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US 2021/0230137 A1Published application
Pyrazine compound
AssigneeSumitomo Chemical Company, Limited
InventorsKohei ORIMOTO, Yoshihiko NOKURA, Yuji NAKAJIMA, Takamasa TANABE, Takahiro KIMURA
Life of this patent
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Abstract
Provided is a compound represented by formula (I): or an N-oxide compound thereof, wherein the variable groups are as defined in the specification. Also provided is an arthropod pest control agent containing a compound represented by formula (I) and an inert carrier. The compound represented by formula (I) and arthropod pest control agent exhibit an excellent controlling effect against arthropod pests.
Claims3
A compound represented by formula (M-3):
- [wherein
- A1 represents a nitrogen atom or a CR4;
- R4 represents a hydrogen atom, a OR27, a NR27R28, a cyano group, a nitro group, or a halogen atom;
- R27 and R28 represent independently of each other, a hydrogen atom, or a C1-C6 alkyl group optionally having one or more halogen atoms;
- R2 represents a C1-C6 alkyl group optionally having one or more halogen atoms, a cyclopropylmethyl group, or a cyclopropyl group;
- q represents 0, 1, 2, or 3;
- R3 represents independently of each other a C1-C6 chain hydrocarbon group optionally having one or more substituents selected from Group B, a phenyl group optionally having one or more substituents selected from Group D, a 5 or 6 membered aromatic heterocyclic group optionally having one or more substituents selected from Group D, a OR12, a NR11R12, a NR11aR12a, a NR29NR11R12, a NR29OR11, a NR11C(O)R13, a NR29NR11C(O)R13, a NR11C(O)OR14, a NR29NR11C(O)OR14, a NR11C(O)NR15R16, a NR24NR11C(O)NR15R16, a N═CHNR15R16, a N═S(O)xR15R16, a S(O)yR15, a C(O)OR17, a C(O)NR11R12, a cyano group, a nitro group, or a halogen atom, and when q is 2 or 3, a plurality of R3 may be identical or different;
- R11, R17, R18, R19, R24 and R29 represent independently of each other a hydrogen atom, or a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms;
- R12 represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkyl group having one substituent selected from Group F, or a S(O)2R23;
- R23 represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, or a phenyl group optionally having one or more substituents selected from Group D;
- R11a and R12a combine together with a nitrogen atom to which they are attached to form a 3 to 7 membered nonaromatic heterocyclic group optionally having one or more substituents selected from Group E {the 3 to 7 membered nonaromatic heterocyclic group represents aziridine, azetidine, pyrrolidine, imidazoline, imidazolidine, piperidine, tetrahydropyrimidine, hexahydropyrimidine, piperazine, azepane, oxazolidine, isooxazolidine, 1,3-oxazinane, morpholine, 1,4-oxazepane, thiazolidine, isothiazolidine, 1,3-thiazinane, thiomorpholine, or 1,4-thiazepane};
- R13 represents a hydrogen atom, a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, a phenyl group optionally having one or more substituents selected from Group D, or a 5 or 6 membered aromatic heterocyclic group optionally having one or more substituents selected from Group D;
- R14 represents a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally having one or more halogen atoms, or a phenylC1-C3 alkyl group {the phenyl moiety in the phenylC1-C3 alkyl group may optionally have one or more substituents selected from Group D};
- R15 and R16 represent independently of each other, a C1-C6 alkyl group optionally having one or more halogen atoms;
- n represents 0, 1, or 2;
- p represents 0, 1, or 2;
- and
- R6 represents independently of each other a C1-C6 alkyl group optionally having one or more halogen atoms, a OR18, a NR18R19, a cyano group, a nitro group, or a halogen atom, and when p is 2, a plurality of R6 may be identical or different;
- Group B:
- a group consisting of a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom;
- Group C:
- a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, and a halogen atom;
- Group D:
- a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally having one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, an amino group, a NHR21, a NR21R22, a C(O)R21, a OC(O)R21, a C(O)OR21, a cyano group, a nitro group, and a halogen atom {R21 and R22 represent independently of each other a C1-C6 alkyl group optionally having one or more halogen atoms};
- Group E:
- a group consisting of a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, a C1-C6 alkoxy group optionally having one or more halogen atoms, a C3-C6 alkenyloxy group optionally having one or more halogen atoms, a C3-C6 alkynyloxy group optionally having one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group;
- Group F:
- a group consisting of a C1-C6 alkoxy group optionally having one or more halogen atoms, an amino group, a NHR21, a NR21R22, a cyano group, a phenyl group optionally having one or more substituents selected from Group D, a 5 or 6 membered aromatic heterocyclic group optionally having one or more substituents selected from Group D, a C3-C7 cycloalkyl group optionally having one or more halogen atoms, and a 3 to 7 membered nonaromatic heterocyclic group optionally having one or more substituents selected from Group C.].
25 more elements
A compound represented by formula (M-30):
- [wherein
- R40 represents a halogen atom, a C1-C4 alkoxy group, or a OR1;
- R1 represents a C2-C10 chain hydrocarbon group having one or more halogen atoms, a (C1-C5 alkoxy)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group having one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C3 alkyl group having one or more substituents selected from Group G, or a C3-C7 cycloalkyl group having one or more substituents selected from Group G;
- R2 represents a C1-C6 alkyl group optionally having one or more halogen atoms, a cyclopropylmethyl group, or a cyclopropyl group;
- n represents 0, 1, or 2;
- p represents 0, 1, or 2;
- R6 represents independently of each other a C1-C6 alkyl group optionally having one or more halogen atoms, a OR18, a NR18R19, a cyano group, a nitro group, or a halogen atom, and when p is 2, a plurality of R6 may be identical or different;
- R18 and R19 represent independently of each other a hydrogen atom, or a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms;
- and
- Group G:
- a group consisting of a halogen atom, and a C1-C6 haloalkyl group].
8 more elements
A compound represented by formula (M-31):
- [wherein
- R40 represents a halogen atom, a C1-C4 alkoxy group, or a OR1;
- R1 represents a C2-C10 chain hydrocarbon group having one or more halogen atoms, a (C1-C5 alkoxy)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group having one or more halogen atoms, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group having one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C3 alkyl group having one or more substituents selected from Group G, or a C3-C7 cycloalkyl group having one or more substituents selected from Group G;
- R2 represents a C1-C6 alkyl group optionally having one or more halogen atoms, a cyclopropylmethyl group, or a cyclopropyl group;
- n represents 0, 1, or 2;
- p represents 0, 1, or 2;
- R6 represents independently of each other a C1-C6 alkyl group optionally having one or more halogen atoms, a OR18, a NR18R19, a cyano group, a nitro group, or a halogen atom, and when p is 2, a plurality of R6 may be identical or different;
- R18 and R19 represent independently of each other a hydrogen atom, or a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms;
- and
- Group G:
- a group consisting of a halogen atom, and a C1-C6 haloalkyl group].
8 more elements
Dependencies are inferred from the claim text.