# US 2020/0399478 A1 · Antimicrobial sacrificial floor coating systems

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- Number: US 2020/0399478 A1
- Document ID: US20200399478A1
- Status: Published application
- Kind: A1
- Application number: 17/007,702
- Filed: 2020-08-31
- Published: 2020-12-24
- Earliest claimed: 2016-07-11
- Assignees: Spartan Chemical Company, Inc.
- Applicants: Spartan Chemical Company, Inc.
- Inventors: Rebecca S. Kaufold; Jason J. Welch; Jamie N. Venable
- Web page: https://patentgrep.com/patent/US20200399478A1

## CPC

- C09D 5/14: Paints containing biocides, e.g. fungicides, insecticides or pesticides (C09D5/16 takes precedence)
- A01N 25/10: Macromolecular compounds
- A01N 47/44: Guanidine; Derivatives thereof
- C08L 3/08: Ethers
- C09D 9/005: {containing organic solvents}
- C09D 9/04: with surface-active agents
- C09D 133/00: Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)
- A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)

## Abstract

Disclosed are antimicrobial sacrificial floor coatings systems including an antimicrobial sacrificial floor coating composition capable of reducing and/or preventing gram positive and gram negative bacterial growth on floors. Also disclosed is an antimicrobial sacrificial floor coating remover being readily capable of removing the antimicrobial sacrificial floor coating as desired from previously treated flooring surfaces. In certain aspects, the antimicrobial sacrificial floor coatings can include a nonionic acrylic polymer; a nonionic wax; and a cationic alkyl biguanide or salt thereof. The antimicrobial sacrificial floor coating may further include a cationic wax that further stabilizes the system during storage, application, and/or post-application to a floor surface. The antimicrobial sacrificial floor coating composition has a pH of less than 7 while exhibiting continuous antimicrobial properties from full cure on a floor surface up to 1 year post-application to the floor surface at a minimum contact time of 1 hour.

## Claims

### Claim 1

An antimicrobial sacrificial floor coating composition comprising:
(a) an acrylic polymer;
(b) a nonionic wax;
(c) a cationic wax; and
(d) an antimicrobial agent comprising a cationic alkyl biguanide or salt thereof, the cationic alkyl biguanide or salt thereof ranging from 0.5 active wt % to 0.95 active wt % in the antimicrobial sacrificial floor coating composition, wherein:
the antimicrobial sacrificial floor coating composition is acidic and forms a coating on a substrate having antimicrobial properties post-application thereto.

### Claim 2 (depends on 1)

The antimicrobial sacrificial floor coating composition of claim 1, wherein the antimicrobial sacrificial floor coating composition is adapted to exhibit a log reduction of from 3.3 to 6 for gram negative bacteria and a log reduction of from 3.11 to 6.3 for gram positive bacteria after a minimum contact time of 1 hour with the coating composition post-application to the substrate.

### Claim 3 (depends on 1)

The antimicrobial sacrificial floor coating composition of claim 1, wherein the antimicrobial sacrificial floor coating composition is heat stable.

### Claim 4 (depends on 1)

The antimicrobial sacrificial floor coating composition of claim 1, wherein the nonionic wax comprises a nonionic alkylene polymer.

### Claim 5 (depends on 4)

The antimicrobial sacrificial floor coating composition of claim 4, wherein the nonionic wax is a high density polyethylene or derivative thereof, a high density polypropylene or derivative thereof, or a combination thereof.

### Claim 6 (depends on 5)

The antimicrobial sacrificial floor coating composition of claim 5, wherein the nonionic wax is at a concentration of between 2.5 wt % to 8 wt % in the antimicrobial sacrificial floor coating composition.

### Claim 7 (depends on 1)

The antimicrobial sacrificial floor coating composition of claim 1, wherein the cationic wax comprises a cationic alkylene polymer.

### Claim 8 (depends on 7)

The antimicrobial sacrificial floor coating composition of claim 7, wherein the cationic alkylene polymer is an oxidized high density polyethylene, an oxidized high density oxidized polypropylene, or a combination thereof.

### Claim 9 (depends on 8)

The antimicrobial sacrificial floor coating composition of claim 8, wherein the cationic alkylene polymer is at a concentration of between 2.5 wt % to 8.0 wt % in the antimicrobial sacrificial floor coating composition.

### Claim 10 (depends on 1)

The antimicrobial sacrificial floor coating composition of claim 1, wherein the cationic alkyl biguanide or salt thereof is polyhexamethylene biguanide, polyaminopropryl biguanide, or a combination thereof.

### Claim 11 (depends on 10)

The antimicrobial sacrificial floor coating composition of claim 10, wherein cationic alkyl biguanide or salt thereof ranges from 0.6 to 0.95 active wt %, in the antimicrobial sacrificial floor coating.

### Claim 12 (depends on 1)

The antimicrobial sacrificial floor coating composition of claim 1, wherein the antimicrobial sacrificial floor coating does not include crosslinking agents and/or is not polymerizable during or post-application to a floor surface.

### Claim 13 (depends on 1)

The antimicrobial sacrificial floor coating composition of claim 1, wherein the antimicrobial sacrificial floor coating composition comprises:
(a) the acrylic polymer at a concentration ranging from 30 to 40 wt % of the antimicrobial sacrificial floor coating composition;
(b) the nonionic wax at a concentration ranging from 2.5 to 8 wt % of the antimicrobial sacrificial floor coating composition,
(c) the cationic wax at a concentration ranging from 2.5 to 8 wt % of the antimicrobial sacrificial floor coating composition;
(d) the antimicrobial agent at a concentration of up to 4 wt % of the antimicrobial sacrificial floor coating composition; and
(e) water at a concentration ranging from 30 to 65 wt % of the antimicrobial sacrificial floor coating composition.

### Claim 14 (depends on 13)

The antimicrobial sacrificial floor coating composition of claim 13, wherein the antimicrobial sacrificial floor coating composition exhibits a log reduction of from 3.3 to 6 for gram negative bacteria and a log reduction of 3.11 to 6.3 for gram positive bacteria after application to the substrate and at a minimum contact time of 1 hour with the coating composition.

### Claim 15

A kit comprising:
an antimicrobial sacrificial floor coating composition in a first container, the antimicrobial sacrificial floor coating composition comprises:
(a) an acrylic polymer;
(b) a nonionic wax;
(c) a cationic wax; and
(d) an antimicrobial agent that includes a cationic alkyl biguanide or salt, the cationic alkyl biguanide or salt thereof ranging from 0.5 active wt % to 0.95 active wt % in the antimicrobial sacrificial floor coating composition; and
(ii) an antimicrobial sacrificial floor coating remover in a second container, the antimicrobial sacrificial floor coating remover comprises:
(a) an organic solvent at a concentration ranging from 17 wt % to 30 wt % of the antimicrobial sacrificial floor coating remover;
(b) a nonionic surfactant at a concentration ranging from 0.5 wt % to 5 wt % of the antimicrobial sacrificial floor coating remover; and
(c) an organic acid at a concentration ranging from 1 wt % to 5 wt % of the antimicrobial sacrificial floor coating remover.

### Claim 16 (depends on 15)

The kit of claim 15, wherein the antimicrobial sacrificial floor coating remover further comprises water.

### Claim 17 (depends on 16)

The kit of claim 16, wherein the antimicrobial sacrificial floor coating remover has a zero volatile organic compound (0 VOC) content.
