyol with 5 to 40 carbon atoms which optionally include a hetero atom, n represents an integer of 2 to 20, and R1 does not include an allyloxycarbonyl group.
3 more elements
Dependencies are inferred from the claim text.