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US 2020/0308323 A1Published application
Cationic Metal Complex, Organometal Catalyst Having Borate-Based Bulky Anion, Method for Preparing the Same, and Method for Preparing Oligomer or Polymer Using the Same
AssigneeLG Chem, Ltd.
InventorsGyeong Shin Choi, Dong Hyun Jo, Won Hee Kim, Seung Young Park, Hyun Taek Oh
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Abstract
The present invention provides an organometal catalyst having a cationic metal complex and a borate-based bulky anion, where the metal is one or more selected from the group consisting of metals in group 13, a method for preparing the same, and a method for preparing an oligomer or a polymer using the same.
Claims20
An organometal catalyst having a cationic metal complex and a borate-based bulky anion, and being represented by the following Formula 1:
- in Formula 1,
- M is selected from the group consisting of metals in group 13,
- L is each independently a coordination solvent molecule comprising a functional group selected from the group consisting of a cyanide group, an isocyanide group, an ether group, a pyridine group, an amide group, a sulfoxide group and a nitro group,
- R1 to R4 are each independently hydrogen, a halogen group, or a substituted or unsubstituted alkyl group of C1-C20,
- R5 and R6 are each independently hydrogen, an alkyl group of C1-C20, an aryl group of C6-C20, or an allyl group,
- a, b, c and a+b+c are each independently an integer of 0 to 3, d and a+b+c+d are each independently an integer of 1 to 10,
- o, p, q and r are each independently an integer of 1 to 5, and
- x and y are an integer of 1 to 4 and are the same to each other.
5 more elements
A method for preparing an organometal catalyst, the method comprising:
- a step of preparing a dispersion comprising a metal precursor represented by the following Formula 2 and a coordinating solvent;
- and
- a step of reacting an organic borate-based compound containing carbon-based, silyl-based, or amine-based cation and a borate-based bulky anion with the dispersion:
- M(OCOR5)e(NO3)f(OR6)g(X)h [Formula 2]
- in Formula 2,
- M is selected from the group consisting of metals in group 13,
- R5 and R6 are each independently hydrogen, an alkyl group of C1-C20, an aryl group of C6-C20, or an allyl group,
- X is Cl, Br or I, and
- e, f, g and h are each independently an integer of 0 to 3, and e+f+g+h is 3.
6 more elements
Dependencies are inferred from the claim text.