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US 2021/0147593 A1Published application
Fluoro acrylate and methods making and using the same
AssigneeMadico, Inc.
InventorsPhilip Canale, Marina Temchenko, Barbara Heck
Life of this patent
Estimating the term…
Abstract
A number of variations may include a method including modifying fluorocopolymer polyols, diols, and related copolymers to make polymerizable materials through polymerizable unsaturation. A number of variations may include products, for example but not limited to coatings, films or painting including modifying fluorocopolymer polyols, diols, and related copolymers.
Claims19
A method comprising reacting:
- where, R2 comprises a fluorine containing monomer;
- at least one of R3, R4, or R5 is a monomer repeat units comprising a group including vinyl acetate, methyl vinyl ether, ethyl vinyl ether, butyl vinyl ether, ethylene, propylene, methyl acrylate, ethyl acrylate butyl acrylate, hexyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, vinyl cyclohexane, acrylic acid, acrylonitrile, acrylamide, glycidyl methacrylate or acrylate, or a monomer vinyl repeating group;
- each of R1 and R6 includes a initiator, chain transfer, chain termination, or coupling, and wherein R is a group of aliphatic or fluorinated aliphatic.
A method comprising reacting
- with at least one of:
- 2-methacryloyloxyethyl isocyanate, 2-isocyanatoethyl methacrylate, 1-isocyanatomethyl methacrylate, 1-isocyanatomethyl acrylate, or inclusively a structure having the general formula:
- where R2 can be from a fluorine containing monomer,
- R1 and R6 are from a group of initiators, chain transfer, chain termination, or coupling groups;
- at least one of R3, R4, or R5 is a monomer repeat units comprising a group including vinyl acetate, methyl vinyl ether, ethyl vinyl ether, butyl vinyl ether, ethylene, propylene, methyl acrylate, ethyl acrylate butyl acrylate, hexyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, vinyl cyclohexane, acrylic acid, acrylonitrile, acrylamide, glycidyl methacrylate or acrylate, or a monomer vinyl repeating group;
- each of R1 and R6 includes a initiator, chain transfer, chain termination, or coupling, and wherein R is a group of aliphatic or fluorinated aliphatic.
3 more elements
A coating solution comprising
- where, R2 comprises a fluorine containing monomer;
- at least one of R3, R4, or R5 is a monomer repeat units comprising a group including vinyl acetate, methyl vinyl ether, ethyl vinyl ether, butyl vinyl ether, ethylene, propylene, methyl acrylate, ethyl acrylate butyl acrylate, hexyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, vinyl cyclohexane, acrylic acid, acrylonitrile, acrylamide, glycidyl methacrylate or acrylate, or a monomer vinyl repeating group;
- each of R1 and R6 includes a initiator, chain transfer, chain termination, or coupling, and wherein R is a group of aliphatic or fluorinated aliphatic.
A coating solution comprising the product of reacting
- with at least one of:
- 2-methacryloyloxyethyl isocyanate, 2-isocyanatoethyl methacrylate, 1-isocyanatomethyl methacrylate, 1-isocyanatomethyl acrylate, or inclusively a structure having the general formula:
- where R2 can be from any fluorine containing monomer which may enhance weatherability such as trifluorochloroethylene, tetrafluoroethylene, hexafluoropropylene, perfluoromethylvinylether, Perfluoropropylvinylether, vinylidene fluoride, vinylfluoride, or a perfluorocycloalkene. R3, R4, and/or R5 monomer repeat units, if included may be chosen from various monomer groups these groups vinyl acetate, methyl vinyl ether, ethyl vinyl ether, butyl vinyl ether, ethylene, propylene, methyl acrylate, ethyl acrylate butyl acrylate, hexyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, vinyl cyclohexane, acrylic acid, acrylonitrile, acrylamide, glycidyl methacrylate or acrylate, or a monomer vinyl;
- R1 and R6 are from a group of initiators, chain transfer, chain termination, or coupling groups;
- Ra is hydrogen or fluorine, or a group including carbon.
2 more elements
A substrate having a solid coating thereon produced by curing
- where, R2 comprises a fluorine containing monomer;
- at least one of R3, R4, or R5 is a monomer repeat units comprising a group including vinyl acetate, methyl vinyl ether, ethyl vinyl ether, butyl vinyl ether, ethylene, propylene, methyl acrylate, ethyl acrylate butyl acrylate, hexyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, vinyl cyclohexane, acrylic acid, acrylonitrile, acrylamide, glycidyl methacrylate or acrylate, or a monomer vinyl repeating group;
- each of R1 and R6 includes a initiator, chain transfer, chain termination, or coupling, and wherein R is a group of aliphatic or fluorinated aliphatic.
A substrate having a solid coating thereon produced by curing
- with at least one of:
- 2-methacryloyloxyethyl isocyanate, 2-isocyanatoethyl methacrylate, 1-isocyanatomethyl methacrylate, 1-isocyanatomethyl acrylate, or inclusively a structure having the general formula:
- where R2 can be from any fluorine containing monomer which may enhance weatherability such as trifluorochloroethylene, tetrafluoroethylene, hexafluoropropylene, perfluoromethylvinylether, Perfluoropropylvinylether, vinylidene fluoride, vinylfluoride, or a perfluorocycloalkene. R3, R4, and/or R5 monomer repeat units, if included may be chosen from various monomer groups these groups vinyl acetate, methyl vinyl ether, ethyl vinyl ether, butyl vinyl ether, ethylene, propylene, methyl acrylate, ethyl acrylate butyl acrylate, hexyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate, vinyl cyclohexane, acrylic acid, acrylonitrile, acrylamide, glycidyl methacrylate or acrylate, or a monomer vinyl;
- R1 and R6 are from a group of initiators, chain transfer, chain termination, or coupling groups;
- Ra is hydrogen or fluorine, or a group including carbon.
2 more elements
Dependencies are inferred from the claim text.