# US 2020/0403231 A1 · Multi-Layered Anode Containing Silicon-Based Compound and Lithium Secondary Battery Including the Same

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- Number: US 2020/0403231 A1
- Document ID: US20200403231A1
- Status: Published application
- Kind: A1
- Application number: 16/968,779
- Filed: 2019-10-02
- Published: 2020-12-24
- Earliest claimed: 2018-10-02
- Assignees: LG Chem, Ltd.
- Applicants: LG Chem, Ltd.
- Inventors: Dong Hwi Kim; Tae Hee Kim; Nanji Yun; Yojin Kim; Hyunkyung Do
- Web page: https://patentgrep.com/patent/US20200403231A1

## CPC

- H01M 4/131: Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
- H01M 4/366: {as layered products}
- H01M 4/133: Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M 4/364: {as mixtures}
- H01M 4/483: {for non-aqueous cells (H01M4/485 takes precedence)}
- H01M 4/587: for inserting or intercalating light metals
- H01M 4/622: {being polymers}
- H01M 4/625: {Carbon or graphite}
- H01M 10/0525: Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
- H01M 2004/021: {Physical characteristics, e.g. porosity, surface area}
- H01M 2004/027: {Negative electrodes}
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

The present disclosure relates to an anode for a lithium secondary battery and a lithium secondary battery including the same, wherein the anode includes an anode current collector; a first anode active material layer formed on at least one surface of the anode current collector and containing a mixture of natural graphite and artificial graphite in a weight ratio of 13˜34:66˜87 and a first binder as the anode active material; and a second anode active material layer formed on the first anode active material layer and containing a mixture of artificial graphite and a silicon-based compound in a weight ratio of 91˜99:1˜9 and a second binder as the anode active material.

## Claims

### Claim 1

An anode for a lithium secondary battery, comprising
an anode current collector;
a first anode active material layer formed on at least one surface of the anode current collector, wherein the first anode active material layer contains a mixture of natural graphite and artificial graphite in a weight ratio of 13 to 34:66 to 87 as the anode active material and a first binder; and
a second anode active material layer formed on the first anode active material layer, wherein the second anode active material layer contains a mixture of artificial graphite and a silicon-based compound in a weight ratio of 91 to 99:1 to 9 as the anode active material and a second binder.

### Claim 2 (depends on 1)

The anode for a lithium secondary battery of claim 1,
wherein the first anode active material layer contains the mixture of natural graphite and artificial graphite in a weight ratio of 20 to 30:70 to 80 as the anode active material, and
the second anode active material layer contains the mixture of artificial graphite and a silicon-based compound in a weight ratio of 95 to 99:1 to 5 as the anode active material.

### Claim 3 (depends on 1)

The anode for a lithium secondary battery of claim 1,
wherein the silicon-based compound is a silicon-based oxide represented by the following Chemical Formula 1:
SiOx [Chemical Formula 1]
wherein 0<x<2.

### Claim 4 (depends on 1)

The anode for a lithium secondary battery of claim 1,
wherein a thickness ratio of the first anode active material layer to the second anode active material layer is 30 to 50:50 to 70.

### Claim 5 (depends on 4)

The anode for a lithium secondary battery of claim 4,
wherein the thickness ratio of the first anode active material layer to the second anode active material layer is 40:60.

### Claim 6 (depends on 1)

The anode for a lithium secondary battery of claim 1,
wherein the first binder and the second binder contain a same kind of a compound.

### Claim 7 (depends on 1)

The anode for a lithium secondary battery of claim 1,
wherein the first binder and the second binder are styrene-butadiene rubber (SBR).

### Claim 8 (depends on 1)

The anode for a lithium secondary battery of claim 1,
wherein the first binder is contained in 1.2 to 5 wt % based on a total weight of the first anode active material layer, and the second binder is contained in 1 to 3 wt % based on a total weight of the second anode active material layer.

### Claim 9 (depends on 1)

The anode for a lithium secondary battery of claim 1,
wherein a weight ratio of the first binder and the second binder is 1.3˜1.7:1.

### Claim 10 (depends on 9)

The anode for a lithium secondary battery of claim 9,
wherein a weight ratio of the first binder and the second binder is 1.5:1.

### Claim 11 (depends on 1)

The anode for a lithium secondary battery of claim 1,
wherein both the first anode active material layer and the second anode active material layer further contain an electrically conductive material, and
the conductive material is contained in 1 wt % to 3 wt % based on a total weight of the anode active material layer in each anode active material layer.

### Claim 12 (depends on 11)

The anode for a lithium secondary battery of claim 11,
wherein the conductive material contained in each anode active material layer is carbon black.

### Claim 13 (depends on 1)

The anode for a lithium secondary battery of claim 1,
wherein the first anode active material layer and the second anode active material layer further contain a thickener, and
the thickener is contained in 1 wt % to 3 wt % based on a total weight of the anode active material layer in each anode active material layer.

### Claim 14 (depends on 13)

The anode for a lithium secondary battery of claim 13,
wherein the thickener contained in each anode active material layer is carboxymethyl cellulose (CMC).

### Claim 15 (depends on 1)

A lithium secondary battery comprising the anode for a lithium secondary battery of claim 1.

### Claim 16

An anode for a lithium secondary battery, comprising
an anode current collector;
a first anode active material layer formed on at least one surface of the anode current collector, wherein the first anode active material layer contains an anode active material comprising a mixture of natural graphite and artificial graphite in a weight ratio of 13˜34:66˜87, and a first binder; and
a second anode active material layer formed on the first anode active material layer, wherein the second anode active material layer contains an anode active material comprising a mixture of artificial graphite and SiO in a weight ratio of 91 to 99:1 to 9, and a second binder.
