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AssigneeThe Regents of the University of Michigan
InventorsTimothy Cernak, Babak Mahjour, Yuning Shen, Andrew McGrath, Rui Zhang
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Disclosed herein is a method of generating a combinatorial library of products having a diverse array of properties. In particular, the method comprises: (a) selecting one or more pairs of reactants comprising complementary functional groups; (b) mapping all possible bond arrangements between the complementary functional groups of each pair to provide a library of possible products; (c) analyzing one or more properties of each possible product to select one or more products with desired properties (desired products); and (d) synthesizing the one or more desired products. Further disclosed herein is a method that involves the retrosynthetic reduction of a complex molecule into simple starting materials.
A method comprising:
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A method of forming a carbon-carbon bond comprising contacting an activated aryl amine with an aryl carboxylic acid or derivative thereof in the presence of a catalytic system comprising a silver salt and a transition metal catalyst comprising copper, nickel, iron, or palladium to form the carbon-carbon bond.
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A method of forming a carbon-carbon bond comprising contacting an aryl amine or activated amine with an alkyl carboxylic acid or derivative thereof in the presence of a co-catalytic system comprising a photoredox co-catalyst and a transition metal co-catalyst comprising copper, nickel, and palladium to form the carbon-carbon bond.
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A method comprising:
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Dependencies are inferred from the claim text.