Method for Forming Highly Reactive Olefin Functional Polymers

A process for the preparation of polybutene having an exo-olefin content of at least 50 mol. % from an isobutene or an isobutene-containing monomer feedstock, which process comprises contacting said isobutene or isobutene-containing feedstock, with a Lewis acid catalyst complexed with a Lewis base, in a substantially or completely apolar polymerization medium, and initiating polymerization of said isobutene or isobutene-containing feedstock with an initiator, wherein said Lewis acid catalyst is a Lewis acid of the formula R′AlCl2, wherein R′ is a hydrocarbyl group;

• said Lewis base is a dihydrocarbyl ether wherein each hydrocarbyl group is independently selected from hydrocarbyl groups having 1 to 8 carbon atoms and one or both hydrocarbyl groups of the dihydrocarbyl ether are substituted with an electron withdrawing group and the initiator is a compound of the formula RX, wherein X is a halide;
• R is a hydrocarbyl group capable of forming a stable carbocation, and the carbon linking group R to group X is tertiary, benzylic or allylic;
• wherein the catalyst complex is pre-activated by addition of water, and the pre-activated catalyst complex is subsequently reacted with from about 0.1 to about 2 molar equivalents, per equivalent of Lewis acid, of a trialkyl aluminum compound wherein each alkyl group of said trialkyl aluminum compound has at least 2 carbon atoms.