# US 2020/0403256 A1 · Fuel cell system

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- Number: US 2020/0403256 A1
- Document ID: US20200403256A1
- Status: Published application
- Kind: A1
- Application number: 16/901,473
- Filed: 2020-06-15
- Published: 2020-12-24
- Earliest claimed: 2019-06-18
- Assignees: Toyota Jidosha Kabushiki Kaisha
- Applicants: Toyota Jidosha Kabushiki Kaisha
- Inventors: Masayuki Itou; Yasushi Araki
- Web page: https://patentgrep.com/patent/US20200403256A1

## CPC

- H01M 8/04679: {of fuel cell stacks}
- H01M 8/04388: {of anode reactants at the inlet or inside the fuel cell}
- H01M 8/04417: {of the coolant}
- H01M 8/04447: {of anode reactants at the inlet or inside the fuel cell}
- H01M 8/04455: {of cathode reactants at the inlet or inside the fuel cell}
- H01M 8/04552: {of the individual fuel cell}
- H01M 8/04559: {of fuel cell stacks}
- H01M 8/04582: {of the individual fuel cell}
- H01M 8/04671: {of the individual fuel cell}
- H01M 8/249: comprising two or more groupings of fuel cells, e.g. modular assemblies
- H01M 2008/1095: {Fuel cells with polymeric electrolytes}
- H01M 2250/20: Fuel cells in motive systems, e.g. vehicle, ship, plane
- Y02E 60/50: Fuel cells
- Y02T 90/40: Application of hydrogen technology to transportation, e.g. using fuel cells
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02T: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION

## Abstract

A fuel cell system includes a first fuel cell, second fuel cell, first voltage detector, second voltage detector, and controller. The first voltage detector detects voltage of first unit cells of the first fuel cell for every “N” unit cells on average, and the second voltage detector detects voltage of the second fuel cell as a whole, or detects voltage of second unit cells of the second fuel cell for every “M” unit cells on average, where “M” is larger than “N”. The controller determines whether any of the second unit cells is in a fuel deficiency state, based on the detection result of the first voltage detector, when a predetermined condition under which states of the first fuel cell and the second fuel cell are regarded as being close to each other is satisfied.

## Claims

### Claim 1

A fuel cell system comprising:
a first fuel cell to which a fuel gas and an oxidant gas are supplied, the first fuel cell including a plurality of first unit cells stacked together;
a second fuel cell to which a fuel gas and an oxidant gas are supplied, the second fuel cell including a plurality of second unit cells stacked together;
a first voltage detector connected to the first fuel cell;
a second voltage detector connected to the second fuel cell; and
a controller configured to control the first fuel cell based on a detection result of the first voltage detector, and control the second fuel cell based on a detection result of the second voltage detector, wherein
each of the first unit cells includes a first electrolyte membrane, a first anode catalyst layer provided on a first surface of the first electrolyte membrane, and a first cathode catalyst layer provided on a second surface of the first electrolyte membrane,
each of the second unit cells includes a second electrolyte membrane, a second anode catalyst layer provided on a first surface of the second electrolyte membrane, and a second cathode catalyst layer provided on a second surface of the second electrolyte membrane,
the first electrolyte membrane and the second electrolyte membrane are made of the same material, and have substantially the same thickness,
the first anode catalyst layer and the second anode catalyst layer are made of the same material, and have substantially the same amount per unit area,
the first cathode catalyst layer and the second cathode catalyst layer are made of the same material, and have substantially the same amount per unit area,
the first voltage detector is configured to detect voltage of the first unit cells for every “N” unit cells on average,
the second voltage detector is configured to detect voltage of the second fuel cell as a whole, or detect voltage of the second unit cells for every “M” unit cells on average, where “M” represents a number that is larger than “N”, and
the controller is configured to determine whether any of the second unit cells is in a fuel deficiency state, based on the detection result of the first voltage detector, when a predetermined condition under which states of the first fuel cell and the second fuel cell are regarded as being close to each other is satisfied.

### Claim 2 (depends on 1)

The fuel cell system according to claim 1, wherein the predetermined condition includes a condition that a difference between a temperature of the first fuel cell and a temperature of the second fuel cell is smaller than a predetermined value.

### Claim 3 (depends on 1)

The fuel cell system according to claim 1, wherein the predetermined condition includes a condition that a difference between a stoichiometric ratio of the fuel gas supplied to the first fuel cell and a stoichiometric ratio of the fuel gas supplied to the second fuel cell is smaller than a predetermined value.

### Claim 4 (depends on 1)

The fuel cell system according to claim 1, wherein the predetermined condition includes a condition that a difference between a pressure in a first fuel gas channel through which the fuel gas flows in the first fuel cell and a pressure in a second fuel gas channel through which the fuel gas flows in the second fuel cell is smaller than a predetermined value.

### Claim 5 (depends on 1)

The fuel cell system according to claim 1, wherein the predetermined condition includes a condition that a difference between a stoichiometric ratio of the oxidant gas supplied to the first fuel cell and a stoichiometric ratio of the oxidant gas supplied to the second fuel cell is smaller than a predetermined value.

### Claim 6 (depends on 1)

The fuel cell system according to claim 1, wherein the predetermined condition includes a condition that a difference between a flow rate of coolant that flows in the first fuel cell and a flow rate of coolant that flows in the second fuel cell is smaller than a predetermined value.

### Claim 7 (depends on 1)

The fuel cell system according to claim 1, wherein the predetermined condition includes a condition that a difference between an output current density of each of the first unit cells and an output current density of each of the second unit cells is smaller than a predetermined value.

### Claim 8 (depends on 1)

The fuel cell system according to claim 1, wherein the controller is configured to perform a cancellation process to cancel the fuel deficiency state, on the second fuel cell, when the controller determines that any of the second unit cells is in the fuel deficiency state.

### Claim 9 (depends on 1)

The fuel cell system according to claim 1, wherein the controller is configured to determine whether any of the first unit cells is in the fuel deficiency state, based on the detection result of the first voltage detector.

### Claim 10 (depends on 9)

The fuel cell system according to claim 9, wherein the controller is configured to perform a cancellation process to cancel the fuel deficiency state, on the first fuel cell, when the controller determines that any of the first unit cells is in the fuel deficiency state.

### Claim 11 (depends on 10)

The fuel cell system according to claim 10, wherein the controller is configured to perform the cancellation process on the second fuel cell, before performing the cancellation process on the first fuel cell, when the controller determines that any of the second unit cells is in the fuel deficiency state.

### Claim 12 (depends on 10)

The fuel cell system according to claim 10, wherein the controller is configured to determine whether any of the second unit cells is in the fuel deficiency state, before determining whether any of the first unit cells is in the fuel deficiency state, in at least one of a case where a voltage parameter correlated with a voltage of the second fuel cell indicates that the voltage of the second fuel cell is lower than a predetermined threshold value, and a case where a temperature parameter correlated with a temperature of the second fuel cell indicates that the temperature of the second fuel cell is lower than a predetermined threshold value, the controller being configured to perform the cancellation process on the second fuel cell, before performing the cancellation process on the first fuel cell, when the controller determines that any of the second unit cells is in the fuel deficiency state.

### Claim 13 (depends on 1)

The fuel cell system according to claim 1, wherein the controller is configured to determine whether any of the second unit cells is in the fuel deficiency state, based on the detection result of the first voltage detector, when the predetermined condition is not satisfied, but a condition indicating a state where any of the second unit cells is more likely to be placed in the fuel deficiency state than any of the first unit cells is satisfied.

### Claim 14 (depends on 1)

The fuel cell system according to claim 1, wherein each of the first unit cells and the second unit cells is comprised of same components.